Long-Range Order, “Tower” of States,and Symmetry Breaking in Lattice Quantum Systems

Journal of Statistical Physics - In a quantum many-body system where the Hamiltonian and the order operator do not commute, it often happens that the unique ground state of a finite system exhibits...     

Collective characteristics of hadron systems produced in beam fragmentation of π+ p collisions at 250 GeV/c

Collective characteristics are studied of hadrons produced in beam fragmentation of non-single-diffractive π⁺ p-interactions at 250 GeV/c. An attempt is made to obtain experimental information on the properties of leading cluster production and fragmentation. On average, the leading cluster carries 0.8±0.1 of the incident momentum, so that the mean value of the inelasticity coefficient of 〈k〉=0.2±0.1 is significantly smaller than that deduced from leading single hadron spectra. The momentum transfer distribution shows that nonsingle-diffractive processes are less peripheral than diffraction dissociation. The analysis of thrust and sphericity shows jet-like structure of pion fragmentation, that of the charge flow an average forward charge of 〈Q _f 〉=0.45±0.04, in agreement with the average charge of the beam valence quarks. Our data are compared to diffraction dissociation and to the Fritiof model.     

Reagents for Detection of Carboxylate Anion Ligands after Chromatographic Separation of Zinc Carboxylato Complexes

JPC – Journal of Planar Chromatography – Modern TLC - Reagents for detection of carboxylate anions as components of zinc carboxylato mixed-ligand complexes, after chromatographic...     

Gaussian bounds for correlations in lattice spin systems

In quite generalN-component ferromagnetic spin systems, it is proved that an arbitrary correlation function is bounded by the corresponding correlation function of a Gaussian model. The bound is useful for the analysis of high-temperature behavior of the system. Similar bounds for truncated correlation functions are also obtained for a class of single-component spin systems.     

The Coefficient of Restitution Does Not Exceed Unity

We study a classical mechanical problem in which a macroscopic ball is reflected by a non-deformable wall. The ball is modeled as a collection of classical particles bound together by an arbitrary potential, and its internal degrees of freedom are initially set to be in thermal equilibrium. The wall is represented by an arbitrary potential which is translation invariant in two directions. We then prove that the final normal momentum can exceed the initial normal momentum at most by O(■mkT), where m is the total mass of the ball, k the Boltzmann constant, and T the temperature. This implies the well-known statement in the title in the macroscopic limit where O(■mkT) is negligible. Our result may be interpreted as a rigorous demonstration of the second law of thermodynamics in a system where a macroscopic dynamics and microscopic degrees of freedom are intrinsically coupled with each other.     

Tate cohomology lowers chromatic Bousfield classes

Let be a finite group. We use recent results of J. P. C. Greenlees and H. Sadofsky to show that the Tate homology of local spectra with respect to produces local spectra. We also show that the Bousfield class of the Tate homology of (for finite) is the same as that of . To be precise, recall that Tate homology is a functor from -spectra to -spectra. To produce a functor from spectra to spectra, we look at a spectrum as a naive -spectrum on which acts trivially, apply Tate homology, and take -fixed points. This composite is the functor we shall actually study, and we'll prove that when is finite. When , the symmetric group on letters, this is related to a conjecture of Hopkins and Mahowald (usually framed in terms of Mahowald's functor ).

     

Thermogravimetric characterization of solid-state ion-exchange procedure in zeolites

The solid-state ion-exchange procedures of zeolites with Cu²⁺, Ni²⁺, Fe²⁺ and Co²⁺ salts can be resulted in prosperous catalysts for NO decomposition. Reactions taking place in solid-state between four transition metal cholirides and H-ZS-5 zeolite were investigated by means of a derivatograph. The results showed that irreversible consumption of surface -OH groups occurred with simultaneous bonding of the transition metal in the zeolite channel structure.     

The role of nitric oxide in cancer improved methods for measurement of nitrite and nitrate by high-performance ion chromatography

The short lifetime of nitric oxide (NO) in vivo impedes its quantitation directly; however, the determination of nitrite and nitrate ions as the end-products of NO oxidation has proven a more practical approach. High-performance ion chromatographic analysis of nitrite in biological fluids is hampered by the large amount of chloride ion (up to 100mmol/l) which results in insufficient peak resolution when utilizing conductimetric detection. Analysis of both anions in small sample volumes is also constrained by the need to minimise sample handling to avoid contamination by environmental nitrate. We report a means to remove Cl⁻ ions from small sample volumes using Ag⁺ resin which facilitates quantitation of either nitrite and nitrate anions in biological samples, using silica or polymer based ion-exchange resins with conductimetric or electrochemical and spectrophotometric detection. Including a reversed-phase guard column before the anion-exchange guard and analytical column also greatly extends column lifetime.     

Alternating oligo(p-phenylene vinylene)--perylene bisimide copolymers: synthesis,photophysics, and photovoltaic properties of a new class of donor--acceptor materials

A Suzuki polycondensation reaction has been used to synthesize two copolymers consisting of alternating oligo(p-phenylene vinylene) (OPV) donor and perylene bisimide (PERY) acceptor chromophores. The copolymers differ by the length of the saturated spacer that connects the OPV and PERY units. Photoinduced singlet energy transfer and photoinduced charge separation in these polychromophores have been studied in solution and in the solid state via photoluminescence and femtosecond pump-probe spectroscopy. In both polymers a photoinduced electron transfer occurs within a few picoseconds after excitation of the OPV or the PERY chromophore. The electron transfer from OPV excited state competes with a singlet energy transfer state to the PERY chromophore. The differences in rate constants for the electron- and energy-transfer processes are discussed on the basis of correlated quantum-chemical calculations and in terms of conformational preferences and folding of the two polymers. In solution, the lifetime of the charge-separated state is longer than in the films where geminate recombination is much faster. However, in the films some charges are able to escape from geminate recombination and diffuse away and can be collected at the electrodes when the polymers are incorporated in a photovoltaic device.