Twista-4,9-diene. Preliminary communication

A synthesis of twista-4,9-diene ( 17 ) from tricyclo[4.3.1.0^3,8]dec-4-en-10-one ( 2 ) is described.     

Carbon dioxide reduction by an Al–O–P frustrated Lewis pair

The reaction of tBu₂P(O)H with Bis₂AlH (Bis = CH(SiMe₃)₂) afforded the adduct tBu₂P(H)–O–Al(H)Bis₂ (3). It slowly releases H₂ to form the first oxygen-bridged geminal Al/P frustrated Lewis pair tBu₂P–O–AlBis₂. It is capable of reversibly binding molecular hydrogen to afford 3, shown by NMR and H/D scrambling experiments, and forms a 1,2-adduct with CO₂. Importantly, the H₂ adduct 3 reduces CO₂ in a stoichiometric reaction leading to the formic acid adduct tBu₂P(H)–O–Al(CO₂H)Bis₂. The formation of the different species was explored by density functional theory calculations which provide support for the experimental results. All products were characterized by NMR spectroscopy as well as X-ray diffraction experiments and elemental analyses.

Addition vs. reduction: the geminal FLP Bis₂Al–O–PtBu₂ can reversibly bind molecular hydrogen, it reacts with CO₂ to give an adduct, and its hydrogen adduct reduces CO₂ to an adduct of formic acid.     

Optical sampling techniques

The optical sampling technique is a novel method to perform time-resolved measurements of optical data signals at high bit rates with a bandwidth that cannot be reached by conventional photodetectors and oscilloscopes. The chapter reviews the techniques that are used in optical sampling systems to perform the ultrafast sampling of the signal under investigation. In addition to the various nonlinear materials and effects used for the optical sampling gates and pulse sources, the realized optical sampling systems also differ in the way, in which the system is synchronized to the data signal. Systems have been reported using synchronous, random and software synchronized configurations. Applications of optical sampling systems include high bit rate waveform and eye diagram measurements, measurements of constellation diagrams of phase modulated data signals, time-resolved measurements of the state-of-polarization as well as investigations of fiber transmission impairments.     

Zur Geschichte der Bohr-Sommerfeldschen Quantentheorie

On the History of Bohr-Sommerfeld Quantum Theory In the present paper articles of N. Bohr, P. Ehrenfest, A. Sommerfeld, P. Epstein and K. Schwarzschild are reviewed with respect to the conceptual essentials in the history of the early quantum theory during the period from 1914 to 1918.