Minimization of scintillation index against displacement parameters

For sinusoidal beams, minimization of scintillation index is carried out against the displacements parameters. It is found that x-y asymmetric cosh-Gaussian beam fulfills the requirements of such optimum beam. Our minimization procedure reveals that the optimum beam is achieved by continually focusing it at the chosen propagation length and by further adjusting displacements parameters to be propagation distance dependent. Scintillation index of thus constructed optimum beam is formulated and numerically evaluated. Our graphical comparisons entailing collimated and focused versions of cos-, cosh-Gaussian, annular-Gaussian and Gaussian beams show that the optimum beam yields the lowest scintillations provided that propagation range is less than or equal to the focusing distance.     

Synthesis and Optical Properties of Novel Red-Emitting PbNb<Subscript>2</Subscript>O<Subscript>6</Subscript>: Eu<Superscript>3+</Superscript> Phosphors

Undoped and PbNb₂O_6:Eu³⁺ (1.0 ≤ x ≤ 6.0 mol%) phosphors were synthesized at 1100 °C for 3.5 h by the conventional solid state reaction method. Synthesized PbNb₂O₆:Eu³⁺ phosphors were characterized by X-ray diffraction (XRD), Scanning electron microscopy (SEM), Energy dispersive spectroscopy (EDS) and Photoluminescence (PL) analyses. The PL spectra showed series of excitation peaks between 350 and 430 nm due to the 4f–4f transitions of Eu³⁺. For 395.0 nm excitation, emission spectra of Eu³⁺ doped samples were observed at 591 nm (orange) and 614 nm (red) due to the ⁵D₀ → ⁷F₁ transitions and ⁵D₀ → ⁷F₂ transitions, respectively. PL analysis results also showed that the emission intensity increased by increasing Eu³⁺ ion content. No concentration quenching effect was observed. The CIE chromaticity color coordinates (x,y) of the PbNb₂O₆:Eu³⁺ phosphors were found to be in the red region of the chromaticity diagram.     

Propagation characteristics of higher-order annular Gaussian beams in atmospheric turbulence

The propagation characteristics of higher-order annular Gaussian (HOAG) beams in turbulence are investigated. From a HOAG source plane excitation, the average intensity of the receiver plane is developed analytically. This formulation is verified against the previously derived HOAG beam solution in free space. The graphical outputs indicate that, upon traveling in turbulent atmosphere, the HOAG beam will undergo different stages of evolution. At intermediate propagation distances, it will attempt to concentrate the energy near the origin. In this process, the appearance of the single higher-order primary beam will be encountered. Eventually HOAG originated beam will become a pure Gaussian beam after propagating an excessive distance in the turbulent medium.     

Convergence of general beams into Gaussian intensity profiles after propagation in turbulent atmosphere

It is shown that a general shaped laser beam will eventually approach a Gaussian average intensity profile after propagation in turbulent atmosphere. In our formulation, source field at the exit plane of the laser is taken as the product of arbitrary functions of source transverse coordinates with Gaussian exponential modulations. Following the expansion of the arbitrary functions in terms of Hermite polynomials, the average receiver intensity expression is derived using the extended Huygens-Fresnel principle and the conditions for the intensity profile to assume a Gaussian shape are stated. The results are illustrated by simulating various source field distributions.     

The molecular structures, vibrational spectroscopies (FT-IR and Raman) and quantum chemical calculations of n-alkyltrimethylammonium bromides

The FT-IR and micro-Raman spectra of three n-alkyltrimethylammonium bromides (dodecyltrimethylammonium bromide (DTAB), tetradecyltrimethylammonium bromide (TTAB) and hexadecyl(cetyl)trimethylammonium bromide (CTAB)) in powder form were recorded in the regions 4000–550 cm^?1 and 3200–300 cm^?1, respectively. The optimized geometries and vibrational frequencies of DTAB, TTAB and CTAB have been carried out with ab initio Hartree-Fock (HF) and density functional theory method B3LYP calculations with the 6–31 G (d, p) basis set in the ground state. The comparison of the observed fundamental vibrational frequencies and calculated results for the fundamental vibrational frequencies of DTAB, TTAB and CTAB indicate that the scaled B3LYP method is superior compared to the scaled HF method.     

