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41.
Anchoring Properties of Nematic Liquid Crystals Studied Using the Attenuated Total Reflection Method
By using the attenuated total reflection method associated with the excitation of surface plasmons, the tilt angle of the liquid crystal director and its gradient at the surface are measured in a planar nematic cell as a function of the applied voltage. The surface anchoring anisotropy δπ of the liquid crystal and the surface elastic constant ks, are found to be δπ = 0.288 erg/cm and ks, = 9·12 × 10-11 erg, respectively, when the boundary condition suggested by Barbero et al is used. The theoretical and experimental values obtained with this boundary condition and that of Mada are discussed. The results show that the boundary condition proposed by Barbero et al is in better agreement with the experiment. 相似文献
42.
43.
利用莫尔条纹的准正弦特性的三维轮廓术 总被引:5,自引:0,他引:5
分析了两个矩形光栅迭合产生的莫尔条纹的光强分布特性,通过选择适当的光栅参数,可得到一个近似的正弦分划板,并把它用于三维面形测量中,实验结果表明,这种方法简单,易于自动处理,有广泛的实用价值。 相似文献
44.
Mingyang Zhao Warren T. Ford Stefan H. J. Idziak Nicholas C. Maliszewskyj Paul A. Heiney 《Liquid crystals》1994,16(4):583-599
The hexa-4-dodecyloxybenzoyl derivative 1 of azacrown [18]-N6 was originally reported to have a 'tubular' mesophase on the basis of its large central ring and 6-fold symmetry. Starting in the mesophase, annealing of 1 under a cover slip results in formation of a new crystalline phase that melts directly to an isotropic liquid at the temperature previously observed for the mesophase to isotropic transition. Thus the phase behaviour of 1 is kinetically controlled. The analogous hexa-3,4-bisdodecyloxybenzoyl derivative 2 of azacrown [18]-N6 has no kinetic limitations to its phase changes and has an enantiotropic columnar liquid crystalline phase. We have synthesized side chain copolysiloxanes with a (CH2)11 spacer and 75-84 per cent by weight of the same 4-dodecyloxybenzoyl-[18]-N6 mesogen. The polysiloxanes also display a liquid crystalline phase. 相似文献
45.
Let φ be a normal function on [0,1) and A'(φ)(1
相似文献
46.
We describe one convenient synthesis route to boron nitride (BN) nanotube by the reaction of boron powder, iron oxide, and ammonium chloride at 600 °C for 12 h. Characterized by XRD, FTIR, XPS, TEM and SAED, the composition and morphology of the products are confirmed. The possible reaction mechanism is also discussed. 相似文献
47.
本文讨论了温度、相变、应力间的耦合关系,给出了铸坯在考虑相变时的热弹塑性蠕变的本构关系,以及计算铸坯内应力的有限元迭代公式。 相似文献
48.
A method has been developed for the qualitative analysis of paeonol, paeoniflorin and their derivatives in Paeoniae Radix by high-performance liquid chromatography-electrospray ionization-mass spectrometry (HPLC-ESI-MS). Gradient elution with acetonitrile-water solvent system was employed in an HPLC-ESI-MS study. The negative-ion ESI mode was suitable for these compounds. The peaks were identified by their mass spectra, UV spectra and fragments of their MS2 spectra. The structures of three unknown compounds are inferred in this paper. 相似文献
49.
Influence of Turbid Medium Parameters on Back Scattered Intensity and Pulsewidth of Picosecond Pulse
In this paper, we simulate a practical in vivo technique in which is produced influence of turbid medium parameters on backscattered intensity and pulsewidth of picosecond for turbid tissue surface of a semiinfinite medium by a small narrow linewidth laser beams. It is shown that the interaction of the ultra short pulse and the turbid tissue is very used as researching the optical parameters of the turbid medium. 相似文献
50.
Yonggang Shangguan Li Zhao Liyang Tao Qiang Zheng 《Journal of Polymer Science.Polymer Physics》2007,45(13):1704-1712
The effects of preparation method, composition, and thermal condition on formation of β‐iPP in isotactic polypropylene/ethylene–propylene rubber (iPP/EPR) blends were studied using modulated differential scanning calorimeter (MDSC), wide angle X‐ray diffraction (WAXD), and phase contrast microscopy (PCM). It was found that the α‐iPP and β‐iPP can simultaneity form in the melt‐blended samples, whereas only α‐iPP exists in the solution‐blended samples. The results show that the formation of β‐iPP in the melt‐blended samples is related to the crystallization temperature and the β‐iPP generally diminishes and finally vanishes when the crystallization temperature moves far from 125 °C. The phenomena that the lower critical temperature of β‐iPP in iPP/EPR obviously increases to 114 °C and the upper critical temperature decreases to 134 °C indicate the narrowing of temperature interval, facilitating the formation of β‐iPP in iPP/EPR. Furthermore, it was found that the amount of β‐iPP in melt‐blended iPP/EPR samples is dependent on the composition and the maximum amount of β‐iPP formed when the composition of iPP/EPR blends is 85:15 in weight. The results through examining the effect of annealing for iPP/EPR samples at melt state indicate that this annealing may eliminate the susceptibility to β‐crystallization of iPP. However, only α‐iPP can be observed in solution‐blended samples subjected to annealing for different time. The PCM images demonstrate that an obvious phase‐separation happens in both melt‐blended and solution‐blended iPP/EPR samples, implying that compared with the disperse degree of EPR in iPP, the preparation method plays a dominant role in formation of β‐iPP. It is suggested that the origin of formation of β‐iPP results from the thermomechanical history of the EPR component in iPP/EPR. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1704–1712, 2007 相似文献