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991.
Xiaodong Jia Chang Qing Congde Huo Fangfang Peng Xicun Wang 《Tetrahedron letters》2012,53(52):7140-7142
A domino process between iminoethyl glyoxylate and N-vinylamides was achieved under the catalytic radical cation salt induced conditions, producing a series of quinoline-2-carboxylates. N-Vinylamides were involved as an acetylene equivalent. A possible mechanism was proposed to rationalize the formation of the products. 相似文献
992.
993.
Yue‐Feng Bi Lu Jia She‐Po Shi Xiao‐Li Sun Yuan‐Yuan Chen Yang‐Bing Zhang 《Helvetica chimica acta》2010,93(10):1953-1959
Two new guaianolides (=guaianolactones), chrysanthguaianolactone A and B ( 1 and 2 , resp.), and one new eudesmane sesquiterpene, chrysanthemdiol A ( 6 ), together with seven known sesquiterpenes were isolated from the flowers of Chrysanthemum indicum L. Their structures were elucidated on the basis of spectroscopic evidence. 相似文献
994.
In the paper,an experiment investigation was conducted for one-and two-degree of freedom vortex-induced vibration(VIV) of a horizontally-oriented cylinder with diameter of 11 cm and length of 120 cm.In the experiment,the spring constants in the cross-flow and in-line flow directions were regulated to change the natural vibration frequency of the model system.It was found that,in the one-degree of freedom VIV experiment,a "double peak" phenomenon was observed in its amplitude within the range of the reduced velocities tested,moreover,a "2T" wake appeared in the vicinity of the second peak.In the two-degree of freedom VIV experiment,the trajectory of cylinder exhibited a reverse "C" shape,i.e.,a "new moon" shape.Through analysis of these data,it appears that,besides the non-dimensional in-line and cross-flow natural vibration frequency ratios,the absolute value of the natural vibration frequency of cylinder is also one of the important parameters affecting its VIV behavior. 相似文献
995.
996.
Gang Feng Yongguang Jia Lingyan Liu Weixing Chang Jing Li 《Journal of polymer science. Part A, Polymer chemistry》2010,48(24):5992-6002
A series of novel organotin‐containing core‐cross‐linked knedels and shell‐cross‐linked knedels were first synthesized facilely from poly(styrene)‐b‐poly(acrylate acid) nanoparticles in different selective solvents [Tetrahydrofuran (THF)/H2O or THF/n‐octane] by using organotin compound 1,3‐dichloro‐tetra‐n‐butyl‐distannoxane as a new cross‐linker. The formation of the 1‐chloro‐3‐carboxylato‐tetra‐n‐butyl‐distannoxane layer in our cross‐linking reaction was supported by Fourier transform infrared (FT‐IR) and inductive coupled plasma emission spectrometer (ICP) analysis of the resulting shell‐cross‐linked knedels and core‐cross‐linked knedels. Transmission electron microscopy (TEM) study showed the spherical morphology and the size of the core‐cross‐linked knedels and shell‐cross‐linked knedel. Especially, the layer structure of the core‐cross‐linked knedels was clearly displayed in TEM image. The increase of extent of cross‐linking lead to the increasing of diameter for the shell‐cross‐linked knedels, whereas there was no significant effect on the core‐cross‐linked knedels. Dynamic light scattering (DLS) measurements gave hydrodynamic diameters of the core‐cross‐linked knedels that were in agreement with the TEM diameters. Moreover, the wall thickness of the shell layer of the core‐cross‐linked knedels could be easily modified by varying the block copolymer composition. Notably, the organotin‐containing core‐cross‐linked knedel exhibited highly efficient catalytic activity for the aqueous esterification reaction under nearly neutral conditions. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2010 相似文献
997.
Strontium tungstate is a well-known stimulated Raman scattering laser material. The unique structure of this crystal allows
the usage of these crystals as matrices for laser active elements with nonlinear self-conversion of radiation to a new spectral
range. The recent advances in crystal growth, particle and thin film fabrication, spectroscopy, and laser properties were
reviewed. The demonstration of laser output of neat and Nd3+-doped SrWO4 crystal shows that it is an efficient self-stimulated Raman scattering laser. 相似文献
998.
