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81.
Kukovecz A Hodos M Horváth E Radnóczi G Kónya Z Kiricsi I 《The journal of physical chemistry. B》2005,109(38):17781-17783
We discuss the formation mechanism of titania nanotubes synthesized by the hydrothermal method. On the basis of a comprehensive analysis of TEM, HRTEM, FT-Raman, and N(2) adsorption data, we point out some major shortcomings of the currently accepted trititanate sheet rollup mechanism. We suggest that a novel formation mechanism, oriented nanotube crystal growth from nanoloop seeds, can explain the experimental findings better than the ones proposed so far. 相似文献
82.
A shear cell was constructed in two variants for simultaneous small-angle X-ray scattering and freeze fracture. Using this cell, the changes in the layer structure and the domain formation of the Synperonic A7-water system were investigated under shear. The reconstructions of both the layer and domain structures were not observed in the steady state after 1 h (following a 2 h long shear period). Destruction of the lamellar arrangement and formation of aggregates occurred during the stress. It was concluded that the tixotropic behavior originates rather from the change of the domain structure with a typical size range of microm than from the changes of the inner structure of domains with lamellar arrangement. 相似文献
83.
Varga L Nagy T Dorman G Kalman F Urge L Darvas F 《Journal of combinatorial chemistry》2006,8(3):338-343
We present here the discovery of a novel, versatile, multicomponent reaction leading to various 4-[4-(pyridinium-1-yl)-2,5-dioxo-2,5-dihydro-1H-pyrrol-3-yl]-2H-pyrazol-3-olate inner salts. The structure of the unusual zwitterionic inner salts was elucidated, and the scope of the novel reaction was investigated. After rapid optimization, the reaction was adapted to parallel synthesis, and an 800-membered compound library was produced. 相似文献
84.
Attila Benkő György Dósa Zsolt Tuza 《Central European Journal of Operations Research》2013,21(4):805-816
In the recent paper (Benk? et al. 2010) we introduced a new problem that we call Bin Packing/Covering with Delivery, or BP/CD for short. Mainly we mean under this expression that we look for not only a good, but a “good and fast” packing or covering. In the present paper we investigate the offline case. For the analysis, a novel view on “offline optimum” is introduced, which appears to be relevant concerning all problems where a final solution is ordering-dependent. We prove that if the item sizes are not allowed to be arbitrarily close to zero, then an optimal offline solution can be found in polynomial time. On the other hand, for unrestricted problem instances, no polynomial-time algorithm can achieve an asymptotic approximation ratio better than 6/7 if $P\ne NP$ . 相似文献
85.
György Keglevich Andrea Kerényi Helga Szelke Timea Imre 《Transition Metal Chemistry》2006,31(3):306-309
Reaction of a series of P-amino and P-cycloalkoxy dibenzo[c.e][1,2]oxaphosphorines (1), (3) and (5) with cis-bis(benzonitrile)dichloroplatinum(II) afforded the title bis(dibenzooxaphosphorino) complexes (2), (4) and (6), respectively. In the case of chiral P-substituents, the complexes (4) and (6) were obtained in homo and heterochiral forms. Stereospecific 1J(195Pt–P) couplings found in the 31P-n.m.r. spectra of the products (2), (4) and (6) suggested the cis orientation of the identical substituents. 相似文献
86.
I. Kirschner I. Halász T. Träger J. Tóth Gy. Kovács T. Porjesz G. Zsolt T. Kármán 《Zeitschrift für Physik B Condensed Matter》1988,73(3):293-297
Different heat treatment procedures were applied during sample preparation, which resulted in different superconducting properties in samples of the same nominal composition, TlCaBa2Cu3O7.5±d
. This manifests itself in different critical temperatures: 104 K, 107 K and 93 K. The highestT
c belongs to the best-crystallized samples in which the tetragonal Tl2Ca1Ba2Cu2O8±d
phase is responsible for the superconductivity. The effect of heat treatments is reflected in the structural and magnetic properties as well. 相似文献
87.
D. Medaković Gy. Batta I. F. Pelyvás F. Sztaricskai 《Journal of carbohydrate chemistry》2013,32(5):631-641
ABSTRACT A new reducing trisaccharide 0-α-D-arabinofuranosyl-(1→ 2)-0-α-D-mannopyranosyl-(1→2)-0-D-glucopyranose (11), named ristriose, has been synthesized in twenty one steps, starting from D-glucose, D-mannose and D-arabinose, with an overall yield of 3.5 %. 相似文献
88.
Dr. Györgyi Váradi Prof. Gábor K. Tóth Dr. Zoltán Kele Dr. László Galgóczy Ádám Fizil Prof. Gyula Batta 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(38):12684-12692
The folding of disulfide proteins is of considerable interest because knowledge of this may influence our present understanding of protein folding. However, sometimes even the disulfide pattern cannot be unequivocally determined by the available experimental techniques. For example, the structures of a few small antifungal proteins (PAF, AFP) have been disclosed recently using NMR spectroscopy but with some ambiguity in the actual disulfide pattern. For this reason, we carried out the chemical synthesis of PAF. Probing different approaches, the oxidative folding of the synthetic linear PAF yielded a folded protein that has identical structure and antifungal activity as the native PAF. In contrast, unfolded linear PAF was inactive, a result that may have implications concerning its redox state in the mode of action. 相似文献
89.
90.
Forced ideal carbocationic copolymerization of isobutylene and isoprene has been achieved by continuous addition of monomer mixtures of different compositions to cumyl chloride/TiCl4 charges at -50°C. The overall rate of copolymerization could be kept equal to that of addition rate with up to 10 mol% isoprene in the mixed monomer feed. In this monomer concentration range the composition of the copolymer was identical to that of the feeds. At higher diene concentrations in the feed, chain transfer to monomer and other side reactions (intramolecular cyclization, gel formation) could not be completely avoided. The number-average molecular weight of the copolymers increased almost linearly with the amount of consumed monomers at 10 mol% isoprene concentrations in the feed (i.e., in the quasiliving range). According to 1H-NMR and 13C-NMR spectroscopy, the products are random copolymers. 相似文献