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红外光谱对碱土金属二元羧酸盐结构的研究 总被引:14,自引:2,他引:14
研究了三十种二元羧酸金属盐的红外光谱,讨论了金属离子和二元酸的种类对二元酸盐配位结构的影响。发现Mg盐、Ba盐,Sr盐为螯合配位,Ca盐,Zn盐中同时存在螯合配位和桥式配位,二元酸的种类对羧酸盐配位结构没有影响。对羧酸盐在常温和熔融后的栩位方式和结构上的差异的研究结果表明,Mg盐,Ca盐与Sr盐,Ba盐在熔融后的结构变化不同。 相似文献
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The optimized geometries, complexation energies, etc. of HXPY (X?=?Al, B; Y?=?H, F, OH) donor–acceptor complexes have been investigated at the B3LYP/6-311+G(d,p), MP2/6-311+G(d,p) and/or CCSD(T)/6-311+G(d,p) levels. The results show that HBPY (Y?=?H, F, OH) is more stable than the corresponding HAlPY (Y?=?H, F, OH), F (or OH) substitution on phosphorus results in decreasing complex stability, and the stronger the electron-attracting nature of the substitution atom, the more stable the complex. Moreover, the thermodynamic and kinetic properties of the formation reaction of these donor–acceptor complexes were also examined within the temperature range 200–800?K using the general statistical thermodynamics and Eyring transition state theory with Wigner correction. It is concluded that the formation of HBPY is thermodynamically favoured over that of the corresponding HAlPY, especially at low temperature, and is kinetically favoured over that of the relevant HAlPY (Y?=?H, F, OH), especially at high temperature. 相似文献
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Wen‐xiong Shi Yun‐yan Li Jun Xu Gui‐qiu Ma 《Journal of Macromolecular Science: Physics》2013,52(6):1115-1126
The relationship of the phase morphology of polypropylene/polyethylene‐terephthalate (PP/PET) blends and their corresponding compatibilized blends with composition was investigated using digital image analysis. A diameter, d g , was defined and calculated to discuss the phase morphology of this polymer blend system. A figure‐estimation method was introduced to determine the width of the distribution of d g . Based on the method, it is proven that the distribution of d g obeys a log‐normal distribution and consequently, the distribution width, σ was calculated. Further, a fractal dimension, D f , was introduced to describe the distribution of main sizes of the particles of the dispersed phase. The results showed that, while d g increased with the concentration of the dispersed phase, σ and D f show different dependence relations on composition;σ increases monotonously but D f shows a maximum at a PET content of 30%, indicating that, even though the whole size distribution is much broader, the distribution of the main body of size becomes more uniform when the content of PET is less than 30%. 相似文献
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对于传统精冲零件检测工艺普遍存在的人工抽检数量少、大尺寸检测困难、手工误差、复杂专用检具成本高且实时性差等所导致的综合效率低的问题,此文通过应用机器视觉、激光测距、精密数控、数据分析等技术开发了大尺寸复杂精冲零件智能测量系统,用于解决传统所检测面临的以上问题。此系统通过伺服运动控制一套由高分辨率工业相机、激光位置传感器和大理石载物台构成的三坐标检测平台,实现对大尺寸复杂精冲零件进行X-Y平面的尺寸精密测量和Z方向的高度或粗糙度精密测量。通过解析DXF图纸文件并应用改进的贪心算法来获取并优化检测路径,结合精密运动反馈拼接局部采样图像以提高机器视觉的检测精度。初步运行结果表明,系统测量600*600*8mm范围内复杂精冲件精度可达到±0.010mm。 相似文献
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Zhong Ju Liu Wenwen Shi Gui Mei Shi Wei Jiang 《International Journal of Theoretical Physics》2018,57(1):184-194
An array of coupled cavities, each of which contains a triangle-down-level atom, is investigated. An effective Hamiltonian can be achieved under the strong classical driving. We can control the transition between Mott-insulator and superfluid states by the classical driving. The frequency conversion in one site has the same effects of nonlinear in BH hamiltonian which can induce insulator-superfluid states. 相似文献
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We investigated the waveguide formation in Lithium Niobate with Femtosecond laser pulse writing directly. The output optical field through waveguide has been observed and refractive-index change was characterized by using grating method. 相似文献
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In this article, we propose a three-party quantum secret sharing protocol with four-state Grover algorithm. The protocol has several advantages. It uses only four initial states which simplifies its experimental implementation. It has a higher encoding capacity, each two-qubit state provides two bits of information. We have experimentally demonstrated the protocol in a nuclear magnetic resonance quantum information processor successfully. 相似文献