Chinalizarin zum qualitativen Nachweis von Nitrat

Ohne ZusammenfassungVerff. danken der Deutschen Forschungsgemeinchaft und dem Fonds der chemischen Industrei für Förderung ihrer Arbeiten.     

g-Factors of high-spin isomers in 194Hg and 196Hg

The g-factors of the 10⁺ isomeric states in ¹⁹⁴Hg and ¹⁹⁶Hg have been measured using the in beam IPAD method. The results $\text{g(}{}^{194}\text{Hg}\text{) = ?0.24(4)}$ and $\text{g(}{}^{196}\text{Hg}\text{) = ?0.18(9)}$ are in agreement with the value expected for an ($\text{i}{}_1\text{3}\text{2}$^?2) neutron satructure and clearly contradict the previous assignment as ($\text{h}{}_{\mathrm{<mtext>1</mtext><mtext>1</mtext><mtext>2</mtext>}}{}^{\mathrm{?2}}$) proton configurations. Cranking model calculations show that the neutron excitation energies in the rotating frame agree satisfactorily with the experimental energies and that the proton excitations are expected ≈2 MeV above the experimental yrast line     

Toward the development of a structurally novel class of chiral auxiliaries. Conformational properties of the aldol adducts of oxadiazinones: observation of unusual shielding effects

Asymmetric aldol reactions were conducted with the titanium enolate of N(3)-hydrocinnamoyl-3,4,5,6-tetrahydro-2H-1,3,4-oxadiazin-2-one to afford aldol adducts 5a-j. The dominant product of the asymmetric aldol reaction was the non-Evans syn adduct as determined by (1)H NMR spectroscopy and X-ray crystallography. When evaluating the (1)H NMR spectra of adducts 5a-j, a highly shielded signal with an average chemical shift of 0.05 ppm was observed. This signal was readily determined to be the C(5)-methyl group of the oxadiazinone. It is presumed that the overall conformation adopted by the aldol adducts in solution places an aromatic ring of the N(3)-substituent in close proximity to the C(5)-methyl group. An investigation of this conformational preference is conducted employing (1)H NMR spectroscopy, X-ray crystallography, and computational methods.     

The g-factor of the Jπ=12+ isomeric state in188Hg

Using the reaction¹⁷⁵Lu(¹⁹F, 6n) theg-factor of the¹⁸⁸Hg isomeric state (J ^π=12⁺,T _1/2=135 ns) has been measured with the TDPAD method. The experimental value g=?0.168(10) supports the interpretation of an almost pure (vi13/2)^?2 configuration for this isomer.