Zur Unterscheidung von prim?ren, sekund?ren und terti?ren Aminen

Ohne Zusammenfassung     

A characterization of the scattered acoustic intensity field in the resonance region for simple spheres

The properties of the scattered acoustic vector fields generated by simple spheres illuminated by monotonic continuous wave (CW) plane waves are investigated. Analytical solutions are derived from general acoustic pressure scattering models and analyzed for wave numbers in the resonance region. Of particular interest is the understanding of the characteristics of the scattered acoustic vector field in the near-to-far-field transition region. The separable active and reactive components of the acoustic intensity are used to investigate the structural features of the scattered field components. Numerical results are presented for the near and transition regions for a rigid sphere. A method of mapping nulls in the scattered intensity field components is described. The analysis is then extended to include a simple fluid-filled boundary and finally the evacuated thin-walled shell. Near field acoustic intensity field structures are compared against mechanical material properties of vacuous shells. The ability to extract scattered field features is illustrated with measurements obtained from a recent in-air experiment using an anechoic chamber and acoustic vector sensor probes to measure the scattered acoustic vector field from rigid spheres.     

Gauge symmetry breaking in matrix models

We argue that some features of the standard model, in particular the fermion assignment and symmetry breaking, can be obtained in matrix model which describes noncommutative gauge theory as well as gravity in an emergent way. The mechanism is based on the presence of some extra (matrix) dimensions. These extra dimensions are different from the usual ones which give to a noncommutative geometry of the Grönewold-Moyal type, and are reminiscent of the Connes-Lott model, although the action is very different.     

Knudsen gas provides nanobubble stability

We provide a model for the remarkable stability of surface nanobubbles to bulk dissolution. The key to the solution is that the gas in a nanobubble is of Knudsen type. This leads to the generation of a bulk liquid flow which effectively forces the diffusive gas to remain local. Our model predicts the presence of a vertical water jet immediately above a nanobubble, with an estimated speed of ～3.3 m/s, in good agreement with our experimental atomic force microscopy measurement of ～2.7 m/s. In addition, our model also predicts an upper bound for the size of nanobubbles, which is consistent with the available experimental data.     

Fuel spray visualization and its impingement analysis on in-cylinder surfaces in a direct-injection spark-ignition engine

Abstract  

Experiments are performed to investigate the effects of fuel spray on in-cylinder mixture preparation and its impingement on cylinder walls and piston top inside a direct-injection spark-ignition engine with optical access to the cylinder. Novel image processing algorithms are developed to analyze the fuel impingement quantitatively on in-cylinder surfaces. The technique is useful to optimize the fuel pressure, injection timing and the number of injections to minimize the fuel impingement on in-cylinder surfaces. E85, which represents a blend of 85% ethanol and 15% gasoline (by volume) is used in this study. Two types of fuel injectors are used; (i) low-pressure production-intent injector with fuel pressure of 3 MPa, and (ii) high-pressure production injector with fuel pressures of 5 and 10 MPa. In addition, the effects of split injection are also presented by maintaining the same amount of fuel used in single injection. It is found that the split injection is an effective way to reduce the overall fuel impingement on in-cylinder surfaces while maintaining a reasonably good air–fuel mixture in the cylinder.     

Advances towards using finger/toenail dosimetry to triage a large population after potential exposure to ionizing radiation

Rapid and accurate retrospective dosimetry is of critical importance and strategic value for the emergency medical response to a large-scale radiological/nuclear event. One technique that has the potential for rapid and accurate dosimetry measurements is electron paramagnetic resonance (EPR) spectroscopy of relatively stable radiation-induced signals (RIS) in fingernails and toenails. Two approaches are being developed for EPR nail dosimetry. In the approach using ex vivo measurements on nail clippings, accurate estimation of the dose-dependent amplitude of the RIS is complicated by the presence of mechanically-induced signals (MIS) that are generated during the nail clipping. Recent developments in ex vivo nail dosimetry, including a thorough characterization of the MIS and an appreciation of the role of hydration and the development of effective analytic techniques, have led to improvements in the accuracy and precision of this approach. An in vivo nail dosimetry approach is also very promising, as it eliminates the problems of MIS from the clipping and it has the potential to be an effective and efficient approach for field deployment. Two types of EPR resonators are being developed for in vivo measurements of fingernails and toenails.