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排序方式: 共有231条查询结果,搜索用时 140 毫秒
21.
T. Ohshima A. Uedono K. Abe H. Itoh Y. Aoki M. Yoshikawa S. Tanigawa I. Nashiyama 《Applied Physics A: Materials Science & Processing》1998,67(4):407-412
Received: 18 February 1998/Accepted: 5 June 1998 相似文献
22.
M. Hashimoto S. Kanemitsu Y. Tanigawa M. Yoshimoto W. -P. Zhang 《Journal of Computational and Applied Mathematics》2003,160(1-2):113-123
We shall extract the essence of the Adamchik–Srivastava generating function method (Analysis (Munich) 18 (1998) 131) by proving the most far-reaching Ramanujan–Yoshimoto formula and by showing that some of the results stated in Srivastava and Choi (Series Associated with the Zeta and Related Functions, Kluwer Academic Publishers, Dordrecht, 2001) are simple consequences of the above-mentioned formula. 相似文献
23.
Issei Otsuka Ryosuke Sakai Toshifumi Satoh Ryohei Kakuchi Harumi Kaga Toyoji Kakuchi 《Journal of polymer science. Part A, Polymer chemistry》2005,43(23):5855-5863
A poly(phenylacetylene) bearing a polycarbohydrate ionophore as a graft chain (copolymer 4 ) was synthesized by the copolymerization of end‐functionalized (1→6)‐2,5‐anhydro‐3,4‐di‐O‐ethyl‐D ‐glucitol with a 4‐ethynylbenzoyl group (macromonomer 2 ) with phenylacetylene. Copolymer 4 showed a split‐type circular dichroism (CD) in the long absorption region of the conjugated polymer backbone (280–500 nm), and the CD pattern varied in response to external stimuli, such as the solvents and temperature. This suggested that 4 had a predominantly one‐handed helical conformation in the polyacetylene backbone. The CD pattern of 4 was completely inverted by the formation of a complex between the macromolecular ionophore units and the selected metal cations, that is, Ba2+, Pb2+, Sr2+, Na+, and Li+. This suggested that copolymer 4 underwent a helix–helix transition through the host–guest complexation with achiral inorganic metal cations. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 5855–5863, 2005 相似文献
24.
Yoshio Tanigawa Kazuaki Nishimura Akihiko Kawasaki Shun-Ichi Murahashi 《Tetrahedron letters》1982,23(52):5549-5552
Allyl diethyl phosphates (1) can be easily substituted with malonates and amines in the presence of palladium(O) catalyst. Synthetic utility of the reaction is demonstrated by the sequential amination-amination and alkylation-amination of (Z)-4-acetoxybut-2-enyl diethyl phosphate (1b) with high regio- and stereoselectivity. 相似文献
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27.
Kazuhiko Orito Harumi Kaga Mitsuomi Itoh S. Osmund De Silva Richard H. Manske Russel Rodrigo 《Journal of heterocyclic chemistry》1980,17(3):417-423
Aromatic methoxy and/or methylenedioxy substituted 7-methyltetrahydrobenz[d]indeno[1,2-b]-azepines 7 and their 12-oxo derivatives 8 were efficiently synthesized by the general method consisting of two types of intramolecular dehydrative cyclizations, as follows. N-Methyl-N-β-phenethylacetamides 1 were cyanomethylated in the two-step process of chloromethylation and treatment of the resultant benzyl chlorides with sodium cyanide. The condensation of the benzyl cyanides 2 with the appropriate benzaldehydes, followed by reduction of the benzylidene function, gave α,β-diphenylpropionitriles 3 . Successively, hydrolysis to the amino acids 4 and the thermal cyclization converted 3 to the benzylbenzazepinones 5 , which were also prepared by benzylation of the benzazepinones 6 smoothly by heating of 5 with phosphoryl chloride to afford the title azepines 7 . Further, these tetracyclic enamines 7 underwent autoxidation to the corresponding 12-oxo derivatives 8 , on exposure to oxygen in the presence of Triton B. 相似文献
28.
We shall investigate several properties of the integral $$ \int_1^\infty {t^{ - \theta } \Delta _k \left( t \right) log^j t dt} $$ with a natural number k, a non-negative integer j and a complex variable θ, where Δ k (x) is the error term in the divisor problem of Dirichlet and Piltz. The main purpose of this paper is to apply the “elementary methods” and the “elementary formulas” to derive convergence properties and explicit representations of this integral with respect to θ for k = 2. 相似文献
29.
Maruyama T Yamamura H Hiraki M Kemori Y Takata H Goto M 《Colloids and surfaces. B, Biointerfaces》2008,66(1):119-124
We investigated DNA-directed aggregation of vesicles using DNA-surfactants. Following tethering of single-stranded DNA oligonucleotides to vesicles using DNA-surfactant, the tethered vesicles were assembled with other vesicles bearing complementary strands. The vesicle aggregation was strongly affected by the salt concentration and by temperature according to the characteristics of DNA hybridization. Restriction enzyme, which can hydrolyze the double-stranded DNA used in the present study, dissociated the vesicle aggregates. Exploration using fluorescently labeled vesicles suggested that the DNA-directed vesicle aggregation took place in a sequence-specific manner through DNA-duplex formation. Interestingly, the DNA-directed aggregation using short DNA-surfactant induced the fusion of vesicles to produce giant vesicles, resulting in an enzymatic reaction in the giant vesicle. 相似文献
30.
Harumi Sato Rumi Murakami Jianming Zhang Katsuhito Mori Isao Takahashi Hikaru Terauchi Isao Noda Yukihiro Ozaki 《Macromolecular Symposia》2005,230(1):158-166
Infrared (IR) spectra and wide-angle X-ray diffraction (WAXD) patterns of poly(3-hydroxybutyrate) (PHB) and its copolyester, poly(3-hydroxybutyrate-co-3-hydroxyhexanoate), P(HB-co-HHx) (HHx = 12 mol%) were measured over a temperature range of 20 °C to higher temperatures (PHB, 185 °C, HHx = 12 mol%, 140 °C) to explore their structure change and thermal behavior and molecular interaction. The WAXD measurements revealed that the a lattice parameter increases significantly with temperature, while the b lattice parameter varies a little in the crystalline PHB and P(HB-co-HHx). It seems that the intermolecular interaction between the CO group of one helical structure and the CH3 group of the other helical structure decreases along the a axis of crystalline PHB and P(HB-co-HHx) with temperature. The temperature-dependent IR spectral variations were analyzed for the CH stretching, CO stretching, CH3 deformation, and C O C stretching variation regions, and bands characteristic of crystalline and amorphous parts were identified in each region. It was found from the anomalous frequencies of the CH3 asymmetric stretching and CO stretching bands of PHB and P(HB-co-HHx) and the X-ray crystallographic structure of PHB that there is an intermolecular interaction (C H…OC hydrogen bond) between the CO group and the CH3 group combining two helical structures in PHB and P(HB-co-HHx). In this review paper we discuss the role of the C H…OC hydrogen bonding and the crystal and lamella structure of PHB and P(HB-co-HHx) (HHx = 12 mol %) in comparison with the structure of Nylon. 相似文献