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111.
    
The new thermotropic polyester/polyaniline (PIn/PAni) blends have been prepared by solution blend of synthesized liquid crystalline poly[4,4′‐bis (ω‐alkoxy) biphenylisophthalate]s having four and six methylene units in spacer (PI4 and PI6) with PAni doped with camphorsolfonic acid (CSA). The percolation threshold electroactivity of prepared blend films has been determined by cyclic voltammetry. The effect of the PAni concentration, solvent nature and polyester structure on the electroactivity of the blends has been investigated. The extremely low percolation threshold of prepared PIn/PAni‐CSA blends from dimethylformamide (DMF) and m‐cresol solution was 3% weight of PAni‐CSA. The amount of conducting polymer necessary to retard the formation of the liquid crystalline (LC) phase is up to 45% by weight. Phase behavior studies by differential scanning calorimetry and polarizing microscopy show that blends with 45% of conducting polymer are both liquid crystal and conductive. The morphology of the blends has been investigated by scanning electron microscopy. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   
112.
    
A new diphenylphosphinite ionic liquid (IL-OPPh2) is introduced. This ionic liquid is used as both a reagent and a solvent to convert alcohols and trimethylsilyl and tetrahydropyranyl (THP) ethers into their corresponding alkyl bromides, thiocyanates or isothiocyanates in the presence of Br2 and SCN at 80 °C. In this ionic liquid, bromination and thiocyanation of alcohols occurs highly selectively in the presence of trimethylsilyl and THP-ethers and also between different classes of alcohols. The use of this ionic liquid allows easy separation of the desired products from the phosphinate by-product.  相似文献   
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114.
Let ${\mathcal P}$ be a partial order and ${\mathcal A}$ an arboreal extension of it (i.e. the Hasse diagram of ${\mathcal A}$ is a rooted tree with a unique minimal element). A jump of ${\mathcal A}$ is a relation contained in the Hasse diagram of ${\mathcal A}$ , but not in the order ${\mathcal P}$ . The arboreal jump number of ${\mathcal A}$ is the number of jumps contained in it. We study the problem of finding the arboreal extension of ${\mathcal P}$ having minimum arboreal jump number—a problem related to the well-known (linear) jump number problem. We describe several results for this problem, including NP-completeness, polynomial time solvable cases and bounds. We also discuss the concept of a minimal arboreal extension, namely an arboreal extension whose removal of one jump makes it no longer arboreal.  相似文献   
115.
    
The aim of this paper is to extend the method of Ammari et al. (Commun. Math. Phys., 2012) to scattering problems. We construct very effective near-cloaking structures for the scattering problem at a fixed frequency. These new structures are, before using the transformation optics, layered structures and are designed so that their first scattering coefficients vanish. Inside the cloaking region, any target has near-zero scattering cross section for a band of frequencies. We analytically show that our new construction significantly enhances the cloaking effect for the Helmholtz equation.  相似文献   
116.
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We consider the boundary value problem of calculating the electrostatic potential for a homogeneous conductor containing finitely many small insulating inclusions. We give a new proof of the asymptotic expansion of the electrostatic potential in terms of the background potential, the location of the inhomogeneities and their geometry, as the size of the inhomogeneities tends to zero. Such asymptotic expansions have already been used to design direct (i.e. noniterative) reconstruction algorithms for the determination of the location of the small inclusions from electrostatic measurements on the boundary, e.g. MUSIC-type methods. Our derivation of the asymptotic formulas is based on integral equation methods. It demonstrates the strong relation between factorization methods and MUSIC-type methods for the solution of this inverse problem.

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117.
The cooling effect of liquid droplets introduced into a hot gas stream flowing in an adiabatic duct is analysed. The coupled interaction between the changes in the droplets and in the surrounding gas conditions is examined as a result of droplets vaporization. It was found that the use of liquid sprays as a rapid cooling process for a hot gas discharge is quite effective.  相似文献   
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Ionic liquids (ILs) have emerged as active pharmaceutical ingredients because of their excellent antibacterial and biological activities. Herein, we used the green-chemistry-synthesis procedure, also known as the metathesis method, to develop three series of ionic liquids using 1-methyl-3-butyl imidazolium, butyl pyridinium, and diethyldibutylammonium as cations, and bromide (Br), methanesulfonate (CH3SO3), bis(trifluoromethanesulfonyl)imide (NTf2), dichloroacetate (CHCl2CO2), tetrafluoroborate (BF4), and hydrogen sulfate (HSO4) as anions. Spectroscopic methods were used to validate the structures of the lab-synthesized ILs. We performed an agar well diffusion assay by using pathogenic bacteria that cause various infections (Escherichia coli; Enterobacter aerogenes; Klebsiella pneumoniae; Proteus vulgaris; Pseudomonas aeruginosa; Streptococcus pneumoniae; Streptococcus pyogenes) to scrutinize the in vitro antibacterial activity of the ILs. It was established that the nature and unique combination of the cations and anions were responsible for the antibacterial activity of the ILs. Among the tested ionic liquids, the imidazolium cation and NTf2 and HSO4 anions exhibited the highest antibacterial activity. The antibacterial potential was further investigated by in silico studies, and it was observed that bis(trifluoromethanesulfonyl)imide (NTf2) containing imidazolium and pyridinium ionic liquids showed the maximum inhibition against the targeted bacterial strains and could be utilized in antibiotics. These antibacterial activities float the ILs as a promising alternative to the existing antibiotics and antiseptics.  相似文献   
120.
    
The present work describes the preparation and characterization of a new cobalt(III) porphyrin coordination compound named (chlorido)(nicotinoylchloride)[meso-tetra(para-chlorophenyl)porphyrinato]cobalt(III) dichloromethane monosolvate with the formula [CoIII(TClPP)Cl(NTC)]·CH2Cl2 (4). The single-crystal X-ray molecular structure of 4 shows very important ruffling and waving distortions of the porphyrin macrocycle. The Soret and Q absorption bands of 4 are very red-shifted as a consequence of the very distorted porphyrin core. This coordination compound was also studied by fluorescence and cyclic voltammetry. The efficiency of our four porphyrinic compounds—the H2TClPP (1) free-base porphyrin, the [CoII(TClPP)] (2) and [CoIII(TClPP)Cl] (3) starting materials, and the new Co(III) metalloporphyrin [CoIII(TClPP)Cl(NTC)]·CH2Cl2 (4)—as catalysts in the photochemical degradation was tested on malachite green (MG) dye. The current voltage of complexes 3 and 4 was also studied. Electrical parameters, including the saturation current density (Js) and barrier height (ϕb), were measured.  相似文献   
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