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排序方式: 共有146条查询结果,搜索用时 15 毫秒
41.
A three‐factor mixture design and response surface methodology were employed to find the optimal weight ratio of graphite powder, n‐dodecylpyridinium hexafluorophosphate and paraffin for the fabrication of a copper hexacyanoferrate modified carbon ionic liquid paste electrode (CuHCFe‐CILPE). The fabricated sensor showed electrocatalytic activity towards oxidation and reduction of hydrogen peroxide. It also was observed that the electrocatalytic activity for hydrogen peroxide oxidation was much higher than the electrocatalytic activity for hydrogen peroxide reduction. Glucose oxidase was then successfully immobilized on the surface of the proposed sensor to examine the possibility of using CuHCFe‐CILPE for the biosensor fabrication. 相似文献
42.
Mohammad Haghighi Zhi-qiang Sun Jin-hu Wu John Bromly Hui Ling Wee Esther Ng Yang Wang Dong-ke Zhang 《Proceedings of the Combustion Institute》2007,31(2):1983-1990
CO2 reforming of methane was studied over a bed of coal char in a fixed bed reactor at temperatures between 1073 and 1223 K and atmospheric pressure with a feed composition of CH4/CO2/N2 in the ratio of 1:1:8. Experimental results showed that the char was an effective catalyst for the production of syngas with a maximum H2/CO ratio of one. It was also found that high H2/CO ratios were favoured by low pressures and moderate to high temperatures. These results are supported by thermodynamic calculations. A mechanism of seven overall reactions was studied and three catalytic reactions of CH4 decomposition, char gasification and the Boudouard reaction was identified as being of major importance. The first reaction produces carbon and H2, the second consumes carbon, and the third (the Boudouard reaction) converts CO2 to CO while consuming carbon. Equilibrium calculations and experimental results showed that any water present reacts to form H2 and carbon oxides in the range of temperatures and pressures studied. Carbon deposition over the char bed is the major cause of deactivation. The rate of carbon formation depends on the kinetic balance between the surface reaction of the adsorbed hydrocarbons with oxygen containing species and the further dissociation of the hydrocarbon. 相似文献
43.
For a finite morphism f : X Y of smooth varieties such that f maps X birationally onto X=f(X), the local equations of f are obtained at the double points which are not triple. If C is the conductor of X over X, and
are the subschemes defined by C, then D and are shown to be complete intersections at these points, provided that C has the expected codimension. This leads one to determine the depth of local rings of X at these double points. On the other hand, when C is reduced in X, it is proved that X is weakly normal at these points, and some global results are given. For the case of affine spaces, the local equations of X at these points are computed. 相似文献
44.
Journal of Sol-Gel Science and Technology - This research is based on synthesis of titania (TiO2) nanophotocatalyst followed by cadmium (Cd) doping to activate the photocatalyst in visible part of... 相似文献
45.
Majid M. Heravi Masoumeh Haghighi Fatemeh Derikvand Fatemeh F. Bamoharram 《合成通讯》2013,43(21):3103-3107
A simple and effective method for tetrahydropyranylation of alcohols and phenols and the regeneration of THP ethers using a catalytic amount of H14[NaP5W30O110] is reported. 相似文献
46.
Mehrdad Seifali Abbas-Abadi Mehdi Nekoomanesh Haghighi Hamid Yeganeh Babak Bozorgi 《Journal of Thermal Analysis and Calorimetry》2013,114(3):1333-1339
The powder of EX5 grade of high density polyethylene—without any additives—manufactured by Amirkabir petrochemical company was separated by shaker equipment. The separated powder of average diameter ~25, ~62.5, ~87.5, ~112.5, ~137.5, ~175 and the particles >200 μm was tested by a thermogravimetric (TG) analysis instrument in nitrogen atmosphere and heating rates of 10, 20, and 30 °C min?1. In addition, the separated powders were analyzed by a melt flow index (MFI) instrument, and the viscosity average molecular mass (M v) of the powders was tested by a viscometer. Kinetic evaluations were performed by Friedman and Kissinger analysis methods and apparent activation energy for the overall degradation of the powders was determined. The effects of molecular mass, MFI, MFR, and particle size on the degradation TG curve, derivative thermogravimetry curve breadth, and activation energy of thermal degradation were considered. The results showed that the M v of EX5 pipe grade produced by two serial reactors is increased by increasing of the particle size and, MFI is decreased with a little deviation by particle size increasing. The particle size has no obvious effect on the melt flow rate (MFR), and MFR as function of molecular mass distribution does not change very much. The results showed that the powder with bigger particles and higher molecular mass moderately increases the activation energy and shifts the degradation curve to the higher temperatures. 相似文献
47.
