A New Approach to α—Bromochalcones

α-Bromo benzolymethylene triphenylphosphorane 3 has been synthesized by the reaction of benzoylmethylene triphenylphosphorane 1 with N-bromosuccinimide in the yield of 87% and can react with aromatic aldehydes 4 to give α-bromochalcones 5 in good yields.     

A Novel, Simple and Efficient Synthesis of Ferrocenyl Enones and Alkynols

Propargylic alcohols are versatile precursors to many organic molecules including natural products and pharmaceutical compounds.[1] In our continuing interest in the development of practical methods for synthesis of ferrocene derivatives, we decided to investigate the efficiencies of ferrocenylacetylene addition to aromatic aldehydes under t-BuOKcatalyzed condition.[2] Interestingly, we found that the usually reliable coupling reaction between terminal alkyne of type 1 and aromatic aldehydes of type 2 does not furnish the expected propargylic alcohols, but that the isomeric aryl enones 3are found in high yield and very short reaction time (10～20 min). This provided a promising protocol for preparation of ferrocenyl chalcones in a practical, economical and mild sense compared with the traditional method. To the best of our knowledge, this unusual reaction was first observed for the addition of ferrocenylacetylene to aldehyde in a base-catalyzed manner (Eq. 1).     

Synthesis of 2-(α-Hydroxyalkyl)-2-Oxazoline under Microwave Irradiation in Bluk

Four 2-(α-hydroxyalkyl)-2-oxazolines and a 2-(α-hydroxy-α,α-diphenyl)-2-benzooxazole were synthesized from β-amimoalcohols and α-hydroxy carboxylic acids under microwave irradiation in the absence of a solvent.     

Synthesis, Structure and Characterization of [Cu(2,2'-bpy)2][{Cu(2,2'-bpy)2}2W12O40(H2)]·4H2O

An organic-inorganic compound [Cu(2,2'-bpy)2][{Cu(2,2'-bpy)2}2W12O4o(H2)]·4H2O (Mr = 4048.00) was prepared from the hydrothermal reaction of Na2WO4·2H2O, CuCl2·2H2O,2,2'-bipyridine (2,2'-bpy) and H2O at 160 ℃ for 4 days. The compound crystallizes in the monoclinic system, space group P21/n with a = 18.9196(8), b = 20.4212(8), c = 21.8129(9)(A), β=96.992(3)°, V= 8365.0(6) (A)3, Dc= 3.214 g/cm3, Z = 4,μ(MoKα) = 17.269 mm-1 and F(000) = 7324.Of the 119837 total reflections, 17315 were unique (Rint = 0.0489). The final R = 0.0385 and wR =0.0770 for 11142 observed reflections with I ＞ 2σ(I). Single-crystal X-ray diffraction reveals that the structure is composed of [{Cu(2,2'-bpy)2}2W12O40(H2)]2- anions, discrete [Cu(2,2'-bpy)2]2 cations and lattice water molecules, and the anion is made up of a {W12O40(H2)}6- α-Keggin core decorated with two {Cu(2,2'-bpy)2}2 groups through bridging oxygen atoms.     

神光-Ⅱ装置三倍频实验中靶场单元技术的改进

 主要介绍为了满足神光-Ⅱ高功率激光装置三倍频光（351nm，3ω）的物理实验要求，靶场三倍频模拟光源和瞄准监视系统两个主要单元技术的改进，即三倍频模拟光源由基频光（1 053nm，3ω）通过腔外的KTP+BBO晶体倍频获得，再经八路分光系统和主激光耦合；瞄准监视系统由透射式光学系统改进为反射式光学系统，避免原系统存在较大的色差，提高瞄准精度。     

一维对称光量子阱结构多通道滤波特性研究

利用传输矩阵法研究了一维对称光量子阱结构的多通道滤波特性,发现该结构的多透射峰具有分布对称、近似等间距和高透射率等特点,且峰值位置能利用等效理论近似解析求出.透射峰的数目可通过阱区结构参量确定和进行调整,结构的光子禁带范围可通过材料参量的选择获得极大的展宽.该结构只采用两种材料,结构简单,易于制作,具有较大的材料选择性.     

基于Labview的光学空间滤波远程虚拟实验

提出了一种利用Labview实现光学空间滤波模拟的新方法,并对经典的阿贝-波特实验设计了仿真程序.该程序可根据用户设置的参量生成二维网格光栅作为整个物理过程的输入物,允许用户选择多种不同的滤波方式,如低通、高通、方向滤波等,并可依次操纵成像的各个步骤.程序可脱离编程环境独立运行,具有跨平台、界面友好、易于操作等优点,并可架设基于浏览器的远程虚拟实验.     

高温高压下β相硼的电导率测量

 硼在高压下具有复杂的结构和多样的物理性质,对其结构和性质的深入研究具有很重要的意义,一直引起理论和实验研究领域的关注。高压下进行电学性质测量是获得物质物理性质的有效手段,利用集成在金刚石对顶砧上的微电路,在高压下和两个不同温度范围内对β相硼进行了电导率测量,分析了导电机制随压力的变化规律。在0～28.1 GPa范围内,β相硼的电导率随着压力的增大是逐渐增大的,卸压后样品的电导率不能回到最初的状态,是一个不可逆的变化过程;由室温到423 K的范围内,β硼的电导率随着温度的不断增加有明显的上升趋势,并且随着压力的升高,电导率变化逐渐加快。此外,对样品在14.5 GPa和18.6 GPa压力下,用溅射到金刚石对顶砧上的氧化铝薄膜做绝热层,对样品进行了激光加热实验,最高温度达到2 224 K,电导率随着温度的上升而增大,结果显示,β相硼的电学特征仍然属于半导体的特征范围内。     

Dynamic Properties of Two-Dimensional Polydisperse Granular Gases

We propose a two-dimensional model of polydisperse granular mixtures with a power-law size distribution in the presence of stochastic driving. A fractal dimension D is introduced as a measurement of the inhomogeneity of the size distribution of particles. We define the global and partial granular temperatures of the multi-component mixture. By direct simulation Monte Carlo, we investigate how the inhomogeneity of the size distribution influences the dynamic properties of the mixture, focusing on the granular temperature, dissipated energy, velocity distribution, spatial clusterization, and collision time. We get the following results: a single granular temperature does not characterize a multi-component mixture and each species attains its own "granular temperature"; The velocity deviation from Gaussian distribution becomes more and more pronounced and the partial density of the assembly is more inhomogeneous with the increasing value of the fractal dimension D; The global granular temperature decreases and average dissipated energy per particle increases as the value of D augments.     

区间数互补判断矩阵的拓扑排序方法

提出了方案之间进行比较时优于与劣于的定义,通过构造与区间数互补判断矩阵相对应的有向图的方法,将互补判断矩阵的排序问题转化为有向图中顶点的拓扑排序问题,将有向图中的顶点按照备选方案的重要性顺序输出,得到的顶点的序列即为备选方案的重要性排序,数值计算实例验证了该方法的有效性与可行性。