The pyrolysis of Pubescens over Ni/C catalyst was studied at 350 °C in H2 flow. The presence of Ni/C catalyst efficiently improved the degradation of raw materials, and produced bio-oil with high content of phenols but low contents of acetic acid, furfural and water. In the reaction, Ni/C catalyst plays the role of catalytic decomposition and catalytic hydrogenation. The existence of the carbon carrier favors the formation of active Ni in small sizes with more defects, which results in high catalytic activity of Ni in biomass decomposition and selective production of phenols. 相似文献
999.
Yan Li Xinru Jia Min Gao Hai He Guichao Kuang Yen Wei 《Journal of polymer science. Part A, Polymer chemistry》2010,48(3):551-557
Gn (n = 3, 4, and 5) poly(amidoamine) (PAMAM) dendrimers were synthesized and peripherally modified with photocleavable o‐nitrobenzyl (NB) groups by reacting o‐nitrobenzaldehyde with the terminal amine groups of PAMAM dendrimers, followed by reducing the imine to amine groups with NaBH4. The NB‐modified dendrimers, Gn‐NB (n = 3, 4, and 5), were characterized by nuclear magnetic resonance and fourier transform infrared spectroscopy. The results showed that the NB groups were successfully attached on the periphery of the dendrimers with near 100% grafting efficiency. Such a photosensitive NB shell could be cut off on irradiation with 365 nm ultraviolet (UV) light. The encapsulation and release of guest molecules, that is, salicylic acid (SA) and adriamycin (ADR), by Gn‐NB were explored. The encapsulation capability of these dendrimers was found to increase as the guest molecular size was decreased and have dependence on the generation of dendrimers as well. For both of SA and ADR, the average encapsulation numbers per dendrimer decreased in the order of G4‐NB > G5‐NB > G3‐NB, indicating that the fourth generation dendrimer was a better container for the guest molecules. The rate of SA release was found to be greater with UV irradiation than that without, suggesting that the NB‐shelled PAMMAM dendrimers could function as a molecular container/box with photoresponsive characteristics. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 551–557, 2010 相似文献
1000.
Peng Zhang Long Huang Yan‐lei Ma Jia‐yuan Peng Tong‐yi Shen Hong‐qi Chen Yu‐kun Zhou Ming Zhang Zhao‐xin Chu Huan‐long Qin 《Electrophoresis》2010,31(10):1731-1738
5‐Fluorouracil has been the chemotherapy agent of first‐choice for colorectal cancer for many years, but since there are no proven predictors of a patient's response to therapy, all patients receive similar treatment. Consequently, identification of biomarkers for therapeutic effect is crucial for the development of novel therapeutic strategies. Two human colorectal cancer cell lines of different metastatic potential (LoVo and SW480) were studied. IC50 of 5‐FU for both cell lines were measured by 3‐(4,5‐dimethy‐lthiazol‐2‐yl)‐2,5‐diphenyltetrazolium assay and validated by cell cycle analysis. Then the cell lines were treated with 5‐FU at IC50 concentration and protein was extracted for 2‐DE. Differential protein spots were examined by MALDI‐TOF/TOF MS. The expression levels of the different proteins were further confirmed by Western blot and immunofluorescence analyses. Eleven proteins were identified. Expression of heterogeneous nuclear ribonucleoprotein K (hnRNP K) in LoVo cells was higher than in SW480 cells, while protein disulfide isomerase (PDI) displayed the opposite trend. After treatment with 5‐FU, the expression of hnRNP K in LoVo decreased more significantly than in SW480, while PDI in SW480 increased more significantly than in LoVo cells. Conclusion: hnRNP K and PDI in the two cell lines have different expression characteristics. The sensitivity to 5‐FU is not consistent in tumor progression. It may assist in development of novel treatment strategies for colorectal cancer metastasis. 相似文献