全文获取类型
收费全文 | 94篇 |
免费 | 1篇 |
专业分类
化学 | 34篇 |
数学 | 9篇 |
物理学 | 52篇 |
出版年
2021年 | 1篇 |
2018年 | 1篇 |
2016年 | 2篇 |
2013年 | 3篇 |
2011年 | 1篇 |
2009年 | 1篇 |
2008年 | 2篇 |
2007年 | 2篇 |
2005年 | 1篇 |
2004年 | 1篇 |
2003年 | 1篇 |
2002年 | 3篇 |
2001年 | 2篇 |
2000年 | 2篇 |
1999年 | 2篇 |
1996年 | 7篇 |
1995年 | 6篇 |
1994年 | 6篇 |
1993年 | 3篇 |
1992年 | 9篇 |
1991年 | 3篇 |
1990年 | 4篇 |
1988年 | 3篇 |
1987年 | 5篇 |
1986年 | 4篇 |
1985年 | 2篇 |
1984年 | 2篇 |
1983年 | 2篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1977年 | 1篇 |
1976年 | 3篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1972年 | 1篇 |
1971年 | 1篇 |
1970年 | 1篇 |
1893年 | 1篇 |
1887年 | 1篇 |
1886年 | 1篇 |
排序方式: 共有95条查询结果,搜索用时 15 毫秒
81.
Klaus Angermund Michael Bühl Eckhard Dinjus Uwe Endruschat Franz Gassner Heinz‐Günter Haubold Josef Hormes Gesa Khl Frank Thomas Mauschick Hartwig Modrow Reinhard Mrtel Richard Mynott Bernd Tesche Thomas Vad Norbert Waldfner Helmut Bnnemann 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2002,114(21):4213-4216
82.
83.
Perfluoromethyl-Element-Ligands. XXXV. Reactivity of Metallated Phosphanes and Arsanes of the Type π-C5H5(CO)3MER2 (M ? Cr, Mo, W; E ? P, As; R ? CF3, CN) The influence of the complex fragments π-C5H5(CO)3M (M ? Cr, Mo, W) on the basicity of the metallated phosphanes or arsanes π-C5H5(CO)3MER2 (E ? P, As; R ? CF3, CN) has been investigated by reactions with sulfur, methyliodide, fluorotrichloromethane, and W(CO)5THF, respectively. π-C5H5(CO)3ME(CF3)2 (E ? P: 1a–c ; E ? As: 2a–c ) react with sulfur only for E ? P to give the complexes π-C5H5(CO)3P(S)(CF3)2 ( 5a–c ) in good yield. The attempted thermal transformation of the phosphane sulfides to η2 coordinated (CF3)2P?S complexes proves unsuccessful. The reactions of 1a–c, 2a–c and π-C5H5(CO)3MP(CN)2 ( 3a–c ) with CH3I or CCl3F do not lead to onium salts, but to cleavage of the M–E bonds forming π-C5H5(CO)3MX (X ? I, Cl) and CH3ER2 and R2ECCl2F, respectively. The reactivity depends on ER2 and M: P(CF3)2 > P(CN)2 > As(CF3)2; Cr > Mo > W. Due to the low donor ability of the complexes 1a–c, 2a–c and 3a–c binuclear compounds π-C5H5(CO)3MER2W(CO)5 (E ? As, R ? CF3: 11a–c ; E ? P, R ? CN: 12a–c ; ER2?P(CN)Ph: 13a, b ) are obtained only with the highly reactive W(CO)5THF. In case of the (CF3)2P bridged derivatives spontaneous CO-elimination leads to the threemembered ring systems ( 10a–c ). 相似文献
84.
85.
Tetraphosphorus Trithio Dihalides and Pseudohalides P4S3Cl2, P4S3Br2, P4S3(CN)2 and P4S3(NCS)2 were prepared by reacting α-P4S3I2 with the corresponding silver halides and pseudohalides, respectively. The 31P n.m.r. data of the compounds are reported. 相似文献
86.
Values for the specific rates of solvolysis of the benzhydryldimethylsulfonium ion in 34 solvents have been analyzed using various forms of the extended Grunwald-Winstein equation. The specific rates are insensitive toward changes in solvent nucleophilicity (N(T)) values, and they correlate best against a combination of Y(+) values (based on the solvolyses of the 1-adamantyldimethylsulfonium ion) and aromatic ring parameter (I) values. Common-molecule return is observed, being especially powerful in solvents rich in fluoro alcohol; the logarithm of the associated mass law constant correlates inversely with the solvent N(T) values. The product selectivities in ethanol-water mixtures are also consistent with an S(N)1 mechanism for the solvolyses. 相似文献
87.
88.
89.
90.