网络的超星分形生长模型

随着信息产业国际化趋势的发展，广域网理论的研究显得越来越重要，中提出了网络的分形生长结构模型和生长方法，从全新的角度讨论广域网的生长、发展的过程。该结构模型将是描述互连广域的重要工具。     

Four Triterpene Oligoglycosides from the seeds of Aesculus Chinensis

TheseedsofAesculuschinensisBge.(Hippocastanaceae)havebeenusedasfolkmedicineforthetreatmentofdistensionandpaininchestandabdomenl.Untilnow,thereisnoreportonitschemicalconstituents.Thispaperdescribesstructureelucidationoftwonewcompounds,escinsIVa3andIVb4onthebasisofspectroscopicmethodsandcomparisonwithescinsla1andfo22.Amongthem,EscinlaIwasstudiedbyX-raydistractionanalysis.Compound3,whitepowder,showediRbandsduetocarboxylanda,p-unsaturatedesterat1740,1713and1640cm-'andstrongabsorptionbandsat34…     

钯-碳/NaHCO3催化下2,4-二氯嘧啶的区域选择性脱氯反应：一种合成2-氯嘧啶的有效方法

本文报道了一种合成2-氯嘧啶的有效方法。易得原料2,4-二氯嘧啶在钯-碳/NaHCO3作用下可以区域选择性地脱除2位氯原子得到2-氯嘧啶。2-氯嘧啶可以用作多种复杂嘧啶衍生物的有效合成砌块。     

Extending the GGobi pipeline from R

This paper describes progress towards developing a platform for rapid prototyping of interactive data visualizations, using R, GGobi, rggobi and RGtk2. GGobi is a software tool for multivariate interactive graphics. At the core of GGobi is a data pipeline that incrementally transforms data through a series of stages into a plot and maps user interaction with the plot back to the data. The GGobi pipeline is extensible and mutable at runtime. The rggobi package, an interface from the R language to GGobi, has been augmented with a low-level interface that supports the customization of interactive data visualizations through the extension and manipulation of the GGobi pipeline. The large size of the GGobi API has motivated the use of the RGtk2 code generation system to create the low-level interface between R and GGobi. The software is demonstrated through an application to interactive network visualization.     

《数学实验》课程建设的认识与实践

我们认为 :数学实验 ,就是对数学进行折腾 .我们提出一些饶有趣味而又有深刻背景的问题 ,让学生尝试自己去解决 ,借助于计算机 ,自己动手去折腾 ,在折腾过程中学习 ,观察现象和结果 ,猜测和验证规律 ,尝试和体验数学的探索、发现和应用     

Groupwise dense families

We show that the Filter Dichotomy Principle implies that there are exactly four classes of ideals in the set of increasing functions from the natural numbers. We thus answer two open questions on consequences of ? < ?. We show that ? < ? implies that ? = ?, and that Filter Dichotomy together with ? < ? implies ? < ?. The technical means is the investigation of groupwise dense sets, ideals, filters and ultrafilters. With related techniques we prove the new inequality ?≤ cf(?). Received: 9 October 1998 / Revised version: 18 August 1999 / Published online: 21 December 2000     

Gold‐ or Platinum‐Catalyzed Cascade Processes of Alkynol Derivatives Involving Hydroalkoxylation Reactions Followed by Prins‐Type Cyclizations

An efficient method for the synthesis of [3.3.1]bicyclic compounds from easily available alkynol derivatives has been developed. The reaction is based on a gold‐ or platinum‐catalyzed tandem process that involves an intramolecular hydroalkoxylation of a triple bond followed by a Prins‐type cyclization. The reaction has been carried out with differently substituted alkynol derivatives and oxygen‐, nitrogen‐, and carbon‐centered nucleophiles. The incorporation of halogen atoms as nucleophiles and elimination reactions has also been studied. Enantiomerically pure [3.3.1]bicyclic systems were easily synthesized from the chiral pool.     

氮氧自由基研究(ⅩⅩⅢ)——哌啶氮氧自由基及其氧铵盐与N,N,N′,N′-四甲基对苯二胺在水溶液中的单电子转移反应

ESR波谱和流动-停止UV动力学研究表明,水溶液中2,2,6,6-四甲基-4-羟基哌啶-1-氧自由基1和相应氧铵澳盐2均可将N,N,N′,N′-四甲基对苯二胺(TMPD)氧化为相应自由基正离子TMPD+,2还能将TMPD+进一步氧化为二价正离子TMPD~(2+).TMPD+可发生可逆歧化,其稳定性强烈受介质酸碱性的影响。利用计算机对动力学曲线的模拟测得上述有关反应的速率常数,并讨论了反应机理。