NEW POLY(METHACRYLATE)S CONTAINING OXIME ESTERS MOIETIES BASED ON CYCLOHEXANON AND CYCLOPENTANON

The synthesis of two new methacrylates such as 2-[(cyclohexylideneamino)oxy]-2-oxoethyl methylacrylate (CHOEMA)and 2-[(cyclopentylideneamino)oxy]-2-oxoethyl methylacrylate(CPOEMA)are described.The monomers produced from the reaction of corresponding cyclohexanone O-(2-chloroacetyl)oxime and cyclopentanone O-(2- chloroacetyl)oxime with sodium methacrylate was polymerized in 1,4-dioxane solution at 65℃using AIBN as an initiator. The monomers and their polymers were characterized by IR,~1H- and ~(13)C-NMR s...     

Effective-field theory with the differential operator technique for a kinetic Blume–Capel model with random diluted single-ion anisotropy

We present the dynamical phase diagrams of the kinetic Blume–Capel model with random diluted single-ion anisotropy in a square lattice under the presence of a time-varying (oscillating) external magnetic field calculated by an analytical method, the effective-field theory (EFT). The kinetics is modeled with the formalism of a master equation. The time-averaged magnetization (M$M$) acts as the order parameter and divides the temperature–field plane into three regions: ferromagnetic, paramagnetic, and coexistence of ferromagnetic and paramagnetic phases. In addition, the hysteresis loop area and the dynamic correlation function are calculated. It is observed that the inclusion of spin–spin correlations suppress the first-order transition lines and dynamical tricritical points for all values of the crystal-field concentration.     

Effective field investigation of dynamic phase transitions for site diluted Ising ferromagnets driven by a periodically oscillating magnetic field

Dynamic behavior of a site diluted Ising ferromagnet in the presence of a periodically oscillating magnetic field has been analyzed by means of the effective field theory (EFT). The dynamic equation of motion has been solved for a honeycomb lattice (z=3$z=3$) with the help of a Glauber type stochastic process. The global phase diagrams and the variation of the corresponding dynamic order parameter as a function of the Hamiltonian parameters and temperature has been investigated in detail and it has been shown that the system exhibits reentrant phenomena, as well as a dynamic tricritical point which disappears for sufficiently weak dilution.     

Effects of the Quenched Random Crystal Field on the Dynamic Spin-1 Blume-Capel Model

In this study, we have analyzed the dynamical phase transitions of spin-1 Blume-Capel model with quenched random crystal field under the effect of a time dependent oscillating magnetic field. We have obtained the magnetic field, temperature (h,T) cross sections of the global phase diagram for constant values of the concentration and the amplitude of the single-ion anisotropy within mean field approximation. There are regions of the phase space where both ordered and disordered phases coexist. In addition, the dynamic phase transition from one regime to the other can be a first- or a second-order depending on the region in the phase diagram. Hence, the system exhibits a number of interesting phenomena and a rich variety of phase diagrams with type being according to the concentration p of active local crystal fields.     

The impact of [1,2,5]chalcogenazolo[3,4-f]-benzo[1,2,3]triazole structure on the optoelectronic properties of conjugated polymers

Two novel conjugated near-infrared (NIR) absorbing donor–acceptor type copolymers comprising benzodithiophene as the donor and [1,2,5]chalcogenazolo[3,4-f]-benzo[1,2,3]triazole derivatives as the acceptors, spaced with thiophene as the π-bridge, were designed and synthesized via Stille polycondensation reaction. The effect of acceptor strength on optoelectronic properties was targeted and investigated. Branched alkyl chains (the extended 2-octyl-1-dodecyl alkyl chain;  C₈C₁₂) were introduced to 5H-[1,2,3]triazolo[4′,5′:4,5]benzo[1,2-c][1,2,5]thiadiazole and 5H-[1,2,3]triazolo[4′,5′:4,5]benzo[1,2-c][1,2,5]selenadiazole for enhanced solubility of polymers which ease the processability hence device constructions. The strongly electron-withdrawing units lead to a substantial change in the absorption properties via promotion of the intramolecular charge transfer band alongside the π–π* transition. The resultant soluble polymers were characterized via cyclic voltammetry to determine highest occupied molecular orbital and lowest unoccupied molecular orbital energy levels as −5.00 and −3.92 eV for PSBT and −4.86 and −4.04 eV for PSeBT, respectively. Electronic band gaps of the copolymers were calculated as 1.08 eV for PSBT and 0.82 eV for PSeBT, respectively. NIR absorbing copolymers were used to construct electrochromic devices.