一种基于Infomax的盲分离算法及其稳定性

本文讨论具有超高斯分布与亚高斯分布的混合源信号的分离问题 ,提出了一种有效的分离算法———拓广的Infomax算法 ,并分析了该算法的渐近稳定性 ,与原有的Infomax算法相比 ,本文所提算法具有更广泛的应用范围 .模拟实验验证了算法的有效性     

同步辐射讲座第一讲 同步辐射XAFS实验站及其应用

介绍了北京和合肥同步辐射XAFS实验站的性能参数和结构, 及在物理，化学，材料和生命科学等研究领域的应用，便于国内广大用户更好地利用其开展高质量的研究工作。     

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应用动态应变测试方法对悬挂式残膜回收机悬挂架进行实地动应力测 试，通过数据处理及其分析，得到悬挂架在工作条件下的应力状态，以及不同工作状态下各 构件的应力情况，并对悬挂架进行了疲劳强度分析，为进一步改进设计提供必要的理论依据.     

Microstructure morphology transitions at mesoscopic epitaxial surfaces

Spiral surface growth is well understood in the limit where motion of the spiral ridge is controlled by the local supersaturation of adatoms in its surrounding. In liquid epitaxial growth, however, spirals can form governed by both, transport of heat as well as solute. We propose for the first time a two-scale model of epitaxial growth which takes into account all of these transport processes. This new model assumes a separation of length scales for the transport of heat compared to that of the solutal field. It allows for the first time numerical simulations of extended surface regions by at the same time taking into account microstructure evolution and microstructure interaction. We apply this model successfully to extend the scaling relation for the step spacing given by the BCF theory [Phil. Trans. R. Soc. London, Ser. A 243, 299 (1951)] to microstructure evolution governed by heat and solute diffusion. Further applications to understand the mechanisms and consequences of spiral interaction at epitaxial surfaces, in particular the resulting morphology transitions, are discussed.     

Theoretical and experimental research on the self‐assembled system of molecularly imprinted polymers formed by salbutamol and methacrylic acid

The quantum chemical method was applied for screening functional monomers in the rational design of salbutamol‐imprinted polymers. Salbutamol was the template molecule, and methacrylic acid was the single functional monomer. The LC‐WPBE/6–31G(d,p) method was used to investigate the geometry optimization, active sites, natural bond orbital charges, binding energies of the imprinted molecule, and solvation energy. The mechanism of action between salbutamol and methacrylic acid was also discussed. The theoretical results show that salbutamol interacts with functional monomers by hydrogen bonds, and the salbutamol‐imprinted polymers with a ratio of 1:4 (salbutamol/methacrylic acid) in acetonitrile had the highest stability. The salbutamol‐imprinted polymers were prepared by precipitation polymerization. The experimental results indicated that the maximum adsorption capacity for salbutamol toward molecularly imprinted polymers was 7.33 mg/g, and the molecularly imprinted polymers had a higher selectivity for salbutamol than for norepinephrine and terbutaline sulfate. Herein, the studies can provide theoretical and experimental references for the salbutamol molecular imprinted system.     

Direct and Short Construction of the ACDE Ring System of Daphenylline

Daphenylline, a novel daphniphyllum alkaloid, boasts a fused and bridging ring system coupled with six stereogenic centers. Here we present a direct and short construction of the ACDE ring system of daphenylline from the known 3‐(2‐bromophenyl)propanal in 10 steps and 17 % overall yield. The synthesis features an iron(III)‐catalyzed aza‐Cope‐Mannich reaction, a self‐terminating 6‐exo‐trig aryl radical‐alkene cyclization and an intramolecular Friedel–Crafts acylation.     

Shock Tube Measurements of the Rate Constant of the Reaction NCN + O2

The rate constant of the comparably slow bimolecular NCN radical reaction NCN + O₂ has been measured for the first time under combustion relevant conditions using the shock tube method. The thermal decomposition of cyanogen azide (NCN₃) served as a clean high‐temperature source of NCN radicals. NCN concentration–time profiles have been detected by narrow‐bandwidth laser absorption at cm^?1. The experiments behind incident shock waves have been performed with up to 17% O₂ in the reaction gas mixture. At such high O₂ mole fractions, it was necessary to take O₂ relaxation into account that caused a gradual decrease of the temperature during the experiment. Moreover, following fast decomposition of NCN₃ and collision‐induced intersystem crossing of the initially formed singlet NCN to its triplet ground state, an unexpected and slow additional formation of triplet NCN has been observed on a 100‐μs timescale. This delayed NCN formation was attributed to a fast recombination of ¹NCN with O₂ forming a ³NCNOO adduct acting as a reservoir species for NCN. Rate constant data for the reaction NCN + O₂ have been measured at temperatures between 1674 and 2308 K. They are best represented by the Arrhenius expression . No pressure dependence has been observed at pressures between 216 and 706 mbar.     

Structure Modification Function of g‐C3N4 for Al2O3 in the In Situ Hydrothermal Process for Enhanced Photocatalytic Activity

Heterojunctions of g‐C₃N₄/Al₂O₃ (g‐C₃N₄=graphitic carbon nitride) are constructed by an in situ one‐pot hydrothermal route based on the development of photoactive γ‐Al₂O₃ semiconductor with a mesoporous structure and a high surface area (188 m²g^?1) acting as electron acceptor. A structure modification function of g‐C₃N₄ for Al₂O₃ in the hydrothermal process is found, which can be attributed to the coordination between unoccupied orbitals of the Al ions and lone‐pair electrons of the N atoms. The as‐synthesized heterojunctions exhibit much higher photocatalytic activity than pure g‐C₃N₄. The hydrogen generation rate and the reaction rate constant for the degradation of methyl orange over 50 % g‐C₃N₄/Al₂O₃ under visible‐light irradiation (λ>420 nm) are 2.5 and 7.3 times, respectively, higher than those over pristine g‐C₃N₄. The enhanced activity of the heterojunctions is attributed to their large specific surface areas, their close contact, and the high interfacial areas between the components as well as their excellent adsorption performance, and efficient charge transfer ability.     

考虑破坏时复合材料结构的分析

本文考虑复合材料结构发生局部破坏时的分析问题,这是一个非线性问题。本文引入带步长限制的变步长增量载荷方案作为解决这一问题的工程途径。用有限元法作为结构分析的基本手段。经试验结果对比,初步表明该方案是可行的。     

Structures of the twisted N = 1 Schrödinger–Neveu–Schwarz algebra

In this paper, we determine the universal central extension, derivation algebra and automorphism group of the twisted N = 1 Schrödinger–Neveu–Schwarz algebra. Furthermore, we generalize these results to the generalized twisted N = 1 Schrödinger–Neveu–Schwarz algebra in the final section.