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951.
Using the full-potential linearized augmented plane wave (FP-LAPW) method, we have studied the effect of chemistry on the average intercalation voltage (AIV) caused by the Na ions intercalating into transition metal oxides. The effect of transition metal was systematically studied by varying M=Co, Ni and Mn in NaMO2 and fixing the α-NaFeO2 layered structure. The effect of the guest atoms into the host material is discussed in terms of the structural and electronic properties. Comparatively to Li intercalation, a significant electron transfer towards transition metal was found. This observation suggests that the transition metal contribute to the AIV determination and confirms the common assumption that intercalated electron reduces M4+ to M3+. 相似文献
952.
Richard P. Stanley 《Israel Journal of Mathematics》2004,143(1):317-339
We survey three recent developments in algebraic combinatorics. The first is the theory of cluster algebras and the Laurent
phenomenon of Sergey Fomin and Andrei Zelevinsky. The second is the construction of toric Schur functions and their application
to computing three-point Gromov-Witten invariants, by Alexander Postnikov. The third development is the construction of intersection
cohomology for nonrational fans by Paul Bressler and Valery Lunts and its application by Kalle Karu to the torich-vector of a nonrational polytope. We also briefly discuss the “half hard Lefschetz theorem” of Ed Swartz and its application
to matroid complexes.
Partially supported by NSF grant #DMS-9988459. 相似文献
953.
Mieko Tanaka-Yamawaki 《Annals of the Institute of Statistical Mathematics》2003,55(2):437-446
Contrary to the common sense in economics and financial engineering, price fluctuations at very fine level of motion exhibit
various evidences against the efficient market hypothesis. We attempt to investigate this issue by studying extensive amount
of foreign currency exchange data for over five years at the finest level of resolution. We specifically focus on the proposed
stability in binomial conditional probabilities originally found in much smaller examples of financial time series. In order
to handle very large data, we have written an efficient program in C that automatically generates those conditional probabilities.
It is found that the stability is maintained for extremely large time duration that covers almost the entire period. Based
on the length of conditions for which the conditional probabilities are distinguishable each other, we identify the length
of memory being less than 3 movements. 相似文献
954.
Under suitable assumptions, a functional central limit theorem is obtained for a three-dimensional model of Maxwellian molecules. This model is related to a nonlinear Boltzmann-type equation. It will be proved that the family of the distributions induced by fluctuation processes converges weakly. 相似文献
955.
Elvira Vidović Doris Klee Hartwig Höcker 《Journal of polymer science. Part A, Polymer chemistry》2007,45(19):4536-4544
Poly(D ,L ‐lactide) and poly(D ,L ‐lactide‐co‐glycolide) with various composition and with one methacrylate and one carboxylate end group were synthesized and grafted onto poly(vinyl alcohol) (PVA) via the carboxylate group. The graft copolymers were crosslinked via the methacrylate groups using a free radical initiator. The polymer networks were characterized by means of NMR and studied qualitatively by means of IR spectroscopy. The influence of the glycolide content in the polyester grafts and of the number of ester units in the grafts on thermal properties and swellability were studied as well. The high swellability in water is characteristic of all hydrogels. Differential scanning calorimetry (DSC) showed a single glass transition temperature that occurs in the range between 51 and 69 °C. Thermogravimetric analysis (TGA) of the networks showed the main loss in weight in the temperature range between 290 and 370 °C. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4536–4544, 2007 相似文献
956.
Elżbieta Godlewska M. Mitoraj F. Devred B. E. Nieuwenhuys 《Journal of Thermal Analysis and Calorimetry》2007,88(1):225-230
A Ti–45.9Al–8Nb
(at%) alloy with a lamellar structure (γ+α2)
was oxidised in air at 700, 800, 850 and 900°C in isothermal and thermal
cycling conditions. The reaction progress was followed by thermogravimetric
measurements. In isothermal conditions the oxidation kinetics followed approximately
a parabolic rate law and the rate constants ranged from about 10–12
kg2 m–4 s–1
at 700°C to 10–10 kg2
m–4 s–1
at 900°C. The oxide scales were built of Al2O3
and TiO2, the former being the main component of the
outermost layer. The oxidation behaviour of Ti–45.9Al–8Nb was
referred to a commercial titanium alloy, WT4 (Ti–6Al–1Mn), and
selected oxidation-resistant alloys. 相似文献
957.
All homothetic self-similar solutions of the Brans-Dicke scalar field in three-dimensional spacetime with circular symmetry
are found in closed form. 相似文献
958.
Fabio Scardigli 《Foundations of Physics》2007,37(8):1278-1295
The Titius–Bode law for planetary distances is reviewed. A model describing the basic features of this rule in the “quantum-like”
language of a wave equation is proposed. Some considerations about the ’t Hooft idea on the quantum behavior of deterministic
systems with dissipation are discussed. 相似文献
959.
JPC – Journal of Planar Chromatography – Modern TLC - Emodin and twelve phenolic acids (ellagic, gallic, protocatechuic, homoprotocatechuic, caffeic, p-hydroxybenzoic, p-coumaric,... 相似文献
960.
J. L. Souza A. F. Santos L. Polese Marisa S. Crespi C. A. Ribeiro 《Journal of Thermal Analysis and Calorimetry》2007,87(3):673-677
Poly(3-hydroxybutyrate), PHB has been structurally
modified through reaction with maleic anhydride, MA. Transesterification reaction
was carried out fixing the PHB and MA and besides time and temperature the
concentration of the triethylamine (used as catalyst) was changed. Glass transition,
melting and crystallization temperature obtained from DSC curves and thermal
degradation temperatures obtained from TG traces were used to evaluate the
influence of the reaction conditions on the modification of PHB according
to factorial design. On the base of the results the optimum conditions are
to perform the PHB modification reaction with MA reaction at 110°C for
1 h with 5% v/v triethylamine. 相似文献