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151.
Chorng‐Shyan Chern Cheng‐Kang Lee Chia‐Che Ho 《Journal of polymer science. Part A, Polymer chemistry》1999,37(10):1489-1499
Stable chitosan‐modified polymethyl methacrylate (PMMA) latex particles were prepared by using 2,2′‐azobis(2‐amidinopropane) dihydrochloride (V‐50) as the cationic initiator. The polymerization rate (Rp) is controlled by the V‐50 concentration ([V‐50]) and Rp is less sensitive to the chitosan concentration ([C]) used in the synthesis work. The reaction system follows Smith–Ewart Case III kinetics due to the relatively large particles produced. The zeta potential data show that the isoelectric point (pI) of the latex particles is 10.7. The amounts of V‐50 (CV‐50) and chitosan (Cc) ultimately incorporated into the particles correlate reasonably well with [V‐50] and [C], respectively. At pH 7, the quantity of the negatively charged bovine serum albumin (BSA, pI = 4.8) adsorbed on the positively charged chitosan‐free particles (Q) via the electrostatic interaction increases with increasing CV‐50. However, Q is relatively insensitive to changes in Cc. This result implies that only the outermost region of the hairy chitosan‐modified particles is available for adsorption of the relatively large protein species. Colloidal stability shows a significant influence on the BSA adsorption process. © 1999 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 37: 1489–1499, 1999 相似文献
152.
Axially chiral allenes are synthesized from chiral propargylamines catalyzed by KAuCl4 in high yields (up to 93% yield) and excellent enantioselectivities (up to 97% ee) in CH3CN at 40 degrees C. The reaction has been applied to the synthesis of novel allene-modified artemisinin derivatives with the delicate endoperoxide moieties remaining intact. A tentative mechanism regarding gold(I)-catalyzed intramolecular hydride transfer was proposed on the basis of deuterium-labeling experiments and ESI-MS analysis of the reaction mixture. 相似文献
153.
Feature extraction plays an important role in the clustering analysis. In this paper an integrated Autoregressive (AR)/Autoregressive Conditional Heteroscedasticity (ARCH) model is proposed to characterize the vibration signal and the model coefficients are adopted as feature vectors to realize clustering diagnosis of rolling element bearings. The main characteristic is that the AR item and ARCH item are interrelated with each other so that it can depict the excess kurtosis and volatility clustering information in the vibration signal more accurately in comparison with two-stage AR/ARCH model. To testify the correctness, four kinds of bearing signals are adopted for parametric modeling by using the integrated and two-stage AR/ARCH model. The variance analysis of the model coefficients shows that the integrated AR/ARCH model can get more concentrated distribution. Taking these coefficients as feature vectors, K means based clustering is utilized to realize the automatic classification of bearing fault status. The results show that the proposed method can get more accurate results in comparison with two-stage model and discrete wavelet decomposition. 相似文献
154.
Yuen MY Kui SC Low KH Kwok CC Chui SS Ma CW Zhu N Che CM 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(47):14131-14141
A series of platinum(II) complexes bearing tridentate cyclometalated C^N^N (C^N^N=6-phenyl-2,2'-bipyridine and π-extended R-C^N^N=3-[6'-(naphthalen-2'-yl)pyridin-2'-yl]isoquinoline) ligands with fluorene units have been synthesised and their photophysical properties have been studied. The fluorene units are incorporated into the cyclometalated ligands by a Suzuki coupling reaction. An increase in the π-conjugation of the cyclometalated ligands confers favourable photophysical properties compared to the 6-phenyl-2,2'-bipyridine analogues. The fluorene-based platinum(II) complexes display vibronic-structured emission bands with λ(max)=558-601 nm, and high emission quantum yields up to 0.76 in degassed dichloromethane. Their emissions are tentatively assigned to excited states with mixed (3)IL/(3)MLCT parentage (IL=intraligand, MLCT=metal-to-ligand charge transfer). The crystal structures of these platinum(II) complexes reveal extensive Pt(II)···π and/or π-π interactions. The fluorene-based platinum(II) complexes are soluble in organic solvents, have high thermal stability with decomposition temperature >350 °C, and can be thermally vacuum-sublimed or solution-processed as phosphorescent dopants for the fabrication of organic light-emitting diodes (OLEDs). A monochromic OLED with 3d as dopant (2 wt%) fabricated by vacuum deposition gave a current efficiency of 14.7 cd A(-1) and maximum brightness of 27000 cd m(-2). A high current efficiency (9.2 cd A(-1)) has been achieved in a solution-processed OLED using complex 3f (5 wt%) doped in a PVK (poly(9-vinylcarbazole)) host. 相似文献
155.
