矩形域上散乱数据多元最优插值的误差估计及其超收敛性（Ⅰ）──带连续边界条件

本文我们讨论了矩形域上带连续边界条件的一类多元散乱数据最优插值。给出了某些情形插值的误差估计，误差估计表明在某些点上还具有超收敛性。     

一种新的数字式多媒体图像采集系统

本文以多媒体概念为指导思想，论述了一种新的数字式多媒体图像采集系统。它采用多制式数字解码器、视频窗口控制器等超大规模集成电路芯片构成，较之以往的模拟式图像采集系统有本质区别     

Discriminant Analysis for Regression Models with Stationary Long-Memory Disturbances

We shall consider the problems of classifying an observation from regression model with stationary long-memory or short-memory disturbances into one of two populations described by the mean functions of the model. We use the log-likelihood ratio as a discrimant statistic which is optimal in the sense of its minimizing the misclassification probabilities. Then we confirm the theoretical results by some simple polynomial regression models.     

便携式条形码阅读器的设计

本设计为一种便携式条形码阅读译码器（简称阅读器），它采用ＩＮＴＥＬ８０３１ＣＰＵ微处理器为主芯片，辅以其它大规模集成电路芯片，构成一智能化系统，阅读及识别采用Ｃｏｄｅ３９码编制的条形码，并能完成条形码信息的存储、数目统计及与微机进行串行通信功能。     

Design,synthesis and biological evaluation of some novel <Emphasis Type="Italic">N</Emphasis>-arylpyrazole derivatives bearing the sulfonamide moiety as cytotoxic agents

A series of novel N-arylpyrazole derivatives (4a–4l) bearing the sulfonamide moiety were synthesized by the condensation reaction of 1,3-dicarbonyl compounds with 4-hydrazinylbenzenesulfonamide. The structures of the obtained compounds were established on the basis of elemental (C, H, and N) and spectral analysis (¹H NMR, ¹³C NMR, ESIMS, and FT-IR). These compounds were tested for their in vitro cytotoxic activity against three human tumor cell lines: MCF-7, Hela, and A549. The results showed that most of the obtained compounds exhibited promising cytotoxicity against the tested cell lines with low IC₅₀ values. The pyrazole derivative 4k, bearing two methoxy groups on the 3-position and 4-position of the phenyl ring, was the most effective one. Its inhibition of cell growth of MCF-7 cells was better than that of celecoxib and cisplatin.     

全自动在线固相萃取-液相色谱-高分辨质谱法测定麦卢卡蜂蜜中的特征标志物

建立了全自动在线固相萃取-液相色谱-高分辨质谱(SPE-LC-HRMS)测定麦卢卡蜂蜜中特征标志物3,5-二甲氧基苯甲酸甲酯-4-双葡萄糖糖苷(leptosperin)的方法。以Dikma Diamonsil Plus C_(18)色谱柱(150 mm×4.6 mm,5μm)为分析柱,0.1%(v/v)甲酸水溶液-乙腈为流动相进行梯度洗脱,在电喷雾负离子、目标二级离子扫描模式下进行检测,外标法定量。结果表明,在0.5~100.0 mg/L范围内该分析物的线性关系良好,相关系数为0.999 3,方法的检出限(LOD,S/N≥3)和定量限(LOQ,S/N≥10)分别为3 mg/kg和10 mg/kg。在不同蜂蜜样品中分别添加50.0、100.0、200.0 mg/kg(洋槐蜜中添加10.0、20.0、50.0 mg/kg)特征化合物标准品进行加标回收率试验,平均回收率为82.0%~95.2%,相对标准偏差为2.7%~9.7%(n=6)。利用该方法对来自新西兰12种不同品种的95个蜂巢成熟原蜜和来自4个国家50个商品化蜂蜜进行了验证。该法快速、灵敏、准确,可为解决进口新西兰麦卢卡蜂蜜的判别难题提供技术支持。     

局部载荷作用简支板屈曲分析

根据能量原理,引入大挠度Von-Karman方程,求解了应力不连续简支板的屈曲问题,得到了临界载荷和临界应力计算系数.     

Nickel-catalyzed cross-coupling of primary alkyl halides with phenylethynyl- and trimethylsilyethynyllithium reagents

A highly efficient alkyl-alkynyl coupling system is described which is promoted by a well-defined and moisture-stable pincer complex [NiCl{C₆H₃-2,6-(OPPh₂)₂}] (1). Non-activated alkyl halides could be efficiently coupled with phenylethynyl- and trimethylsilylethynyllithium reagents at room temperature. Compared to the alkylation of primary alkyl halides with alkynyllithium reagents in literatures, this method requires milder conditions (room temperature) and proceeds quickly. This research will make these readily available alkynyllithium reagents much more useful for organic synthesis.     

阴离子型含氟两亲接枝共聚物的合成及其胶束化行为研究

以聚乙二醇甲醚甲基丙烯酸酯(MPEGMA)为大分子单体,甲基丙烯酸六氟丁酯(HFMA)、对苯乙烯磺酸钠(NaSS)为共聚单体,采用大分子单体接枝共聚法,制备了一种阴离子型含氟两亲接枝共聚物P( HFMA-co-NaSS) -g-PEG.利用FTIR、1H-NMR和19F-NMR对共聚物的分子结构进行了表征.表面张力法测...