A novel low compressible and superhard carbon nitride: Body-centered tetragonal CN(2)

A novel body-centered tetragonal CN(2) (4 units per cell), named as bct-CN(2), has been predicted here using our newly developed particle swarm optimization algorithm for crystal structure prediction. Bct-CN(2) is energetically much superior (3.022 eV per f.u.) to previously proposed pyrite structure and stable against decomposition into a mixture of diamond + N(2) or 1/3(C(3)N(4) + N(2)) above 45.4 GPa. No imaginary phonon frequencies in the whole Brillouin zone indicate bct-CN(2) is dynamically stable. The electronic calculations indicate that bct-CN(2) is a wide gap dielectric material with an indirect band gap of 3.6 eV. The ideal tensile, shear, and compressive strength at large strains of bct-CN(2) are examined to understand further the microscopic mechanism of the structural deformation. Strikingly, it is found that bct-CN(2) has high calculated ideal strength, bulk modulus, shear modulus, and simulated hardness, indicating its very incompressible and superhard nature. The results provide new thoughts for designing and synthesizing novel superhard carbon nitrides, and insights for understanding the mechanical properties.     

测量1 MA/100 ns脉冲大电流的微分环

强光一号加速器能输出上升沿约100 ns、幅值约2 MA的电流脉冲。实验中通常采用自积分式Rogowski线圈监测负载电流。为与该线圈比对校验,研制了一种快响应、结构简单、抗电磁干扰性能较好的微分环。标定实验给出,微分环测量的响应时间约1.2 ns,频谱响应范围10 kHz~100 MHz,灵敏度为6.1310-11(Vs)/A。其快时间响应将有助于监测与负载物理特性有关的瞬态电流变化。在加速器二极管短路状态对微分环和积分式Rogowski线圈进行了实验比对,数值积分给出的电流波形与后者基本相符,峰值偏差小于10%,表明微分环的设计合理,同时校验了电流测量的可信度。      

Efficient Heck cross-coupling of 3-iodo-benzopyrones with olefins under microwave irradiation without phosphine

An efficient and effective microwave-assisted Heck cross-coupling of different terminal olefins with various 3-iodo-benzopyrones including sterically hindered, electron-rich, electron-neutral, and electron-deficient is developed. It proceeded faster and generally gave good to excellent yields under microwave irradiation, phosphine-free, and air condition. The reaction could render this method particularly attractive for the efficient preparation of biologically and medicinally interesting molecules.     

POLYMER-SUPPORTED CLUSTER II SYNTHESIS, CHARACTERIZATION AND CATALYTIC PROPERTIES OF POLYMERSUPPORTED HETEROPENTAMETALLIC CLUSTER FeCO3 (CO)12 (μ3-AuPph2CH2■-■)*

The polymer-supported cluster FeCo3 (CO)_(12) (μ3-AuPph_2 CH_2) (4) has been synthesized through reaction of CH_2 ph_2 PAuCl with the cluster anion FeCo_3 (CO)_(12)~-. They are characterized through IR spectra, electronic spectra and XPS, with homogenous analog FeCo_3 (CO)_(12) (μ3-AuPph_3) (3) as reference compound. The cluster (3) and the polymer-supported cluster (4) are good catalysts for hydroformylation of olefins. They have better activity and selectivity than the cluster (1) and (2).The supported cluster (4) is more stable and has catalytic activity at higher temperature than its homogeneous analog (3). From the metal core level binding energies in XPS and λ_(max) in electronic spectra, it is found that the metal-metal bonds in (4) are reinforced bypolymer supporter. The cluster (3) and (4) can be reused , and possibly do not fragment to one metal species in the course of catalytic reaction.     

双曲矩阵分解修正问题的一些结果

This paper considers the updating problem of the hyperbolic matrix factorizations. The sufficient conditions for the existence of the updated hyperbolic matrix factorizations are first provided. Then, some differential inequalities and first order perturbation expansions for the updated hyperbolic factors are derived. These results generalize the corresponding ones for the updating problem of the classical QR factorization obtained by Jiguang SUN.     

