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91.
Ki Mann Jee Dong Chul Park 《International Journal of Infrared and Millimeter Waves》2003,24(12):2105-2117
A spurious-suppressed transversal filter using the multiple-coupled line is proposed. The frequency characteristics of the multiple-coupled line are analyzed in detail. In order to compare the performances, the novel spurious-suppressed transversal filter using triple-coupled half-wavelength directional couplers is designed at 30 GHz. The spurious-suppression characteristics of the proposed transversal filter are verified by the full wave analysis and the measurement. The spurious response of the fabricated filter is effectively suppressed and the large attenuation is obtained in the stopband. 相似文献
92.
We apply the theory of signature invariants of links in rational homology spheres to covering links of homology boundary links. From patterns and Seifert matrices of homology boundary links, we derive an explicit formula to compute signature invariants of their covering links. Using the formula, we produce fused boundary links that are positive mutants of ribbon links but are not concordant to boundary links. We also show that for any finite collection of patterns, there are homology boundary links that are not concordant to any homology boundary links admitting a pattern in the collection.
93.
Ki Byung Sunwoo Seung Joon Park Seong Jae Lee Kyung Hyun Ahn Seung Jong Lee 《Rheologica Acta》2002,41(1-2):144-153
Three-dimensional numerical simulation of viscoelastic coextrusion process has been performed and numerical results were
compared with the experimental data of Karagiannis et al. (1990). By varying the magnitude of the second normal stress difference
and its ratio of Fluid I and Fluid II, we were able to control the interface profile and the degree of encapsulation along
the downstream direction. By increasing the parameter α (αFluid I=αFluid II) from 0.1 to 0.4 in the Giesekus model and increasing the α ratio (αFluid IαFluid II) between Fluid I and Fluid II from 2.0 to 4.0 in the permissible range of realistic polymeric systems, the interface profile
and the degree of encapsulation along the downstream direction were fitted with the experimental results. There was little
difference between the numerical results and the experimental data in the interface profile and the degree of encapsulation
along the downstream direction when the α ratio was set to 3.0 (0.3:0.1). Fluid I with larger magnitude of the second normal
stress difference protrudes into Fluid II with smaller magnitude of the second normal stress difference around the symmetric
plane, while Fluid II wraps around Fluid I near the side walls. As the ξ
1
ratio (ξ
1
,Fluid Iξ
1
,Fluid II) increases from 1.0 to 3.0 for the two-mode Phan-Thien and Tanner model, it was found that the curvature of the interface
profile increased, and the difference between the numerical results and the experimental data in the interface profile and
the degree of encapsulation along the downstream direction was almost negligible when the ξ
1
ratio was set to 3.0 (0.54:0.18). Although the parameters of viscoelastic models were fitted by using the shear viscosity
data only, quantitative agreements between the numerical results and the experimental coextrusion data were quite satisfactory.
Received: 24 April 2001 Accepted: 5 June 2001 相似文献
94.
Anchoring Mechanism of ZnO Nanoparticles on Graphitic Carbon Nanofiber Surfaces through a Modified Co‐Precipitation Method to Improve Interfacial Contact and Photocatalytic Performance
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Dr. Gowra Raghupathy Dillip Dr. Arghya Narayan Banerjee Dr. Veettikunnu Chandran Anitha Dr. Sang Woo Joo Dr. Bong Ki Min Dr. Sandesh Y. Sawant Dr. Moo Hwan Cho 《Chemphyschem》2015,16(15):3214-3232
A facile three‐step co‐precipitation method is developed to synthesize graphitic carbon nanofibers (CNFs) decorated with ZnO nanoparticles (NPs). By interchanging intermediate steps of the reaction processes, two kinds of nanohybrids are fabricated with stark morphological and physicochemical differences. The morphologies differ because of the different chemical environments of the NP/nanocluster formation. The hybrid with larger and non‐uniform ZnO nanocluster size is formed in liquid phase and resulted in considerable interfacial defects that deteriorate the charge‐transfer properties. The hybrid with smaller and uniform ZnO NPs was formed in a dry solid phase and produced near‐defect‐free interfaces, leading to efficient charge transfer for superior photocatalytic performance. The results broaden the understanding of the anchoring/bonding mechanism in ZnO/CNF hybrid formation and may facilitate further development of more effective exfoliation strategies for the preparation of high‐performance composites/hybrids. 相似文献
95.
Back Cover: Cofactor‐Free Light‐Driven Whole‐Cell Cytochrome P450 Catalysis (Angew. Chem. Int. Ed. 3/2015)
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96.
Rücktitelbild: Cofactor‐Free Light‐Driven Whole‐Cell Cytochrome P450 Catalysis (Angew. Chem. 3/2015)
97.
