首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   20110篇
  免费   3471篇
  国内免费   2381篇
化学   14116篇
晶体学   183篇
力学   1159篇
综合类   125篇
数学   2764篇
物理学   7615篇
  2024年   87篇
  2023年   442篇
  2022年   666篇
  2021年   665篇
  2020年   873篇
  2019年   793篇
  2018年   710篇
  2017年   681篇
  2016年   1007篇
  2015年   991篇
  2014年   1129篇
  2013年   1513篇
  2012年   1759篇
  2011年   1813篇
  2010年   1264篇
  2009年   1120篇
  2008年   1276篇
  2007年   1123篇
  2006年   1015篇
  2005年   906篇
  2004年   726篇
  2003年   638篇
  2002年   694篇
  2001年   554篇
  2000年   443篇
  1999年   442篇
  1998年   361篇
  1997年   328篇
  1996年   344篇
  1995年   298篇
  1994年   245篇
  1993年   172篇
  1992年   168篇
  1991年   163篇
  1990年   125篇
  1989年   96篇
  1988年   54篇
  1987年   56篇
  1986年   76篇
  1985年   47篇
  1984年   32篇
  1983年   26篇
  1982年   15篇
  1981年   11篇
  1980年   4篇
  1976年   1篇
  1975年   2篇
  1974年   1篇
  1969年   1篇
  1957年   5篇
排序方式: 共有10000条查询结果,搜索用时 203 毫秒
161.
The image displaying methods used in a millimeter wave radiometric imaging system have great influence on its imaging quality. In order to obtain high quality millimeter wave radiometric images, intensive studies on the image displaying methods are needed. This paper describes the image displaying method of Ground-based 8mm Millimeter Wave Radiometric Imaging (GMWRI) system and compares two different image displaying methods. The experimental results prove the unequal size element arc displaying method fits GMWRI system better.  相似文献   
162.
用光锥QCD求和规则研究D→Klv~l衰变过程,首先计算D→K跃迁形状因子,通过构造新的关联函数,消除了twist-3波函数的不确定性给计算结果所带来的影响,从而使计算结果更加精确. 计算得到的分支比与最近的实验数据相一致. 关键词: QCD光锥求和规则 D介子半轻衰变 分支比 形状因子  相似文献   
163.
164.
郭鹏飞 《数学研究》2006,39(1):83-88
考查了次正规子群对有限群结构的影响,得到有限群可解的若干充分条件和超可解的一个充分条件.  相似文献   
165.
用超磁致伸缩调谐光纤光栅的光分/插复用器   总被引:9,自引:2,他引:7  
提出并研究了一种新型多信道切换的全光分/插复用器,它主要由光纤Bragg光栅(FBG)和一对光环行器组成.采用了一种高效的超磁致伸缩材料(GMM)使FBG产生有效的Bragg波长偏移.用控制电流来调控FBG的应变和Bragg波长偏移.用4只相同的FBG与波长叠加技术相结合,可建立能提供15种不同下路信道方式的OADM.  相似文献   
166.
Ethylene–propylene copolymerization, using [(Ph)NC(R2)CHC(R1)O]2TiCl2 (R1 = CF3, Ph, or t‐Bu; R2 = CH3 or CF3) titanium complexes activated with modified methylaluminoxane as a cocatalyst, was investigated. High‐molecular‐weight ethylene–propylene copolymers with relatively narrow molecular weight distributions and a broad range of chemical compositions were obtained. Substituents R1 and R2 influenced the copolymerization behavior, including the copolymerization activity, methylene sequence distribution, molecular weight, and polydispersity. With small steric hindrance at R1 and R2, one complex (R1 = CF3; R2 = CH3) displayed high catalytic activity and produced copolymers with high propylene incorporation but low molecular weight. The microstructures of the copolymers were analyzed with 13C NMR to determine the methylene sequence distribution and number‐average sequence lengths of uninterrupted methylene carbons. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 5846–5854, 2006  相似文献   
167.
A novel cyclic ether monomer 3‐{2‐[2‐(2‐hydroxyethoxy)ethoxy]ethoxy‐methyl}‐3′‐methyloxetane (HEMO) was prepared from the reaction of 3‐hydroxymethyl‐3′‐methyloxetane tosylate with triethylene glycol. The corresponding hyperbranched polyether (PHEMO) was synthesized using BF3·Et2O as initiator through cationic ring‐opening polymerization. The evidence from 1H and 13C NMR analyses revealed that the hyperbranched structure is constructed by the competition between two chain propagation mechanisms, i.e. active chain end and activated monomer mechanism. The terminal structure of PHEMO with a cyclic fragment was definitely detected by MALDI‐TOF measurement. A DSC test implied that the resulting polyether has excellent segment motion performance potentially beneficial for the ion transport of polymer electrolytes. Moreover, a TGA assay showed that this hyperbranched polymer possesses high thermostability as compared to its liquid counterpart. The ion conductivity was measured to reach 5.6 × 10?5 S/cm at room temperature and 6.3 × 10?4 S/cm at 80 °C after doped with LiTFSI at a ratio of Li:O = 0.05, presenting the promise to meet the practical requirement of lithium ion batteries for polymer electrolytes. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 3650–3665, 2006  相似文献   
168.
Amphiphilic biodegradable block copolymers [poly(sebacic anhydride)–poly(ethylene glycol)–poly(sebacic anhydride)] were synthesized by the melt polycondensation of poly(ethylene glycol) and sebacic anhydride prepolymers. The chemical structure, crystalline nature, and phase behavior of the resulting copolymers were characterized with 1H NMR, Fourier transform infrared, gel permeation chromatography, and differential scanning calorimetry. Microphase separation of the copolymers occurred, and the crystallinity of the poly(sebacic anhydride) (PSA) blocks diminished when the sebacic anhydride unit content in the copolymer was only 21.6%. 1H NMR spectra carried out in CDCl3 and D2O were used to demonstrate the existence of hydrophobic PSA domains as the core of the micelle. In aqueous media, the copolymers formed micelles after precipitation from water‐miscible solvents. The effects on the micelle sizes due to the micelle preparation conditions, such as the organic phase, dropping rate of the polymer organic solution into the aqueous phase, and copolymer concentrations in the organic phase, were studied. There was an increase in the micelle size as the molecular weight of the PSA block was increased. The diameters of the copolymer micelles were also found to increase as the concentration of the copolymer dissolved in the organic phase was increased, and the dependence of the micelle diameters on the concentration of the copolymer varied with the copolymer composition. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 1271–1278, 2006  相似文献   
169.
170.
The electrochemical behavior of gatifloxacin (GTFX) and its interaction with natural calf thymus DNA (ctDNA) is investigated by differential pulse voltammetry (DPV) on a carbon paraffined electrode. According to the suggested electrochemical equation, a binding constant of 1.7058 x 10(5) (mol L(-1))(-1) and binding sizes s = 3.09 (base pairs) of GTFX with ctDNA are obtained by nonlinear fit analysis of electrochemical data. The results demonstrate that GTFX has the properties of an intercalative binder.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号