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21.
Back Cover: Exploring Excited‐State Tunability in Luminescent Tris‐cyclometalated Platinum(IV) Complexes: Synthesis of Heteroleptic Derivatives and Computational Calculations (Chem. Eur. J. 52/2014)
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22.
Dr. Luis Martín-Gomis Sairaman Seetharaman David Herrero Prof. Dr. Paul A. Karr Prof. Dr. Fernando Fernández-Lázaro Prof. Dr. Francis D'Souza Prof. Dr. Ángela Sastre-Santos 《Chemphyschem》2020,21(20):2254-2262
The effect of donor-acceptor distance in controlling the rate of electron transfer in axially linked silicon phthalocyanine-C60 dyads has been investigated. For this, two C60-SiPc-C60 dyads, 1 and 2 , varying in their donor-acceptor distance, have been newly synthesized and characterized. In the case of C60-SiPc-C60 1 where the SiPc and C60 are separated by a phenyl spacer, faster electron transfer was observed with kcs equal to 2.7×109 s−1 in benzonitrile. However, in the case of C60-SiPc-C60 2 , where SiPc and C60 are separated by a biphenyl spacer, a slower electron transfer rate constant, kcs=9.1×108 s−1, was recorded. The addition of an extra phenyl spacer in 2 increased the donor-acceptor distance by ∼4.3 Å, and consequently, slowed down the electron transfer rate constant by a factor of ∼3.7. The charge separated state lasted over 3 ns, monitoring time window of our femtosecond transient spectrometer. Complimentary nanosecond transient absorption studies revealed formation of 3SiPc* as the end product and suggested the final lifetime of the charge separated state to be in the 3–20 ns range. Energy level diagrams established to comprehend these mechanistic details indicated that the comparatively high-energy SiPc.+-C60.− charge separated states (1.57 eV) populated the low-lying 3SiPc* (1.26 eV) prior returning to the ground state. 相似文献
23.
Víctor García‐Herrero Carlos Torrado‐Salmern Juan Jos García‐Rodríguez Guillermo Torrado Santiago Torrado‐Santiago 《Journal of separation science》2019,42(9):1702-1709
Rapid, simple, and sensitive submicellar liquid chromatography with fluorescence detection was developed and validated to quantify naproxen in plasma and brain samples after oral administration of Naproxen formulations. The method used tramadol as an internal standard. Different submicellar mobile phases with organic phases ranging from 40 to 60% were studied to improve the native fluorescence of the Naproxen and decrease retention times. Separation was done in a Zorbax SB C8 column (250 × 4.6 mm, 5 μm) with a mobile phase containing acidic 0.007 M sodium dodecyl sulfate/acetonitrile (50:50, v/v) at a flow rate of 1 mL/min. Detection was performed with an excitation wavelength of 280 nm and emission of 310 nm and 360 nm for internal standard and Naproxen, respectively. The method was validated by International Conference of Harmonization standards. The method is specific, accurate, and precise (relative standard deviation <3%). Limits of detection and quantification were 0.08 and 0.25 μg/mL, respectively, for biological samples. This method was applied to analyze brain/plasma ratios in mice that had received oral administrations of Naproxen micellar formulations containing 10% w/w of sodium dodecyl sulfate, Cremophor RH 40, or Tween 80. The sodium dodecyl sulfate micelles were faster and more widely distributed in the mouse brains. 相似文献
24.
A practical, brief and selective synthesis of several pinene oxide derived terpenoids can be achieved from readily available starting materials. The key step is a radical reaction promoted by titanocene chloride. 相似文献
25.
Chilling resistances of isolates of Pythium ultimum var. ultimum from the Arctic and Temperate Zones
Hoshino T Tojo M Kanda H Herrero ML Tronsmo AM Kiriaki M Yokota Y Yumoto I 《Cryo letters》2002,23(3):151-156
Chilling resistances in moss pathogenic fungi, Pythium ultimum var. ultimum, from Longyearbyen, Svalbard (78 degree N, 15 degree E), located in the Arctic Zone and in the same isolates from Temperate Zone, were determined. Both strains had similar optimum growth temperatures. However, the strains from Svalbard could grow and survive at 0 - 5 degrees C. In addition, chilling treatment induced irregular mycelial morphology in the Arctic isolates. On the other hand, the isolates from Japan did not grow at temperatures below 5C and were destroyed after chilling stress (0 degree C for 3 days or at 4 degrees C for 1 week). The results suggested that isolates from Svalbard highly adapted to the severe spring condition in Polar environments. 相似文献
26.
Domingo A. Herrero 《Mathematische Annalen》1974,207(4):271-279
27.
Hernandez J Solla-Gullón J Herrero E Aldaz A Feliu JM 《The journal of physical chemistry. B》2005,109(26):12651-12654
The surface structure of gold nanorods has been determined by studying the behavior of electrochemical reactions sensitive to the structure and compared to that obtained by other structure characterization techniques. Lead underpotential deposition (UPD) reveals that the surface of the nanorods is composed by (111) and (110) domains, while (100) domains are practically absent from the surface. In the case of the oxygen reduction reaction, the formation of hydrogen peroxide as a final product of the reaction in the whole potential range also indicates that (100) domains are absent on the surface of the nanoparticles, corroborating the previous result. These results are compared with other surface structure information provided by other techniques. 相似文献
28.
29.
Absence of dc-conductivity in lambda-DNA 总被引:2,自引:0,他引:2
de Pablo PJ Moreno-Herrero F Colchero J Gómez Herrero J Herrero P Baró AM Ordejón P Soler JM Artacho E 《Physical review letters》2000,85(23):4992-4995
The electrical conductivity of biomaterials on a molecular scale is of fundamental interest in the life sciences. We perform first principles electronic structure calculations, which clearly indicate that lambda-DNA chains should present large resistance values. We also present two direct procedures to measure electrical currents through DNA molecules adsorbed on mica. The lower limit for the resistivity is 10(6) Omega . cm, in agreement with our calculations. We also show that low energy electron bombardment induces a rapid contamination and dramatically affects the measured conductivity, thus providing an explanation to recent reports of high DNA conductivity. 相似文献
30.
H. Herrero 《The European physical journal. Special topics》2007,146(1):235-247
Chebyshev collocation methods are high-order methods.
This means that high precision is obtained with low-order
expansions. Then `small' matrices appear in the numerical
implementation and reduced computing resources become necessary.
Thermoconvective fluid dynamics problems are large ones, involving
various partial differential equations for several fields in large
dimensions. The models present a number of difficulties, such as
the different orders of derivatives for the different fields, or
lack of information on the boundary conditions for pressure. This
paper presents a review of the specific characteristics of this
method when it is applied to thermoconvective problems: the
method, the types of problems, the different resulting models, the
strategies to overcome the difficulties of the different
derivative orders and the characteristics of the matrices, and the
convergence properties. A comparison of its efficiency with other
numerical methods like finite differences and finite elements is
included. 相似文献