F－L模型的状态方程与退禁闭相变图象

用温度场论方法计算了Ｆ－Ｌ模型在有限温度和密度下的状态方程，分析了压强对净重子数密度的等温线．结果表明，在平均场近似下，Ｆ－Ｌ模型所给出的退禁闭相变为一级相变．     

Barium(II)–2,4‐dinitrophenolate–18‐crown‐6 at 183 K

The title compound, bis(2,4‐dinitrophenolato‐κ²O,O′)(1,4,7,10,13,16‐hexaoxadecane‐κ⁶O)barium(II), [Ba(C₆H₃N₂O₅)₂(C₁₂H₂₄O₆)], is a 1:1 complex of barium(II)–2,4‐di­nitro­phenolate and 1,4,7,10,13,16‐hexaoxa­cyclo­octa­decane (18‐crown‐6). Its structure is located on a crystallographic inversion centre. The temperature dependence of the crystal structure has been studied. The monoclinic β angle of the P2₁/­n space group increases with increasing temperature. The packing structure of the complex is stabilized by intermolecular C—H?O interactions.     

氢化丁苯共聚物结构的核磁共振波谱表征Ⅰ.13C谱带的归属

本文分别用JEOL FX-90Q和Bruker AM-300波谱仪测定了氢化聚丁二烯和氢化丁苯共聚物的¹H,¹³C-NMR谱,得到了分辨率较高的谱图和新的结构信息。借助DEPT技术确定了各谱带的CH或CH₂类型。利用Grant-Paul和Lindeman-Adams介绍的化学位移经验计算公式,考虑苯基对α、β和γ碳原子的影响,计算了各种三单元序列中有关碳原子的化学位移。对脂肪碳部分的28组谱带重新进行了归属。化学位移计算值与实测值基本相符,并得到了不同组成的模型聚合物¹³C-NMR谱的各谱带强度变化规律的验证。     

一种实现光源与光纤耦合的方法

本文介绍了一种用显微镜筒与透镜构成的光学系统来实现光源与光纤耦合的方法。该方法具有光路系统小巧方便、耐用、耦合效率高等优点。     

工业CT图像均匀性校正

在工业CT图像重建过程中,射束硬化使得图像出现“杯状”伪影,阵列探测器响应不一致使得图像出现环状伪影、带状伪影和点伪影,影响图像均匀性.本文分析了射束硬化的原理和探测器响应不一致的数学模型,并通过实验,对探测器响应进行多挡板定标得到校正系数表.利用查表插值的方法对投影数据进行均匀性校正,消除上述伪影.     

自体静脉移植血管的拉伸实验研究

本文考察了自体移植静脉的纵向应力应变关系。将狗股静脉移植于股动脉，在术后不同时间切取移植静脉进行纵向单轴拉伸实验。结果表明，移植静脉的应力－应变曲线比正常静脉靠近应力坐标轴并在术后逐渐向左移动。这显示了移植血管管壁组织在术后的逐渐硬化。     

闪光灯泵浦的Nd:KGd(WO4)2激光器

报道了用闪光灯泵浦的掺钕的钨酸钆镓(Nd³⁺:KGd(WO₄)₂激光器.在重复频率1Hz,脉宽120μs的灯泵下,测量了不同透过率下激光输出能量,获得最大输出能量384mJ,斜率效率1.0%,外推阈值0.54J.在调Q运行时,Nd:KGW晶体的斜率效率为0.16%,最大输出能量46mJ.     

ROOM TEMPERATURE LIGHT-THERMO-DETECTOR MADE OF HIGH-Tc SUPERCONDUCTOR

Based on the anisotropic Seebeck tensor coefficients, a light-thermo-radiation detector made of high-T_c superconductor (YBa₂Cu₃O_7-δ) was fabricated, which can function at room temperature. The induced voltaic signals at various modulation frequencies for radiation from He-Ne laser and from a 500 K black body were measured. The noise ratio for detecting He-Ne laser radiation and the D^* for black body were evaluated. Compared with bolometer made of high-T_c superconductor which functions at liquid nitrogen, and with pyroelectric detector, it was found that the advantages of this new device are that the device can work at room temperature with very low noise and very fast response. Although having a lower D^* value than that of bolometer for the present device construction, we point out the possibility and the direction for improving the D^* value, hence the promising prospect of this kind of device.     

A global optimization design for quasi-optics power combiner of 3mm wave solid-state sources

This paper describes a global optimization design for quasi-optics power combiner of solid-state millimeter-wave sources. The operating frequency is about 100 GHz and the oscillating sources are GaAs Gunn diodes. The source-array plane is a matrix consisting of NxN (N=3,5, ..., 2k+1, where k is positive integer) diodes. The radio frequency power of the combiner is from threefold to sevenfold larger than the sum total of the single diodes power. The global optimums of the array and the location in the cuvity of the suorce-array plane will be given by a global optimizition method.     

Intramolecular motion and isotope effects in muonium‐substituted chloroalkyl radicals

Muon irradiation of pure liquid 3‐chloropropene, CH₂=CH-CH₂Cl, yields a primary radical, \dot\mboxCH₂-CHMu-CH₂Cl, and a secondary radical, MuCH₂-\rm\dot\mboxCH-CH₂Cl. 2‐methyl‐3‐chloropropene yields only the tertiary radical, MuCH₂-\rm\dot\mboxC(CH₃)-CH₂Cl. These three chloroalkyl radicals have been characterized by μSR and μLCR, and the hyperfine coupling constants (hfcs) have been determined over a range of temperatures, either in the pure liquid precursor or in concentrated solution. The temperature variation of the hfcs has been analyzed to obtain estimates of the barrier to internal rotation about the C_\alpha-C_\beta axis for various alkyl groups, and also their minimum energy conformations, i.e. their orientations with respect to the axis of the 2p_z orbital of the unpaired electron. The tertiary radical is particularly interesting because all three methyl‐like groups, -CH₃,-CH₂Cl and -CH₂Mu, are represented. The results can be compared to electron spin resonance data for analogous radicals, to provide information on the effects of Mu substitution for H. This revised version was published online in August 2006 with corrections to the Cover Date.