Huang JS Leung SK Cheung KK Che CM 《Chemistry (Weinheim an der Bergstrasse, Germany)》2000,6(16):2971-2981
Bis(N-ethylideneethanamine)ruthenium(ii) porphyrins, [Ru11(Por)(N(Et)=CHMe)2] (Por=TTP, 4-Cl-TPP), were prepared by the reaction of dioxoruthenium(VI) porphyrins with triethylamine in approximately 85% yields. The reaction between dioxoruthenium(VI) porphyrins and benzophenone imine afforded bis(diphenylmethyleneamido)ruthenium(IV) porphyrins, [Ru(IV)(Por)(N=CPh2)2] (Por=TTP, 3,4,5-MeO-TPP), in approximately 65% yields. These new classes of metalloporphyrins were characterized by 1H NMR, UV/Vis, and IR spectroscopy as well as by mass spectrometry and elemental analysis. The X-ray crystallographic structures of [Ru(II)(TTP)(N(Et)=CHMe)2] and [Ru(IV)(3,4,5-MeO-TPP)(N=CPh2)2] revealed an axial Ru-N bond length of 2.115(6) A for the imine complex and 1.896(8) A for the methyleneamido complex. Each of the N=CPh2 axial groups in [Ru(IV)(3,4,5-MeO-TPP)(N=CPh2)2] adopts a linear coordination mode with a corresponding Ru-N-C angle of 175.9(9)degrees. Spectral and structural studies revealed essentially single bonding character for the bis(imine) complexes but a multiple bonding character for the bis(methyleneamido) complexes with respect to their axial Ru-N bonds. 相似文献
156.
Che Ming Ko 《Physics letters. [Part B]》1983,120(4-6):294-296
We show that an important contribution to subthreshold K− production in high energy heavy ion collision is the strangeness exchange reactions Yπ→K---N between the hyperons and pions initially produced in the collision. Estimates are given for the number of K− produced via this mechanism and it accounts for a large fraction of the experimental observation. 相似文献
157.
Dr. Jiwei Liu Junjie Xu Prof. Renchao Che Huajun Chen Mengmei Liu Zhengwang Liu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(21):6746-6752
A facile and efficient strategy for the synthesis of hierarchical yolk–shell microspheres with magnetic Fe3O4 cores and dielectric TiO2 shells has been developed. Various Fe3O4@TiO2 yolk–shell microspheres with different core sizes, interstitial void volumes, and shell thicknesses have been successfully synthesized by controlling the synthetic parameters. Moreover, the microwave absorption properties of these yolk–shell microspheres, such as the complex permittivity and permeability, were investigated. The electromagnetic data demonstrate that the as‐synthesized Fe3O4@TiO2 yolk–shell microspheres exhibit significantly enhanced microwave absorption properties compared with pure Fe3O4 and our previously reported Fe3O4@TiO2 core–shell microspheres, which may result from the unique yolk–shell structure with a large surface area and high porosity, as well as synergistic effects between the functional Fe3O4 cores and TiO2 shells. 相似文献
158.
159.
T. L. Che Q. C. Gao W. P. Zhang Z. X. Nan H. X. Li Y. G. Cai J. S. Zhao 《Russian Journal of Coordination Chemistry》2009,35(10):723-730
Coordination polymers, [Sm2(Pzdc)3(H2O)]
x
· 2xH2O (I) and [Nd2(Pzdc)3(H2O)]
x
· 2xH2O (II), were obtained by hydrothermal reactions with 2,3-pyrazinedicarboxylic acid (H2Pzdc) and the salts nitrates, and characterized by single crystal X-ray structure, thermogravimetric analysis, element analysis
and infrared spectroscopy. The X-ray crystal diffraction data indicates that two complexes crystal in a monoclinic system
with the space group P21/c, of the three dimensional framework. The Pzdc ligand in the complexes I and II adopts tetradentate, hexadentate, and heptadentate
bridging modes. The influences of coordination modes of the Pzdc ligand on the superstructural diversity is discussed. The
photoluminescent data suggest that the ligands act as efficient “antennas” sensitizing the luminescence of the Sm3+ ion. Complex I exhibits strong fluorescent emission bands in the solid state at room temperature. 相似文献
160.