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961.
962.
Mizuki Ono 《Communications in Mathematical Physics》1989,126(1):25-48
We consider then-dimensional Euclidean lattices withZ
m
symmetries. It is shown that such lattices can be considered as ideals of some cyclotomic fields. Therefore we can translate problems about the above lattices into those about number theory. For alln (n22), we have obtained the classification of such lattices. 相似文献
963.
Ono Y Sugihara Y Ishii A Nakayama J 《Journal of the American Chemical Society》2003,125(40):12114-12115
2,3-Di(1-adamantyl)thiirene 1-oxide quickly reacted with Lawesson's reagent in CH2Cl2 at room temperature to provide di(1-adamantyl)ethanedithione (1) as thermally labile, violet crystals in 20% isolated yield. The use of CS2 as the solvent gave 1 in 46% isolated yield. The reaction in the presence of dimethyl acetylenedicarboxylate furnished dimethyl 4,5-di(1-adamantyl)-2,3-thiophenedicarboxylate in 51% yield. A tentative mechanism for the formation of 1 is proposed on the basis of the experimental observations. The structure of 1 was characterized on the basis of spectroscopic data (NMR, mass, IR, Raman, and UV/vis) and DFT calculations. 1 rearranged to 3,4-di(1-adamantyl)-1,2-dithiete quantitatively with kinetic parameters of DeltaH = 17.6 +/- 0.2 kcal mol-1, DeltaS = -23.0 +/- 0.7 cal K-1 mol-1, and DeltaG = 24.4 +/- 0.4 kcal mol-1. Peracid oxidation and Pt-complex formation of 1 are also reported. 相似文献
964.
Yu Harabuchi Yuriko Ono Satoshi Maeda Tetsuya Taketsugu Kristopher Keipert Mark S. Gordon 《Journal of computational chemistry》2016,37(5):487-493
A new type of reaction pathway which involves a nontotally symmetric trifurcation was found and investigated for a typical SN2‐type reaction, NC‐ + CH3X → NC? CH3 + X‐ (X = F, Cl). A nontotally symmetric valley‐ridge inflection (VRI) point was located along the C3v reaction path. For X = F, the minimum energy path (MEP) starting from the transition state (TS) leads to a second‐order saddle point with C3v symmetry, which connects three product minima of Cs symmetry. For X = Cl, four product minima have been observed, of which three belong to Cs symmetry and one to C3v symmetry. The branching path from the VRI point to the lower symmetry minima was determined by a linear interpolation technique. The branching mechanism is discussed based on the reaction path curvature and net atomic charges, and the possibility of a nonotally symmetric n‐furcation is discussed. © 2015 Wiley Periodicals, Inc. 相似文献
965.
Qinghui Li Rina Suzuki Yuki Ono Izumi Nakai Keiichi Tanaka Satoshi Nakayama Haruo Takahashi 《X射线光谱测定》2009,38(5):369-375
Suspended particulate matter (SPM) collected in the urban area of Tokyo was analyzed using a transition edge sensor (TES) microcalorimeter x‐ray detector mounted on a FE‐SEM system. This prototype microcalorimeter spectrometer with an energy resolution of 19 eV identified some severe peak overlaps in the spectra measured by the traditional Si(Li) solid state detector, including S Kα with Pb Mα, Zn Lα with Na Kα, and Ti Kα with Ba Lα. In addition, the TES microcalorimeter showed good spatial resolution for the microanalysis of SPM. The focused ion beam(FIB) was successfully applied to fabricate a cross section of a single SPM particle. The chemical compositonal difference between surface and inner parts, and among different surface parts of the SPM was also determined. Through combination of the FIB technique and the TES microcalorimeter, we achieved a better understanding of the SPM. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
966.
Nitration of 4,7-ethanoisoindoles gave 1-nitro derivatives in moderate yields. Reduction of a nitro to amino group was successfully performed by sodium hydrosulfite in the case of ethyl 3-nitro-4,7-ethanoisoindole-1-carboxylate. The amino derivative was converted to benzylidenaminoisoindoles based on the retro Diels-Alder reaction. Their UV-vis spectra showed strong absorptions at 500-700 nm. 相似文献
967.
Hajime Tanaka 《Linear algebra and its applications》2009,430(2-3):865-867
We give a new proof of Theorem 6 in [L. Qiu and X. Zhan, On the span of Hadamard products of vectors, Linear Algebra Appl. 422 (2007) 304–307]. 相似文献
968.
Masahide Shimokawabe Kohei Okumura Hironobu Ono Nobutsune Takezawa 《Reaction Kinetics and Catalysis Letters》2001,73(2):267-274
NO3-type and NO2-type adsorbed species are formed on Cu-ZSM-5 together with adsorbed O species at 523 K in the decomposition of NO accompanied
by the evolution of N2, N2O, and NO2.
This revised version was published online in June 2006 with corrections to the Cover Date. 相似文献
969.
M Ono K Nishimura H Tsubouchi Y Nagaoka K Tomioka 《The Journal of organic chemistry》2001,66(24):8199-8203
(-)-Neplanocin A (1), S-adenosylhomocystein hydrolase inhibitor, was synthesized. The characteristic of this synthesis is a stereoselective construction of five-membered ring of neplanocin A by intramolecular aldol reaction of the lithium enolate that was generated by conjugate addition of lithium thiolate. TBS-protected chiral omega-oxo-alpha,beta-unsaturated ester 16, which was prepared from D-mannitol, was treated with 1.2 equiv of lithium benzylthiolate in THF at -20 degrees C to give three separable cyclization products in good yields and stereoselectivity. After conversions of protective groups, the benzylsulfanyl part of 21 was removed by oxidation to sulfoxide and subsequent thermal elimination to give the requisite double bond. Through the functional group transformations of 30, total synthesis of (-)-neplanocin A (1) was accomplished. 相似文献
970.
Seiji Yamaguchi Kazuaki Awajima Yoshiro Hirai Hajime Yokoyama Shunsaku Shiotani 《Journal of heterocyclic chemistry》1998,35(6):1249-1255
Bromination of 3-bromofuro[2,3-b]- 1a , -[3,2-b]- 1b and - [3,2-c]pyridine 1d afforded the 2,3-dibromo derivatives 2a, 2b and 2d , while the -[2,3-c]- compound 1c did not give the dibromo derivative. Nitration of 1a-d gave the 2-nitro-3-bromo compounds 3a-d . The N-oxides 4a-d of 1a-d were submitted to the cyanation with trimethylsilyl cyanide to yield the corresponding α-cyanopyridine compound 6a-d . Chlorination of 4a and 4d with phosphorus oxychloride gave mainly the chloropyridine derivatives 7a, 7′a and 7d , while 4b and 4c gave mainly the chlorofuran derivatives 7′b and 7′c accompanying formation of the chloropyridine derivatives 7b, 7′b and 7c . Acetoxylation of 4a and 4b with acetic anhydride yielded the acetoxypyridine compounds 8a, 8′a and 8b , while 4c and 4d gave the acetoxypyridine 8′c, 8′d and 8′d , pyridone 8c and 8d , acetoxyfuran 8′c and dibromo compound 9c and 9′c. 相似文献