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G. F. Goya R. C. Mercader M. B. Vassallo I. L. Botto R. Sáez Puche 《Hyperfine Interactions》1994,83(1):199-201
The oxidic phase FeMoVO7 of the Fe2O3-V2O5-MoO3 system has been synthesized. Susceptibility measurements from 4.2 K to room temperature display an antiferromagnetic behaviour with an effective magnetic moment of 5.80
b
. This value, and the measured Mössbauer isomer shift of 0.40±0.02 mm/s, are characteristic of high-spin Fe(III). The lowT
n
value of 15 K suggests a weak interaction among the Fe-O polyhedra. The relative small QS=0.28±0.02 mm/s found in this compound shows that the Fe-O polyhedra symmetry is close to octahedral and almost undistorted. 相似文献
995.
I. Orúe P. Gorría F. Plazaola M. L. Fernández-Gubieda J. M. Barandiarán 《Hyperfine Interactions》1994,94(1):2199-2205
Mössbauer measurements have been performed on amorphous and nanocrystalline alloy ribbons of nominal composition Fe86Zr7Cu1B6. The nanocrystalline samples were obtained by annealing the as-quenched alloy at different temperatures in the range between 650 and 870 K. Mössbauer spectra of the as-quenched amorphous sample have been recorded at 77 K, room temperature and above the Curie temperature (330 K) at 360 K. We have also performed Mössbauer measurements at room temperature in the nanocrystalline alloys to characterize the phases that appear after the annealing and their relative concentration. The as-quenched sample spectra reveal the existence of two inequivalent sites for Fe. Such a feature is also observed in the remaining amorphous phase of the annealed samples. In the first steps of crystallization, -Fe precipitates and its concentration increases with the annealing temperature. The experimental results suggest that the composition of the whole amorphous phase does not suffer large changes during crystallization. 相似文献
996.
Results of the57Fe Mössbauer spectroscopy of greigite from the greigite-rich horizon of the middle part of the miocene series (Sokolov Basin, North Bohemia) are reported. From the room-temperature transmission spectra of the powdered samples magnetically separated from claystones, the Mössbauer analyses were performed. Relative abundances of various magnetic and non-magnetic Fe2+ and Fe3+ species led to the identification of the two magnetic iron sites in greigite in accordance with its spinel structure having mutually near effective magnetic inductions of 32.1 and 31.3 T, respectively. In addition, three pyrrhotite and two magnetite magnetic sites plus probably two pyrite and/or arsenopyrite iron positions were identified, of which some have been reported in the literature as the greigite iron contributions. 相似文献
997.
57Fe Mössbauer study of amorphous and nanocrystalline Fe73.5Nb3Cu1Si13.5B9 after neutron irradiation
57Fe Mössbauer spectroscopy is used to study neutron irradiation induced changes in the short-range order of Fe73.5Nb3Cu1Si13.5B9 alloy. The samples are investigated in both amorphous and nanocrystalline states. Neutron irradiation leads to an increase of the standard deviation of a hyperfine field distribution (HFD), implying rearrangement of the atoms towards disordering. Simultaneously, changes in the average value of the hyperfine field and a net magnetic moment position occur as a consequence of a spin reorientation, atom mixing and microscopic stress centres which are introduced by neutron irradiation. 相似文献
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S. Szatmári 《Applied physics. B, Lasers and optics》1994,58(3):211-223
At present the performance of short-pulse rare-gas-halide excimer-laser systems is definitely below that of solid-state systems, as far as the maximum peak-power is concerned. However, short-pulse excimer lasers are expected to be the best candidates to produce the highest focused intensities (I 1020 W/cm2) provided by the shorter wavelength and less optical distortion in the gaseous active medium. This is especially feasible if the present performance of short-wavelength focusing optics is improved, and the problem of the limited extraction efficiency of excimers is solved. In this paper the results of former developments, novel methods, such as spatially-evolving chirped-pulse amplification, off-axis amplification, interferometric multiplexing, and some considerations for the achievable maximum brightness of table-top excimer systems are presented. 相似文献