Phase transition in ordered porphyrin layers on iodide modified Cu(1 1 1): An EC-STM study

The self-assembly of meso-tetra (N-methyl-4-pyridyl) porphyrine tetratosylat (H₂TMPyP) on an iodide modified Cu(1 1 1) surface has been studied by means of in situ electrochemical-scanning tunneling microscopy (EC-STM). The I/Cu(1 1 1) surface was found to be a good substrate for the self-assembly of highly ordered layers of porphyrin cations. Furthermore, a reversible structural phase transition within the highly ordered porphyrin layer was observed during variation of the electrode potential, as a consequence of changing electronic properties of the substrate.     

Poly[di‐μ3‐chloro‐μ2‐trans‐1,2‐di‐4‐pyridylethyl­ene‐dicopper(I)]: a two‐dimensional organic–inorganic hybrid constructed from linear CuCl clusters and bridging ligands

The structure of the title compound, [Cu₂Cl₂(C₁₂H₁₀N₂)]_n, contains infinite CuCl staircase‐like chains, which lie about inversion centres. The trans‐1,2‐di‐4‐pyrid­ylethyl­ene mol­ecules also lie about inversion centres and connect the CuCl chains through Cu—N coordination bonds into a two‐dimensional organic–inorganic hybrid network. The planar sheets are stacked along the c axis and associated through weak C—H⋯Cl inter­actions. The results show a reliable structural motif with controllable separation of the CuCl chains by variation of the length of the ligand.     

Enhanced Photocatalytic Efficiency of TiO2 by Combining the Modification of Ag Nanoparticles with the Application of Anodic Bias

Ag-TiO2/TTO film electrode was used as photoanode to investigate the feasibility of a hybrid technology of Ag nanoparticles combined with the application of anodic bias.The results showed that the deposited Ag and applied anodic bias have an apparent additive effect.     

A New Sesquiterpene Polyol Ester from Celastrus Angulatus

A new sesquiterpene polyol ester, angulatin D, has been isolated from the root bark of Celastrus angulatus. The chemical structure is elucidated on the basis of spectral analysis.     

A New Furostanol Saponin from the Water-extract of Dioscorea nipponica Mak., the Raw Material of the Traditional Chinese Herbal Medicine Wei Ao Xin

26-O-β-D-Glucopyranosyl-furost-5(6),20(22)-dien-3β,26-diol 1, a new furostanol saponin, was isolated from the water-extract of Dioscorea nipponica Mak., the raw material of a traditional Chinese herbal medicine Wei Ao Xin. The structure of 1 was determined on the basis of its spectral data especially by NMR spectroscopy. The result provides the first example of naturally occurring furostanol saponins with a single saccharide chain at the C-26 position.     

α模型中不固定多重数下的阶乘矩、粒子数关联矩

利用二维相空间自仿射分形的随机级联α模型,采用蒙特卡罗模拟的方法,研究了阶乘矩､粒子数关联矩在不固定多重数下,对应于多重数相对起伏强度n_f的依赖关系,得到:阶乘矩、粒子数关联矩依赖于多重数相对起伏n_f,但间歇指数一般不依赖于n_f,当n_f较小时这种依赖性得以消除.     

Synthesis of a novel multivalent galactoside with high hepatocyte targeting for gene delivery

A novel bifunctional glycolipid which carded a cluster of thiogalactosides as the hepatocyte targeting ligand for gene delivery was prepared. Hexa-antennary alcohol 1 was used as the core scaffold to attach a cholesterol molecule by a poly（ethylene glycol） chain, while its remaining branches were linked with five acetylgalactosides, which would be deacetylated later to produce pentaantennary galactoside. Liposome containing the galactoside showed high affinity and transfection activity in hepatoma cells HepG2.     

A New Daphnane Diterpene from Daphne tangutica

Daphne tangutica Maxim., a shrub of Thymelaeaceae family, meanly grows in northwest area of China at altitude of 1500-4000 m. The root barks of this plant are utilized as a traditional Tibetan medicine for releasing pain, curing rheumatism and as an abort…     

Kinetics and mechanism of promoted hydrolysis of 4‐nitrophenyl acetate by zinc(II)‐tripod: Different roles of mononuclear and trinuclear species

Coordination studies on Zn(II) complexes of 1,3,5‐tri(2,5‐diazahexyl)benzene (L) show that by comparison with the non‐deprotonation of complex ZnL in a 1:1 system, the three‐dimensional complexiaton decreases the pK_a of the Zn‐bound water molecule, that is, pK_a = 7.47 for trinulclear complex Zn₃L in a 3:1 metal–ligand ratio. These two types of zinc(II) complexes have been examined as catalysts for the hydrolysis of 4‐nitrophenyl acetate (NA) in 10% (v/v) CH₃CN at 298 K, I = 0.10 mol dm^?3 KNO₃ at pH range 6.5–8.2 and 8.5–10, respectively. Kinetic studies show that the second‐order rate constants of NA‐hydrolysis catalyzed by complexes ZnL, Zn₃L, and Zn₃LH_?1 are 0.021, 0.0082, and 0.342 mol^?1 dm³ s^?1, respectively. In all the cases, the pH‐dependent observed first‐order rate constant, k_obs, shows sigmoidal pH–rate profile. The 1:1 complex ZnL–H₂O undergoes NA hydrolysis by direct rate‐determining hydrolysis to produce 4‐nitrophenol(ate) (NP^?) and ZnL(OOCCH₃); while in the 3:1 system the oxygen atom of acetic group forms a H‐bond with the Zn(II)‐bound water of the second branch of tripod indicating that the polynuclear centers are associated and bi‐functional. © 2003 Wiley Periodicals, Inc. Int J Chem Kinet 36: 41–48 2004     

~(190)Tl的πh_(9/2)νi_(13/2)扁椭球转动带的旋称反转研究(英文)

利用能量为 1 6 7— 1 75MeV的35Cl束流 ,通过16 0 Gd(35Cl,5n)熔合蒸发反应研究了190 Tl的高自旋态能级结构 .实验建立了190 Tl基于πh9/2 　 　νi13/2 组态的转动带 .在束测量结果和194 Biα衰变的α γ测量结果确定地指定了190 Tl的πh9/2 　 　νi13/2 转动带的自旋值 .基于自旋指定 ,发现了190 Tl的πh9/2 　 　νi13/2 扁椭球转动带在低自旋时旋称反转 .这是首次在基于πh9/2 　 　νi13/2 组态的扁椭球转动带中观测到旋称反转 .考虑了质子 -中子剩余相互作用的粒子 -转子模型能够解释πh9/2 　 　νi13/2 扁椭球转动带的低自旋旋称反转 .