Synthesis of a benzoxazine with precisely two phenolic OH linkages and the properties of its high‐performance copolymers

A phenolic OH‐containing benzoxazine ( F‐ap ), which cannot be directly synthesized from the condensation of bisphenol F, aminophenol, and formaldehyde by traditional procedures, has been successfully prepared in our alternative synthetic approach. F‐ap was prepared by three steps including (a) condensation of 4‐aminophenol and 5,5'‐methylenebis(2‐hydroxybenzaldehyde) (1) , (b) reduction of the resulting imine linkage by sodium borohydride, and (c) ring closure condensation by formaldehyde. The key starting material, (1) , was prepared from 2‐hydroxybenzaldehyde and s‐trioxane in the presence of sulfuric acid. F‐ap is structurally similar to bis(3,4‐dihydro‐2H‐3‐phenyl‐1,3‐benzoxazinyl)methane ( F‐a, a commercial benzoxazine based on bisphenol F/aniline/formaldehyde) except for two phenolic OHs. The phenolic OHs can provide reaction sites with epoxy and 1,1'‐(methylenedi‐p‐phenylene)bismaleimide (BMI). The structure–property relationships between the thermosets of F‐ap /epoxy, F‐a /epoxy, F‐ap /BMI, and F‐a /BMI were discussed. Experimental data showed that thermosets based on F‐ap /epoxy and F‐ap /BMI provided much better thermal properties than those based on F‐a /epoxy and F‐a /BMI. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 2686–2694     

Synthesis of two dihydropyrroloindoledione‐based copolymers for organic electronics

Two novel dihydropyrroloindoledione (DPID)‐based copolymers have been synthesized in a two directional approach and characterized (gel permeation chromatography (GPC), ultraviolet‐visible (UV–vis), cyclic voltammetry, and computational models). These planar, broad absorption copolymers show promise for use in organic electronics, with deep energy levels and low bandgaps. The two‐directional Knoevenagel condensation used demonstrates the versatility of DPID as a useful yet underexploited conjugated unit. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013     

氮化镓外延单晶中束缚激子辐射复合的偏振特性

研究发现,氮化镓外延单晶中束缚于中性施主中心和受主中心上的束缚激子BED°和BEA°的复合发光,具有偏振特性。这种偏振特性,会随激发光的强度发生变化。当激发光的强度在104W/cm2和106W/cm2间变化时,偏振度首先以二次方的规律随激发光强的增强而增加,而后超于饱和。本文首先用单轴晶体中介电函数的各向异性解释了荧光固有偏振度的起因,继而采用束缚激子间相互作用的电偶极子模型解释了荧光偏振度随激发光光强的变化规律。     

汉语句法的分段循环分析策略

定义了汉语的分段语法，并根据自然语言的分段循环结构，提出了汉语的分段循环分析策略．它的基本思想是确定语言的一组基本范畴，其相应的句法规则段及其之间的优先关系，对于每一个句法规则段，分别依次采用改进的Ｋｉｌｂｕｒｙ算法、它的优点在于分析过程中的项目集比较小，而且避免了无用分析树的产生，从而大大提高了分析效率．     

光场显微镜实现裸眼三维实时显示

提出了一种将光场显微镜与裸眼三维显示技术相结合的方法,实现了利用光场显微镜对微观样品进行三维裸眼实时观察的技术。该技术将光场显微镜得到的子图像阵列直接投影在微透镜阵列的焦平面上,在空间一定区域内双眼可分别观看到两幅不同视角图像,使观察者产生立体视觉。该系统具有结构简单,无需相干光源,无需佩戴特殊眼镜,可多人同时观看等优点,应用前景广泛。