首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   8517篇
  免费   1388篇
  国内免费   1253篇
化学   6599篇
晶体学   146篇
力学   460篇
综合类   77篇
数学   869篇
物理学   3007篇
  2024年   30篇
  2023年   190篇
  2022年   314篇
  2021年   358篇
  2020年   441篇
  2019年   443篇
  2018年   322篇
  2017年   352篇
  2016年   417篇
  2015年   439篇
  2014年   506篇
  2013年   678篇
  2012年   737篇
  2011年   807篇
  2010年   567篇
  2009年   495篇
  2008年   584篇
  2007年   464篇
  2006年   419篇
  2005年   350篇
  2004年   265篇
  2003年   234篇
  2002年   270篇
  2001年   189篇
  2000年   170篇
  1999年   135篇
  1998年   103篇
  1997年   104篇
  1996年   104篇
  1995年   107篇
  1994年   98篇
  1993年   82篇
  1992年   56篇
  1991年   48篇
  1990年   44篇
  1989年   50篇
  1988年   30篇
  1987年   25篇
  1986年   27篇
  1985年   36篇
  1984年   19篇
  1983年   15篇
  1982年   10篇
  1981年   10篇
  1980年   4篇
  1979年   2篇
  1977年   2篇
  1971年   1篇
  1959年   2篇
  1957年   3篇
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
951.
A theory is proposed for the special complex cavity; it is in the form of a single resonant circuit having a TE0n&lrarr2;TE0,n+p mode converter and it features excellent mode selectivity, high power capability, and an asymmetric triangle profile of the RF field that is favourable to efficient operation for a 35-GHz second-harmonic gyromonotron employing this complex cavity with TE03 mode output are numerically illustrated and experimentally demonstrated. Power as high as 200 kW and efficiency as high as 30% have been obtained. These experimental results are record values for a gyrotron operating at the second-harmonic millimeter wavelength. Implications of the single-resonant complex cavity for the fundamental harmonic and third-harmonic high-average-power gyrotron design are discussed  相似文献   
952.
We propose a 4-velocity unidimensional discrete Boltzmann model with two different speeds 2, 1 and two different masses 1, 2. With the three conservation laws of mass, momentum, and energy satisfied, we can introduce a nontrivial temperature. First, we determine the similarity shock waves satisfying physical properties: positivity, shock stability, inequalities of the subsonic and supersonic flows, increase or decrease of both mass and temperature across the shock. It results that either the speed of the shock front is higher than the speed 1 of the slow particles and the shocks are compressive or less than 1 and the shocks are rarefactive. We observe overshoots of the temperature, across the shock, with bumps higher and higher as the shock front speed increases. Second, we study the (1+1)-dimensional shock waves. They represent the superposition and collision of two compressive shocks traveling in opposite directions and we observe temperature overshoots for not too large times.  相似文献   
953.
2003年8月开始,我应邀参加了物理通报教材研究中心组织的高中物理改革教材的编写工作.在编写过程中,如何领会与掌握“坚持时代性与基础性相结合原则”一直是大家关注的一个热点问题.本文介绍一下我对这一问题的思考与认识以及在教材编写中的一些具体做法.抛砖引玉,希望更多同志参与探讨.  相似文献   
954.
CH2?CHCH2CpTiCl3 (1), CH2?CHCH2CH2CpTiCl3 (2) and CH3CH2CH3CpTiCl3 (3) have been synthesized and characterized. The influence of the alkenyl substituent groups on the catalyst activities in the syndiotactic polymerization of styrene was investigated. The catalyst activities decreased in the order CH2?CHCH2CH2CpTiCl3 > CH3CH2CH2CH2CpTiCl3 > CH3CH2CH2CpTiCl3 > CH2?CHCH2CpTiCl3 (Cp?C5H4). By using complex 1, the dependence of the activity on the concentration of methylaluminoxane, triisobutylaluminum and diisobutylaluminum hydride was investigated. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   
955.
956.
