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221.
The retention behaviour of beta-lactam antibiotics in micellar electrokinetic chromatography (EKC) was investigated. Sodium dodecyl sulphate (SDS) and sodium N-lauroyl-N-methyltaurate were used an anionic surfactants at concentrations of 0.05-0.3 M. It was found that the retention of ionic substances in micellar EKC is determined by the following three factors: the electrophoretic migration of the ionic substances, the interaction between the ionic substances and ionic surfactants and solubilization of the solute by the micellar phase. A difference in the retention behaviours of cationic substances was observed between the two anionic surfactants, which have different groups neighbouring the charge-bearing groups. The effect of an ion-pairing reagent was also investigated to make the effect of the micelle clearer. All test solutes were successfully separated by micellar EKC at SDS concentrations above 0.1 M, with theoretical plate numbers ranging from 70,000 to 260,000. 相似文献
222.
Fluorescence intermittency in InP self-assembled dots is investigated by means of far field imaging and single dot spectroscopy. Based on our observation that blinking dots are found in the vicinity of scratches and the blinking frequency is drastically enhanced under a near-infrared laser irradiation, we attribute the origin of the fluorescence intermittency to a local electric field due to a carrier trapped at a deep localized center in the Ga0.5In0.5P matrix. The validity of this explanation is confirmed by a thermal activation-type behavior of the switching rate and artificial reproduction of the blinking phenomenon by an external electric field. 相似文献
223.
The invention of atomic force microscopy (AFM) enabled us to study the statistical properties of single polymer chains by a method called "nanofishing," which stretches a single polymer chain adsorbed on a substrate with its one end by picking it at the other end. A force-extension curve obtained for a single polystyrene chain in a Theta solvent (cyclohexane) shows good agreement with a worm-like chain model and, therefore, gives microscopic information about entropic elasticity. Furthermore, the nanofishing technique can be used for dynamic viscoelastic measurement of single polymer chains. An AFM cantilever is mechanically oscillated at its resonant frequency during the stretching process. This technique enables the estimation of quantitative and simultaneous elongation-dependent changes of stiffness and viscosity of a single chain with the use of a phenomenological model. In this study, the effect of solvent on viscosity in low extension regions reveals that the viscosity is attributed to monomer-solvent friction. Thus, static and dynamic nanofishing techniques are shown to give powerful experimental proofs for several basic questions in polymer physics. The techniques are expected to reveal hidden properties of polymer chains or polymer solutions by any types of macroscopic measurements in the future. 相似文献
224.
Catalytic Enantioselective Reaction of α‐Aminoacetonitriles Using Chiral Bis(imidazoline) Palladium Catalysts 下载免费PDF全文
Masaru Kondo Tomoki Nishi Prof. Dr. Tsubasa Hatanaka Prof. Dr. Yasuhiro Funahashi Prof. Dr. Shuichi Nakamura 《Angewandte Chemie (International ed. in English)》2015,54(28):8198-8202
The catalytic enantioselective reaction of diphenylmethylidene‐protected α‐aminoacetonitriles with imines has been developed. Good yields and diastereo‐ and enantioselectivities were observed for the reaction of various imines using chiral bis(imidazoline)/Pd catalysts. The reaction of α‐aminonitriles with di‐tert‐butyl azodicarboxylate afforded chiral α,α‐diaminonitriles in high yields with high enantioselectivities. 相似文献
225.
Optical Review - In this study, we present a new method for measuring the tilt of an image sensor to the lens. The assembly accuracy of the lens and image sensor units has a significant influence... 相似文献
226.
Kasahara T Nishi N Yamamoto M Kakiuchi T 《Langmuir : the ACS journal of surfaces and colloids》2004,20(3):875-881
The electrochemical instability has been shown to appear in the transfer of cationic surfactant ions across the 1,2-dichloroethane/water interface. Cyclic voltammograms possess all fundamental characteristics that are predicted by the theory of electrochemical instability: the presence of the instability window, that is, the potential range where the interface becomes unstable, the location of the instability window around the standard ion transfer potential of surface-active ions, and the dependence of the width of the instability window on the concentration of the surfactant ions. Electrocapillary measurements clearly demonstrate that the interface becomes unstable, while the interfacial tension is positive, being higher than 20 mN m(-1). The electrocapillary curve exhibits the discontinuities at both ends of the instability window, indicating the similarity between the electrochemical instability and the phase transitions induced by the temperature, pressure, and chemical potential. The results from voltammetry and interfacial tension measurements for cationic surfactants support the idea that the electrochemical instability, so far reported in the transfer of anionic surfactants across the liquid/liquid interface, is one of intrinsic properties of the two-phase systems where the partition of surface-active ions takes place. 相似文献
227.
228.
Ochiai M Nishi Y Goto S Frohn HJ 《Angewandte Chemie (International ed. in English)》2005,44(3):406-409
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230.
In the present work, nanoparticles of previously synthesized 3a derivatives of vanillic acid were synthesized by the nanoprecipitation method. Nanoparticles were further characterized by UV–vis spectroscopy, FTIR spectroscopy, SEM analysis, XRD and zeta sizer. Diabetes was instigated in Wistar albino rats by intraperitoneal (I.P.) administration of Streptozotocin (60 ?mg/kg body weight). Vanillic acid (100 ?mg/kg), 3a (100 ?mg/kg) and 3aNPs (50 ?mg/kg) body weight were given orally for a period of 21 days. Blood glucose level and biochemical parameters such as cholesterol, triglycerides, LDL, HDL, VLDL and antioxidant parameters were assessed by using diagnostic kits. SEM analysis and PDI of 3aNPs was found to be 0.2 which indicate monodisperse distribution. Significant decline in blood glucose level (p ?< ?0.001) was observed in antidiabetic studies along with the lipid lowering and antioxidant effect in dose-dependent manner. The noted results of the study showed that nanoparticles were found to be effective in treating diabetes. 相似文献