Structural and Near-Infrared Properties of Nd<Superscript>3+</Superscript> Activated Lu<Subscript>3</Subscript>NbO<Subscript>7</Subscript> Phosphor

Undoped and Nd³⁺ doped lutetium niobate phases have been prepared by a conventional solid state reaction method using lutetium acetate and niobium oxide at 1250 °C for 6 h. X-ray diffraction patterns of the 6 mol% Lu₃NbO₇ sample exhibited a cubic fluorite single phase. Phase structure exhibited interesting crystallization behaviour depending on increasing Nd³⁺ concentration which led to a Lu₃NbO₇ single phase formation during the heat treatment process. SEM investigations were also in agreement with the XRD results. Morphologies of Nd³⁺ doped lutetium niobate powders exhibited oval like shapes and grain sizes varied between 0.3 and 5 μm. Near-infrared luminescence properties of Nd³⁺ doped Lu₃NbO₇ were also studied. 1.06 μm laser transition characteristics of Nd³⁺ doped lutetium niobate have been observed. Concentration quenching phenomenon was not detected depending on increasing Nd³⁺ doping concentrations at room temperature.     

Dry sliding wear behavior of TIG welding clad WC composite coatings

In this study, melted tungsten carbide powders on the surface of AISI 4340 steel was applied by using tungsten inert gas (TIG) method. It was observed that it has been solidified in different microstructures depending on the production parameters. As a result of microstructure examinations, in the surface modified layers an eutectic and dendrite solidification was observed together with WC, W₂C phases. In the layer produced, the hardness values varied between 950 and 1200 HV. The minimum mass loss was observed in the sample, which was treated in 1.209 mm/s production rate, 0.5 g/s powder feed rate and 13.9 kJ/cm heat input.     

Off-axis Gaussian Schell-model beam and partially coherent laser array beam in a turbulent atmosphere

The propagation of an off-axis Gaussian Schell-model (GSM) beam in a turbulent atmosphere is investigated based on the extended Huygens-Fresnel integral formula. Analytical formulae for the cross-spectral density and corresponding partially coherent complex curvature tensor of an off-axis GSM beam propagating in a turbulent atmosphere are derived. Based on these formulae, the propagation properties of such kind of beam in a turbulent atmosphere are investigated in detail. Furthermore, the methods are extended to investigate the propagation properties of a partially coherent laser array beam in a turbulent atmosphere. The properties of an off-axis GSM beam and a partially coherent laser array beam in a turbulent atmosphere are closely related with the beam parameters and the structure constant of the turbulent atmosphere.     

Photoluminescence properties of Li6CaB3O8.5: M3+ (M3+: Dy and Sm)

Li₆CaB₃O_8.5: M³⁺ (M³⁺: Dy and Sm) phosphors were synthesized by a solution combustion synthesis. The synthesized materials were characterized by using the powder XRD. The emission and excitation spectra of these materials were measured at room temperature with a spectrofluorometer. Both Li₆CaB₃O_8.5: Dy³⁺ and Li₆CaB₃O_8.5: Sm³⁺ phosphors emit red, yellow and green light. Consequently, these materials are promising phosphors for white LEDs.     

Clairaut Anti-invariant Submersions from Sasakian and Kenmotsu Manifolds

We investigate new Clairaut conditions for anti-invariant submersions from Sasakian and Kenmotsu manifolds onto Riemannian manifolds. We prove that there do not exist Clairaut anti-invariant submersion admitting vertical Reeb vector field in case of the total manifold is Sasakian. Several illustrative examples are also included.