Summary. The dynamical behavior of the damped sine-Gordon equation with homogeneous Neumann boundary condition is studied. It is shown that the equation has an unbounded one-dimensional global attractor in a suitable functional space when the ``damping' and the ``diffusing' are not very small. Received March 16, 1999; accepted December 10, 1999  相似文献   
957.
A novel hyperbranched polyyne (hb‐ DPP ) with triphenylamine as the core, 2,5‐dioctylpyrrolo [3,4‐c]pyrrole‐1,4 (2H,5H)‐dione ( DPP ) as the connecting unit has been designed and synthesized by Glaser‐Hay oxidative coupling reaction, which was characterized by IR, NMR, UV‐vis, FL, and GPC. The polymer exhibits high molecular weight (Mw up to ~6.55 × 104 Da) and is readily soluble in common organic solvents such as toluene, chloroform, tetrahydrofuran, N,N‐dimethyl formamide and so on. The one‐ and two‐photon absorption (TPA) properties have been investigated. The TPA cross section of the polymer was measured by open‐aperture Z‐scan experiment using 140 femtosecond (fs) pulse, and the TPA cross section for hb‐ DPP was determined to be 579 GM per repeating unit at wavelength of 800 nm. In tetrahydrofuran, hb‐ DPP exhibits intense frequency up‐converted fluorescence with the peak located at 584 nm under the excitation of 800 nm fs pulses. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 4400–4408, 2009  相似文献   
958.
Novel AB2‐type amphiphilic block copolymers of poly(ethylene glycol) and poly(N‐isopropylacrylamide), PEG‐b‐(PNIPAM)2, were successfully synthesized through single‐electron transfer living radical polymerization (SET‐LRP). A difunctional macroinitiator was prepared by esterification of 2,2‐dichloroacetyl chloride with poly(ethylene glycol) monomethyl ether (PEG). The copolymers were obtained via the SET‐LRP of N‐isopropylacrylamide (NIPAM) with CuCl/tris(2‐(dimethylamino)ethyl)amine (Me6TREN) as catalytic system and DMF/H2O (v/v = 3:1) mixture as solvent. The resulting copolymers were characterized by gel permeation chromatography and 1H NMR. These block copolymers show controllable molecular weights and narrow molecular weight distributions (PDI < 1.15). Their phase transition temperatures and the corresponding enthalpy changes in aqueous solution were measured by differential scanning calorimetry. As a result, the phase transition temperature of PEG44b‐(PNIPAM55)2 is similar to that in the case of PEG44b‐PNIPAM110; however, the corresponding enthalpy change is much lower, indicating the significant influence of the macromolecular architecture on the phase transition. This is the first study into the effect of macromolecular architecture on the phase transition using AB2‐type amphiphilic block copolymer composed of PEG and PNIPAM. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 4420–4427, 2009  相似文献   
959.
周倩  万宝年  吴振伟  黄娟 《中国物理》2005,14(12):2539-2545
The line-integrated optical measurement of impurity radiation profiles for the study of light impurity transport is performed in the HT-7 tokamak. The carbon impurity line emissivity is obtained by Abel inversion. The radial transport behaviours of carbon impurities at different central line averaged electron densities ne are investigated in ohmic discharges. The diffusion coefficient Dk(r), the convection velocity Wk(r) and the total flux of the impurity ions Fk decrease with the increase of ne, which shows a reduction in the impurity particle transport at higher electron densities.  相似文献   
960.
In this paper, fluorescence correlation spectroscopy (FCS) was applied to measure the size of water-soluble quantum dots (QDs). The measurements were performed on a home-built FCS system based on the Stokes-Einstein equation. The obtained results showed that for bare CdTe QDs the sizes from FCS were larger than the ones from transmission electron microscopy (TEM). The brightness of QDs was also evaluated using FCS technique. It was found that the stability of the surface chemistry of QDs would be significantly improved by capping it with hard-core shell. Our data demonstrated that FCS is a simple, fast, and effective method for characterizing the fluorescent quantum dots, and is especially suitable for determining the fluorescent nanoparticles less than 10 nm in water solution.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号