Peels of buckyballs

The polymer analogous aromatization of double-stranded Diels-Alder polymers to give fully unsaturated, all-carbon ladder polymers by means of dehydration and dehydrogenation is described. The polymers obtained were characterized by solid state ¹³C NMR spectroscopy.     

On measurement and irreversible processes

The nature of physical measurements performed on microscopic systems is discussed, and it is suggested that the procedures which are conventionally referred to as measurements fall into at least three different categories. The connection between observation processes and irreversible processes is stressed. The customary quantum mechanical treatment of irreversible processes is discussed, and its deficiencies from the philosophical point of view are criticized. The standpoint that quantum mechanics should not be considered as a basic philosophical system but rather as an immensely useful tool is defended. Some attempts at developing a more basic theory are discussed, and a hypothesis is put forward concerning the role of entropy within some possible future nonlocal hidden-variable theory.     

Exponential sums on , II

We prove a vanishing theorem for the -adic cohomology of exponential sums on . In particular, we obtain new classes of exponential sums on that have a single nonvanishing -adic cohomology group. The dimension of this cohomology group equals a sum of Milnor numbers.

     

Dopant-pair structures segregated on a hydrogen-terminated Si(100) surface

Novel atomic structures on a H-terminated Si(100)-(2x1)-H surface were found using scanning tunneling microscopy (STM). The structures are distinguishable only from Si dimers in empty-state STM images. They were observed on arsenic- and phosphorus-doped substrates, but not on boron-doped substrates. Surface density of these structures was found to be proportional to the dopant density in the substrate. First-principles calculations clarify that they are consisting of dopant pairs that are segregated from the bulk material. Hydrogen atoms attached to the dopant pair are found to flip between two positions on the surface due to a quantum effect.