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931.
合成了手性物质N-十二酰基-l-脯氨酸(N-DDO-l-Pro)(脯氨酸, Pro), 作为PVC膜电极的载体, 在PVC膜表面与被测试液中Cu(II)与脯氨酸形成的配合物[Cu(II)(l-Pro)2]或[Cu(II)(d-Pro)2]进行配体交换, 形成[(l-Pro)Cu(II) (N-DDO-l-Pro)]或[(d-Pro)Cu(II)(N-DDO-l-Pro)]配合物. 由于生成的配合物热力学稳定性不同, 电极能优先响应l-Pro, 线性范围10-4~10―1 mol•L-1, 斜率57 mV•dec-1, 检测限3.89×10-5 mol•L-1. 电极能够对脯氨酸进行手性检测, 其对映选择性系数lg为-3.19. 相似文献
932.
933.
Dispersion characteristics of two-dimensional unmagnetized dielectric plasma photonic crystal 总被引:1,自引:0,他引:1
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This paper studies dispersion characteristics of the
transverse magnetic (TM) mode for two-dimensional unmagnetized
dielectric plasma photonic crystal by a modified plane wave method.
First, the cutoff behaviour is made clear by using the
Maxwell--Garnett effective medium theory, and the influences of
dielectric filling factor and dielectric constant on effective
plasma frequency are analysed. Moreover, the occurence of large gaps in
dielectric plasma photonic crystal is demonstrated by comparing the
skin depth with the lattice constant, and the influence of plasma
frequency on the first three gaps is also studied. Finally, by using
the particle-in-cell simulation method, a transmission curve in the
\Gamma -X direction is obtained in dielectric plasma photonic
crystal, which is in accordance with the dispersion curves
calculated by the modified plane wave method, and the large gap between
the transmission points of 27~GHz and 47~GHz is explained by
comparing the electric field patterns in particle-in-cell
simulation. 相似文献
934.
The goal of this investigation is to introduce a new computer procedure for the integration of B-spline geometry and the absolute nodal coordinate formulation (ANCF) finite element analysis. The procedure is based on developing a linear transformation that can be used to transform systematically the B-spline representation to an ANCF finite element mesh preserving the same geometry and the same degree of continuity. Such a linear transformation that relates the B-spline control points and the finite element position and gradient coordinates will facilitate the integration of computer aided design and analysis (ICADA). While ANCF finite elements automatically ensure the continuity of the position and gradient vectors at the nodal points, the B-spline representation allows for imposing a higher degree of continuity by decreasing the knot multiplicity. As shown in this investigation, a higher degree of continuity can be systematically achieved using ANCF finite elements by imposing linear algebraic constraint equations that can be used to eliminate nodal variables. The analysis presented in this study shows that continuity of the curvature vector and its derivative which corresponds in the cubic B-spline representation to zero knot multiplicity can be systematically achieved using ANCF finite elements. In this special case, as the knot multiplicity reduces to zero, the recurrence B-spline formula causes two segments to automatically blend together forming one cubic segment defined on a larger domain. Similarly in this special case, the algebraic constraint equations required for the C 3 continuity convert two ANCF cubic finite elements to one finite element, demonstrating the strong relationship between the B-spline representation and the ANCF finite element representation. For the same order of interpolation, higher degree of continuity at the finite element interface can lead to a coarser mesh and to a lower dimensional model. Using the B-spline/ANCF finite element transformation developed in this paper, the equations of motion of a finite element mesh that represents exactly the B-spline geometry can be developed. Because of the linearity of the transformation developed in this investigation, all the ANCF finite element desirable features are preserved; including the constant mass matrix that can be used to develop an optimum sparse matrix structure of the nonlinear multibody system dynamic equations. 相似文献
935.
Optical switching based on the manipulation of microparticles in a colloidal liquid using strong scattering force
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This paper demonstrates the realization of an optical switch by optically manipulating a large number of polystyrene spheres contained in a capillary.The strong scattering force exerted on polystyrene spheres with a large diameter of 4.3 μm is employed to realize the switching operation.A transparent window is opened for the signal light when the polystyrene spheres originally located at the beam centre are driven out of the beam region by the strong scattering force induced by the control light.The switching dynamics under different incident powers is investigated and compared with that observed in the optical switch based on the formation of optical matter.It is found that a large extinction ratio of ~ 30 dB and fast switching-on and switching-off times can be achieved in this type of switch. 相似文献
936.
焊管的残余应力测试与研究 总被引:6,自引:1,他引:5
通过小孔法与分割法对φ272mm螺旋埋弧焊管和φ380mm对接焊管的残余应力测试,分析探讨了螺旋焊缝、环焊缝以及焊缝热影响区的残余应力分布。研究结果表明,不同工艺焊接成型的圆管,其焊缝纵向均匀为拉应力分布,焊缝横向均为压应力分布,焊缝热影响区的残余应力分布各异。 相似文献
937.
In this paper, we have obtained the necessary and sufficient condition for the set of points at infinity on the plane R
2 to be a periodic orbit which is called an equatorial periodic orbit of a planar vector field X(x), and the formulae about the multiplicity of the equatorial periodic orbit of X(x). We have also proved that the main result of [9] is erroneous with regard to the formulae.
This work is supported by the NSF of China 相似文献
938.
939.
940.