An innovative procedure for functionalization of polyolefins was developed. It was found that synthesized polyolefins end‐capped with trimethoxysilane (silylated polyolefins) are new polyolefin‐based adhesives. To prepare the mentioned materials,1‐octene as a higher α‐olefin was cooligomerized with two linear, nonconjugated dienes (ie, 1,5‐hexadiene and 1,7‐octadiene) by using metallocene catalyst system, Cp2HfCl2/MAO, at room temperature. Then, amine‐terminated trimethoxysilane (3‐aminopropyltrimethoxysilane) was reacted with unsaturated bonds of synthesized cooligomers in the presence of palladium(II) acetate. Embedding of the dienes on 1‐octene oligomeric chains was explored by Fourier transform infrared (FTIR), 1H, and 13C‐NMR spectroscopy. On the basis of the results, 1,5‐hexadiene showed both 1‐butene branch and five‐member ring. On the other hand, 1,7‐octadiene was incorporated by 1,2‐addition, forming both 1‐hexene branch and seven‐member ring in the cooligomer backbone. Mole percentage of C?C and cyclic moieties reached to a value of 28.54, 18.59% mol in 1‐octene/1,5‐hexadiene, and 38.04, 6.71% mol in 1‐octene/1,7‐octadiene cooligomers, respectively. Reaction of synthesized cooligomers with 3‐aminopropyltrimethoxysilane was confirmed by FTIR spectroscopy, which yielded targeted adhesives. To study the adhesion properties, resulting adhesives were applied to different substrates. Obtained results demonstrated that tensile shear strength of synthesized adhesives to polar substrates was 2.21% to 2.84% more than nonpolar substrates. Among studied systems, the best performance was achieved by1‐octene/1,7‐octadiene–based adhesive and Al substrate with tensile shear strength of 1.45 N/mm2. 相似文献
48.
During recent developments on the theories and experimental techniques of compressed liquids and liquid mixtures, it has been revealed that there exist some regularities. Among these, the regularity found by Huang and O'Connell is that the isotherms of reduced bulk modulus of compressed liquids as a function of molar volume intersect at a common point. This intersection is a useful tool for evaluating the reliability of an equation of state (EOS) for producing equilibrium properties of matter. This paper also deals with an extension of the above regularity to some liquefied natural gas (LNG) mixtures including: N2+CH4, N2+C2H6, CH4+C2H6, CH4+C3H8, and CH4+C4H10 at different temperatures. The present work gives a theoretical analysis for the common bulk modulus point in terms of a statistical‐mechanical equation of state for mixtures. In addition, we have calculated excess molar volume of N2+CH4 mixture in terms of temperature and compared it with experimental values. 相似文献
49.
In this study, for the first time an electrochemiluminescence sensor for ultra-trace monitoring of lamotrigine is reported. The sensing probe was fabricated using silver prussian blue analogue as a new effective co-reaction accelerator and carboxylated sulfur-doped graphitic carbon nitride nanocomposite as a new green luminophore. Also potassium peroxydisulfate was utilized as a strong co-reactant. The proposed ECL sensor exhibited excellent wide linear range (3.45×10−15 to 2.98×10−8 M), low detection limit (4.89×10−16 M), the relative standard deviation of 1.07 %, outstanding reproducibility and superior long-term stability. The prominent advantages of the sensor showed that it can be used to determine LMT in clinical samples. 相似文献
50.
Roya Zahedi Faramarz Afshar Taromi Seyed Heidar Mirjahanmardi Mehdi Nekoomanesh Haghighi Khosrow Jadidi Roghayeh Jamjah 《高分子科学》2016,34(3):268-279
The penta-ether compound was synthesized by the reaction of di(trimethylolpropane) with sodium hydride as the strong base and methyl iodide as the alkyl halide. This compound was characterized by NMR, FTIR, and GC techniques. The MgCl2-supported titanium catalysts were incorporated with varying amounts of penta-ether compound as the internal donor and also the catalysts without the internal donor were synthesized. The synthesized catalysts and the conventional Ziegler- Natta catalyst were characterized. The titanium contents were determined by spectrophotometry, magnesium by complexometric titration and chloride by argentometric titration. The effects of the new internal donor on propylene polymerization with the prepared MgCl2-supported Ziegler-Natta catalysts were investigated and then these results were compared to the results obtained using the conventional diisobutyl phthalate-besed-Ziegler-Natta catalyst. The highest crystallinity degree, melting temperature, and isotacticity of polypropylene were obtained using the catalyst with a penta-ether/Mg molar ratio equal to 0.21. 相似文献