首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   28293篇
  免费   4970篇
  国内免费   3016篇
化学   19545篇
晶体学   264篇
力学   1697篇
综合类   187篇
数学   2998篇
物理学   11588篇
  2024年   115篇
  2023年   639篇
  2022年   1038篇
  2021年   1146篇
  2020年   1137篇
  2019年   1147篇
  2018年   1007篇
  2017年   916篇
  2016年   1405篇
  2015年   1357篇
  2014年   1578篇
  2013年   2042篇
  2012年   2508篇
  2011年   2490篇
  2010年   1669篇
  2009年   1623篇
  2008年   1735篇
  2007年   1571篇
  2006年   1438篇
  2005年   1266篇
  2004年   938篇
  2003年   781篇
  2002年   757篇
  2001年   598篇
  2000年   570篇
  1999年   624篇
  1998年   548篇
  1997年   522篇
  1996年   458篇
  1995年   459篇
  1994年   379篇
  1993年   316篇
  1992年   255篇
  1991年   217篇
  1990年   245篇
  1989年   174篇
  1988年   119篇
  1987年   87篇
  1986年   94篇
  1985年   79篇
  1984年   47篇
  1983年   51篇
  1982年   42篇
  1981年   25篇
  1980年   20篇
  1979年   5篇
  1978年   4篇
  1977年   4篇
  1957年   5篇
  1916年   3篇
排序方式: 共有10000条查询结果,搜索用时 8 毫秒
51.
Indirect and direct boundary integral equations equivalent to the original boundary value problem of differential equation of plane elasticity are established rigorously. The unnecessity or deficiency of some customary boundary integral equations is indicated by examples and numerical comparison.  相似文献   
52.
In this paper the sufficient conditions for the existence of positive solutions of the neutral difference equations with positive and negative coefficients are established. The results improve some known conclusions in the literature  相似文献   
53.
In the reversible addition–fragmentation transfer (RAFT) copolymerization of two monomers, even with the simple terminal model, there are two kinds of macroradical and two kinds of polymeric RAFT agent with different R groups. Because the structure of the R group could exert a significant influence on the RAFT process, RAFT copolymerization may behave differently from RAFT homopolymerization. The RAFT copolymerization of methyl methacrylate (MMA) and styrene (St) in miniemulsion was investigated. The performance of the RAFT copolymerization of MMA/St in miniemulsion was found to be dependent on the feed monomer compositions. When St is dominant in the feed monomer composition, RAFT copolymerization is well controlled in the whole range of monomer conversion. However, when MMA is dominant, RAFT copolymerization may be, in some cases, out of control in the late stage of copolymerization, and characterized by a fast increase in the polydispersity index (PDI). The RAFT process was found to have little influence on composition evolution during copolymerization. The synthesis of the well‐defined gradient copolymers and poly[St‐b‐(St‐co‐MMA)] block copolymer by RAFT miniemulsion copolymerization was also demonstrated. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 6248–6258, 2004  相似文献   
54.
In this note,we develop,without assuming the Haar condition,a generalized simultaneousChebyshev approximation theory which is similar to the classical Chebyshev theory and con-rains it as a special case.Our results also contain those in[1]and[3]as a special case,and thetwo conjectures proposed by C.B.Dunham in[2]are proved to be true in the case of simulta-neous approximation.  相似文献   
55.
有序分组资料的线性趋势检验主要用于检验几个二项总体反应率的线性趋势;在医学与生物学中最典型的用途是研究剂量和反应的关系. 如果用Z检验来代替通常在本检验中所用的卡方检验,就可容易地导出本检验的确切概率计算方法,和其他2×C有序列联表有着相同的形式.本文给出了该检验的确切概率计算方法.  相似文献   
56.
57.
Fuzzy集的基数   总被引:6,自引:0,他引:6  
关于Fuzzy集的基数,[1]中曾对有限支集的Fuzzy集以及极苛刻条件下的无限Fuzzy集给出过一种定义。但是,正如本文将要指出的那样,该定义是不合理的。本文将从研究Fuzzy映射入手,给出Fuzzy集基数的一般性定义。基于这一定义,不但得到有关基数的大部分结论,而且有其自身的特殊性。  相似文献   
58.
In this paper, we simulate a practical in vivo technique in which is produced influence of turbid medium parameters on backscattered intensity and pulsewidth of picosecond for turbid tissue surface of a semiinfinite medium by a small narrow linewidth laser beams. It is shown that the interaction of the ultra short pulse and the turbid tissue is very used as researching the optical parameters of the turbid medium.  相似文献   
59.
The crystallization behavior of miscible syndiotactic polystyrene (sPS) and atactic polystyrene (aPS) blends with different sPS/aPS weight ratios was investigated in supercritical CO2 by using Fourier‐transform infrared spectroscopy, differential scanning calorimetry, and wide‐angle X‐ray diffraction. Supercritical CO2 and aPS exhibited different effects on the conformational change of sPS and competed with each other. Increasing the content of amorphous aPS in the blends made its effect on the conformational change of sPS gradually surpass that of supercritical CO2. Supercritical CO2 favored the formation of the helical conformation of sPS in lower temperature range and the all trans planar conformation in higher temperature range, instead of forming the latter one only in higher temperature range in ambient atmosphere. However, increasing aPS content in the blends pushed the range for forming the helical conformation to lower temperature and made the all trans planar conformation dominant in aPS/sPS 25/75 blend after treating in supercritical CO2 above 60 °C. The all trans planar zigzag conformation was more favorable than the helical conformation after mixing aPS in sPS in supercritical CO2. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1755–1764, 2007  相似文献   
60.
A combination of nitroxide‐mediated radical polymerization and living anionic polymerization was used to synthesize a series of well‐defined graft (co)polymers with “V‐shaped” and “Y‐shaped” branches. The polymer main chain is a copolymer of styrene and p‐chloromethylstyrene (PS‐co‐PCMS) prepared via nitroxide‐mediated radical polymerization. The V‐shaped branches were prepared through coupling reaction of polystyrene macromonomer, carrying 1,1‐diphenylethylene terminus, with polystyryllithium or polyisoprenyllithium. The Y‐shaped branches were prepared throughfurther polymerization initiated by the V‐shaped anions. The obtained branches, carrying a living anion at the middle (V‐shaped) or at the end of the third segment (Y‐shaped), were coupled in situ with pendent benzyl chloride of PS‐co‐PCMS to form the target graft (co)polymers. The purified graft (co)polymers were analyzed by size exclusion chromatography equipped with a multiangle light scattering detector and a viscometer. The result shows that the viscosities and radii of gyration of the branched polymers are remarkably smaller than those of linear polystyrene. In addition, V‐shaped product adopts a more compact conformation in dilute solution than the Y‐shaped analogy. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4013–4025, 2007  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号