Won Se Suh Ki Hyun Kim Ho Kyung Kim Sang Un Choi Kang Ro Lee 《Helvetica chimica acta》2015,98(8):1087-1094
Two new aryl‐tetralin lignan glycosides, linderanosides A and B ( 1 and 2 , resp.), and a new dihydrobenzofuran neolignan glycoside, linderanoside C ( 3 ), together with five known lignan derivatives ( 4 – 8 ) were isolated from the trunk of Lindera glauca. The structures of these new compounds were determined through spectroscopic analyses, including extensive 2D‐NMR data and acid hydrolysis. The absolute configurations of the compounds were clarified by circular dichroism (CD) spectroscopic studies. Compounds 1 – 8 were evaluated for their cytotoxicity against A549 (non‐small cell lung adenocarcinoma), SK‐OV‐3 (ovarian cancer cells), A498 (human kidney epithelial cells), and HCT‐15 (colon cancer cells) human tumor cell lines using sulforhodamine B assays in vitro. 相似文献
98.
Surface and Structural Investigation of a MnOx Birnessite‐Type Water Oxidation Catalyst Formed under Photocatalytic Conditions
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Benjamin J. Deibert Jingming Zhang Paul F. Smith Dr. Karena W. Chapman Dr. Sylvie Rangan Debasis Banerjee Kui Tan Hao Wang Nicholas Pasquale Prof. Feng Chen Prof. Ki‐Bum Lee Prof. G. Charles Dismukes Prof. Yves J. Chabal Prof. Jing Li 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(40):14218-14228
Catalytically active MnOx species have been reported to form in situ from various Mn‐complexes during electrocatalytic and solution‐based water oxidation when employing cerium(IV) ammonium ammonium nitrate (CAN) oxidant as a sacrificial reagent. The full structural characterization of these oxides may be complicated by the presence of support material and lack of a pure bulk phase. For the first time, we show that highly active MnOx catalysts form without supports in situ under photocatalytic conditions. Our most active 4MnOx catalyst (~0.84 mmol O2 mol Mn?1 s?1) forms from a Mn4O4 bearing a metal–organic framework. 4MnOx is characterized by pair distribution function analysis (PDF), Raman spectroscopy, and HR‐TEM as a disordered, layered Mn‐oxide with high surface area (216 m2g?1) and small regions of crystallinity and layer flexibility. In contrast, the SMnOx formed from Mn2+ salt gives an amorphous species of lower surface area (80 m2g?1) and lower activity (~0.15 mmol O2 mol Mn?1 s?1). We compare these catalysts to crystalline hexagonal birnessite, which activates under the same conditions. Full deconvolution of the XPS Mn2p3/2 core levels detects enriched Mn3+ and Mn2+ content on the surfaces, which indicates possible disproportionation/comproportionation surface equilibria. 相似文献
99.
Fluorescence Polarization Based Nucleic Acid Testing for Rapid and Cost‐Effective Diagnosis of Infectious Disease
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Dr. Ki Soo Park Prof. Richelle C. Charles Prof. Edward T. Ryan Prof. Ralph Weissleder Prof. Hakho Lee 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(46):16359-16363
A new nucleic acid detection method was developed for a rapid and cost‐effective diagnosis of infectious disease. This approach relies on the three unique elements: 1) detection probes that regulate DNA polymerase activity in response to the complementary target DNA; 2) universal reporters conjugated with a single fluorophore; and 3) fluorescence polarization (FP) detection. As a proof‐of‐concept, the assay was used to detect and sub‐type Salmonella bacteria with sensitivities down to a single bacterium in less than three hours. 相似文献
100.
Ki Dong Yang Woo Ri Ko Jun Ho Lee Prof. Sung Jae Kim Prof. Hyomin Lee Prof. Min Hyung Lee Prof. Ki Tae Nam 《Angewandte Chemie (International ed. in English)》2017,56(3):796-800
The electrocatalytic conversion of CO2 to value-added hydrocarbons is receiving significant attention as a promising way to close the broken carbon-cycle. While most metal catalysts produce C1 species, such as carbon monoxide and formate, the production of various hydrocarbons and alcohols comprising more than two carbons has been achieved using copper (Cu)-based catalysts only. Methods for producing specific C2 reduction outcomes with high selectivity, however, are not available thus far. Herein, the morphological effect of a Cu mesopore electrode on the selective production of C2 products, ethylene or ethane, is presented. Cu mesopore electrodes with precisely controlled pore widths and depths were prepared by using a thermal deposition process on anodized aluminum oxide. With this simple synthesis method, we demonstrated that C2 chemical selectivity can be tuned by systematically altering the morphology. Supported by computational simulations, we proved that nanomorphology can change the local pH and, additionally, retention time of key intermediates by confining the chemicals inside the pores. 相似文献