Characterization of the carrot defect in 4H-SiC epitaxial layers

Characterization of the epitaxial defect known as the carrot defect was performed in thick 4H-SiC epilayers. A large number of carrot defects have been studied using different experimental techniques such as Nomarski optical microscopy, KOH etching, cathodoluminescence and synchrotron white beam X-ray topography. This has revealed that carrot defects appear in many different shapes and structures in the epilayers. Our results support the previous assignment of the carrot defect as related to a prismatic stacking fault. However, we have observed carrot defects with and without a visible threading dislocation related etch pit in the head region, after KOH etching. Polishing of epilayers in a few μm steps in combination with etching in molten KOH and imaging using Nomarski optical microscope has been used to find the geometry and origin of the carrot defects in different epilayers. The defects were found to originate both at the epi-substrate interface and during the epitaxial growth. Different sources of the carrot defect have been observed at the epi-substrate interface, which result in different structures and surfaces appearance of the defect in the epilayer. Furthermore, termination of the carrot defect inside the epilayer and the influence of substrate surface damage and growth conditions on the density of carrot defects are studied.     

New Coordination Polymers of 1,4-Bis(2″-Hydroxyphenylazomethine) Phenylene

Coordination polymers of 1,4-bis(2′-hydroxyphenylazomethine) phenylene have been prepared with the metal ions Ti(III), Cr(III), Fe(III), Mn(II), Ni(II), and Cu(II). They were characterized by elemental analysis, IR, and electronic spectra. The metal contents in all polymers were found to be consistent with a 1:1 (metal:ligand) stoichiometry. The thermal behavior of these coordination polymers has been studied by thermogravimetric analysis in air up to 750°C, and the data showed that they are thermally stable up to 200°C. Physical properties such as the solubility and viscosity of the polymer complexes were also determined. Electrical conductivity measurements of the synthesized polychelated polymers showed that they are insulators except for the Ni(II) complex which shows a semiconducting character. Mössbauer data clearly establish the 3 + oxidation state for the iron complex polymer.     

Silica aerogel–iron oxide nanocomposites: recoverable catalysts for the oxidation of alcohols with hydrogen peroxide

Various aerogels of silica gel doped with Fe₂O₃ were prepared by sol–gel method. They were calcined to produce nanoparticle solids. The nanosized mixed oxides were active in the oxidation of alcohols and produced carbonyl compounds in very good to excellent yields using hydrogen peroxide.     

Simple Stereoselective HPLC Method for Studying the Isomerisation of Cefditoren Pivoxil and Its Isomeric Purity in Pharmaceuticals

A new rapid, simple and stereoselective HPLC method for studying the isomerisation of cefditoren pivoxil in bulk and its isomeric purity in dosage form was developed and validated. This kind of isomerisation could form due to the effect of temperature on analyte during the manufacturing process or improper storage of pharmaceutical formulations. The separation between cefditoren pivoxil and cefditoren ∆3 isomer was obtained with resolution not less than 2.00 in the presence of methanol and phosphate buffer at pH 5.20 (70:30, v:v) onto Luna C18 stationary phase within 15 min analysis time. Under the validated stereoselective HPLC conditions, isomeric purity of cefditoren pivoxil was successfully determined in tablets with inter and intra-days relative standard deviation ≤4.6 %.

     

Empirical correlation study of dryout heat transfer at high pressure using high order neural network and feed forward neural network

A hybrid high order neural network (HHONN) and a feed forward neural network (FNN) are developed and applied to find an optimized empirical correlation for prediction of dryout (DO) heat transfer. The values predicted by the HHONN and FNN models are compared with each other and also with the previous values of empirical correlation. HONN successfully provides an efficient open-box model of nonlinear input–output mapping which provides easier understanding of data mining. By removing the hidden layers, HONN structures become simpler than FNNs and initialization of learning parameters (weights) will not be catastrophic. The RMS results show that the HHONN model has superior fitting specification for prediction of DO heat transfer problem compared to the other prediction methods.     

Combined electroosmotically and pressure driven flow of power-law fluids in a slit microchannel

Electroosmotic flow of power-law fluids in the presence of pressure gradient through a slit is analyzed. After numerically solving the Poisson–Boltzmann equation, the momentum equation with electroosmotic body force is solved through an iterative numerical procedure for both favorable and adverse pressure gradients. The results reveal that, in case of pressure assisted flow, shear-thinning fluids reach higher velocity magnitudes compared with shear-thickening fluids, whereas the opposite is true when an adverse pressure gradient is applied. The Poiseuille number is found to be an increasing function of the dimensionless Debye–Hückel parameter, the wall zeta potential, and the flow behavior index. Comparison between the exact and the results based on the Debye–Hückel linearization reveals that the simplified solution leads to large errors in evaluating the velocity profile for zeta potentials higher than 25 mV, except for shear-thickening fluids in the presence of favorable pressure gradient.     

Non-oscillating/Oscillating Shear Layer over a Large Deep Cavity at Low-Subsonic Speeds

The flow over a deep cavity at low subsonic velocity is considered in the present paper. The cavity length-to-depth aspect ratio is L/H = 0.2. Single hot-wire measurements characterized the incident turbulent boundary layer and show the influence of the cavity on the streamwise statistic components just downstream from the cavity. The streamwise mean and fluctuating velocity profiles are affected by the cavity. PIV measurements reveal the presence for ejection-like events responsible of local perturbations of the skewness and the flatness coefficients. Time-resolved PIV technic is also used to characterize phase properties of shear layer oscillating cycle. It is shown that for deep cavity with first Rossiter mode, only one vortical structure is formed at the cavity leading edge. Then, it grows while convecting downstream along the shear layer. A well-defined ejection process begins after the vortex impact near the cavity downstream corner. A cylinder device placed spanwisely near the cavity leading edge eliminates the resonance and highly modifies the behavior of the shear layer flow. In fact, the shear layer could be divided into upper and lower parts with different structure aspects.     

Analysis of shock wave reflection from fixed and moving boundaries using a stabilized particle method

In the present paper, the efficiency of an enhanced formulation of the stabilized corrective smoothed particle method （CSPM） for simulation of shock wave propagation and reflection from fixed and moving solid boundaries in compressible fluids is investigated. The Lagrangian nature and its accuracy for imposing the boundary conditions are the two main reasons for adoption of CSPM. The governing equations are further modified for imposition of moving solid boundary conditions. In addition to the traditional artificial viscosity, which can remove numerically induced abnormal jumps in the field values, a velocity field smoothing technique is introduced as an efficient method for stabilizing the solution. The method has been implemented for one- and two-dimensional shock wave propagation and reflection from fixed and moving boundaries and the results have been compared with other available solutions. The method has also been adopted for simulation of shock wave propagation and reflection from infinite and finite solid boundaries.