CuAl2Cl8. Darstellung und Kristallstruktur

CuAl₂Cl₈. Preparation and Crystal Structure. Crystals of CuAl₂Cl₈ have been prepared. Their remission spectrum agrees with that of gaseous CuAl₂Cl₈. The crystal structure (P2₁/c;a = 6.614, b = 7.376, c = 12.319 Å; β = 94.11°) shows a molecular lattice with Cu in square planar coordination, which is completed to a stretched octahedron (as in solid CuCl₂) by two Cl atoms from neighbour molecules. Al has tetrahedral coordination.     

Numerical simulation of a three dimensional quantum dot

We consider the problem to compute relevant energy states and corresponding wave functions of a three dimensional semiconductor quantum dot. Let Ω_q ⊂ ℝ³ be a domain occupied by the quantum dot, which is embedded in a matrix Ω_m of different material. A typical example is an InAs pyramidal quantum dot embedded in a cuboid GaAs matrix. (© 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)     

Elliptic Interface Problems in Axisymmetric Domains. Part I: Singular Functions of Non - Tensorial Type

We study the regularity of solutions of interface problems for the Poisson equation in axisynunetric domains. The Fourier decomposition of the 3D-problem into a sequence of 2D-variational equations end uniform (with respect to the sequence parameter) a prior; estimates of their solutions are derived. Some non-tensorial singular functions describing the behaviour of the solution near interface edges are given and the smoothness of the stress intensity distribution as well as the tangential regularity are characterized in tenns of Sobolev spaces. In a forthcoming part II of this paper, the results will be applied to error estimates of the so-called Fourier-finite-element method for solving approximately elliptic interface problems in 3D.     

G-spaces and Fixed Point Sets

For a compact connected group G, in a compact free G-space M every closed subset is the fixed point set of an autohomeomorphism if the weight of M is not bigger than that of G. In a compact group with nonsingleton components, every closed subset is the fixed point set of an autohomeomorphism if and only if the weight of the whole group is not bigger than that of the component of the identity.     

Variational characterization of eigenvalues of a non-symmetric eigenvalue problem governing elastoacoustic vibrations

Small amplitude vibrations of an elastic structure completely filled by a fluid are considered. Describing the structure by displacements and the fluid by its pressure field one arrives at a non-selfadjoint eigenvalue problem. Taking advantage of a Rayleigh functional we prove that its eigenvalues can be characterized by variational principles of Rayleigh, minmax and maxmin type.     

Chernoff's Theorem and Discrete Time Approximations of Brownian Motion on Manifolds

Let be a one-parameter family of positive integral operators on a locally compact space . For a possibly non-uniform partition of define a finite measure on the path space by using a) for the transition between any two consecutive partition times of distance and b) a suitable continuous interpolation scheme (e.g. Brownian bridges or geodesics). If necessary normalize the result to get a probability measure. We prove a version of Chernoff's theorem of semigroup theory and tightness results which yield convergence in law of such measures as the partition gets finer. In particular let be a closed smooth submanifold of a manifold . We prove convergence of Brownian motion on , conditioned to visit at all partition times, to a process on whose law has a density with respect to Brownian motion on which contains scalar, mean and sectional curvatures terms. Various approximation schemes for Brownian motion on are also given.      

Assemblies from metallic and semiconducting nanocrystals

Optical properties of nanomaterials such as semiconductor and metal quantum dots are important for sensors and photovoltaic applications. We report on optical, microscopic, and AFM investigations on bulk and single nanoobjects such as metal and semiconducting nanoparticles. Firstly, of special interest is the investigation of Ag metal nanoaggregates formed in zeolites. Here, the defined structure of the zeolite serves both as size directing and a stabilizing agent. The size selected Ag aggregates fluoresce in the zeolite cages even after storage under ambient conditions for almost one year. In addition, single Ag particles escape the cages and can be investigated by fluorescence microscopy also with respect to sensor applications. Secondly, with respect to photovoltaic applications, energy transfer among organic dye molecules and semiconductor quantum dots is of great importance. We report on the extension of the optical absorption of ZnSe quantum dots into the UV regime and investigate excitation energy transfer within self-assembled nanoaggregates of surface functionalized QDs and fluorescent styrylpyridine dyes.     

Perfect imaging through a disordered waveguide lattice

It is experimentally demonstrated that perfect imaging is possible in disordered wave guiding media, provided that the disorder is off-diagonal, i.e., that only the spacing varies randomly between the otherwise identical lattice sites. On-diagonal disorder or Kerr nonlinearity destroys the imaging.     

High-resolution imaging of single fluorescent molecules with the optical near-field of a metal tip

We show that a concentration of light at a metal tip allows near-field optical imaging of single fluorescent dye molecules at very high resolution, despite strong quenching effects. Details as small as 10 nm were observed in the fluorescence patterns of single Cy-3 dyes bound to the termini of DNA. Data evaluation by model fitting determines the positions of the dyes to an accuracy even better than 1 nm and also yields their 3D orientation. The metal tip simultaneously provides high-resolution topographic imaging complementing the optical signal for a detailed surface examination.     

Generation of hard X-ray radiation using the triboelectric effect by peeling adhesive tape

The triboelectric effect describes electrical charging when bringing different materials into contact. We report on the generation of hard X-ray radiation by peeling various adhesive tapes under medium vacuum conditions. Beside vacuum housing and pumps as instrumentation only an electric motor, two rolls and a metal foil as target material are necessary. The spectral distribution of generated X-rays was analyzed using an energy-dispersive detector. Depending on peeling speed, pressure and choice of material combination, electrons with energies sufficient to excite emission in the hard X-ray region are produced. The results are discussed in terms of triboelectric separation of charge carriers.