强光一号激光触发开关的触发系统

介绍了基于强光一号实验平台的2 MV级激光触发开关（LTGS）实验中触发系统的设计与应用情况。系统中使用了一台266 nm 四倍频Nd:YAG激光器,单次触发输出参数为80 mJ,7 ns,0.5 mrad的激光脉冲,用于触发LTGS。激光器的触发源为两台DG535脉冲发生器,联合强光一号触发信号发生装置使用,保证了激光脉冲与开关电压峰值的同步性。触发系统在自击穿电压波峰前200 ns将激光脉冲馈入开关,在充气0.2～0.3 MPa条件下均能成功触发,得到了充气0.3 MPa时触发抖动3.86 ns的结果。     

Quality consistency evaluation of commercial transfer factor injections by chromatographic fingerprint combined with multivariate statistical analysis

The current quality control methods relying mainly on chromogenic reaction can hardly ensure the quality and safety of the biochemical drug with complex chemical composition. Therefore, a chromatographic fingerprint method was developed for the quality evaluation of a multicomponent biochemical drug, transfer factor injection. High‐performance liquid chromatography fingerprint was measured by using a C₁₈ column (250 × 4.6 mm, 5 µm) with a mobile phase composed of 0.1% trifluoroacetic acid–water and 0.085% trifluoroacetic acid–acetonitrile under gradient elution. The developed method was validated and was subsequently applied to 57 batches of commercial products which were sampled by National Drug Assessment Program. High‐resolution mass spectrometry analysis was performed on characteristic peaks of fingerprints, and a series of amino acids, nucleosides, and deoxynucleosides were identified. In the fingerprint assessments, principal component analysis and Hotelling T² analysis yielded the best results. The results generally indicated that there was a significant difference among products of batch‐to‐batch or from different manufacturers. Abnormal samples and its discriminatory components were also explored. In summary, the established fingerprinting method with multivariate statistical analysis could offer an efficient, reliable, and practical approach for quality consistency evaluation of transfer factor injection, providing a reference for the quality control of other multicomponent biochemical drugs.     

Long-length IBAD-MgO buffer layers for high performance RE-123 coated conductors by a large ion beam source

In Fujikura, a large-scale ion-beam-assisted deposition (IBAD) system with a large ion source has been employed to fabricate biaxially textured MgO films. The large-scale IBAD system has multiple deposition lanes where substrate tapes move, and therefore we have to optimize experimental conditions at each lane. We selected an appropriate deposition area and, finally, we successfully fabricated a 1 km-length IBAD-MgO film at a production rate of 1 km/h. We also studied pulsed-laser-deposited (PLD) CeO₂ films directly on the IBAD-MgO films in spite of a large lattice mismatch between CeO₂ and MgO. From transmission electron microscope (TEM) observations at an interface between MgO and CeO₂ films, it is revealed that there is domain-matching-epitaxy relationship between MgO and CeO₂ films. We also fabricated thin (1.0 μm) and thick (3.7 μm) PLD – GdBa₂Cu₃O_7−x (GdBCO) film on the long-length CeO₂/MgO substrate (over 150 m). Critical currents (I_c) and current density (J_c) were over 300 A and 3 MA/cm² respectively for the thin GdBCO film and were about 645 A and 1.7 MA/cm² for the thick GdBCO film at 77 K in self-field.     

太赫兹波大气传输衰减模型

基于修正的Van-Vleck Weisskopf线型、辐射传输色散理论和水汽连续体吸收模型,结合HITRAN数据库,建立了太赫兹波大气传输衰减模型VVWH,形成了对宽频太赫兹波在真实大气中水平传输衰减的数值模拟能力。同时对太赫兹时域光谱技术（THz-TDS）获取的透射光谱实测数据进行了对比分析。计算结果与实验结果总体变化趋势一致,在吸收谱线处两者吻合良好,但在低频的大气窗口区,实验结果相比计算呈现出更强的传输衰减。考察了相对湿度对太赫兹波大气传输衰减特性的影响变化。     

黄河黑山峡大柳树坝坝址岩体渗漏量及灌浆量数值模拟研究

大坝坝址岩体的渗漏研究对于大坝的安全运营至关重要。在进行渗漏治理的措施中,灌浆是常见的一种,但目前确定灌浆的各项参数,如配合比,孔距等,需通过灌浆试验花费大量的人财物力及时间才能确定。为快速查清每一种灌浆方案所灌浆量,本文针对模拟坝址水库渗漏灌浆效果的三维数值模拟开展了计算研究。在对大柳树坝坝址岩体地质情况及渗漏情况分析的基础上,将蓄水前的地下水运移规律模拟出,与实际通过钻孔平硐资料及分析得出的实际地下水运移规律做比较,验证对地下水运移规律的假设; 然后将蓄水后的地下水运移规律模拟出,确定地下水的运移规律,了解地下水运移的方向,验证与根据实际情况初步判断的地下水运移方向是否吻合; 最后通过数值模拟确定在一定灌浆浆液配合比的情况下所需灌浆量与实际的灌浆试验结果做比较。得出结果与实际灌浆试验结果吻合,证明通过数值模拟,建立浆液配合比与灌浆效果之间的关系,在类似情况快速地选取配合比是可行的。