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941.
942.
A strategy for selection of reference materials in stable oxygen isotope analyses of solid materials
The propagation of uncertainties associated with the stable oxygen isotope reference materials through a multi-point normalisation procedure was evaluated in this study using Monte Carlo (MC) simulation. We quantified the normalisation error for a particular selection of reference materials and their number of replicates, when the choice of standards is restricted to either nitrates, sulphates or organic reference materials alone, and in comparison with when this restriction was relaxed. A lower uncertainty in stable oxygen isotope analyses of solid materials performed using High-Temperature Pyrolysis (HTP) can be readily achieved through an optimal selection of reference materials. Among the currently available certified reference materials the best performing pairs minimising the normalisation errors are USGS35 and USGS34 for nitrates; IAEA-SO-6 and IAEA-SO-5 for sulphates; and IAEA-601 and IAEA-602 for organic materials. The normalisation error can be reduced further--by approximately half--if each of these two analysed reference materials is replicated four times. The overall optimal selection among all nine considered reference materials is the IAEA-602 and IAEA-SO-6 pair. If each of these two reference materials is replicated four times the maximum predicted normalisation error will equal 0.22‰, the minimum normalisation error 0.12‰, and the mean normalisation error 0.15‰ over the natural range of δ(18)O variability. We argue that the proposed approach provides useful insights into reference material selection and in assessing the propagation of analytical error through normalisation procedures in stable oxygen isotope studies. 相似文献
943.
944.
945.
JPC – Journal of Planar Chromatography – Modern TLC - In the phototherapeutic use of photosensitizers, lipophilicity is an important parameter that allows predicting their biological... 相似文献
946.
947.
Asymmetric aldol-Tishchenko reaction catalyzed by Yb-complexes with basic amino acid-derived ligands
Simple amino acid-derived esters have been identified as promising chiral sources for the ytterbium-catalyzed aldol-Tishchenko reaction of aromatic aldehydes with aliphatic ketones. The 1,3-anti-diols with three stereogenic centers were isolated in excellent yields, complete anti-diastereocontrol and enantioselectivities of up to 50% ee. 相似文献
948.
Urszula Domańska Kamil Paduszyński Zuzanna Żołek-Tryznowska 《The Journal of chemical thermodynamics》2011,43(2):167-171
(Liquid + liquid) phase equilibria (LLE) of binary mixtures containing hyperbranched polymer Boltorn® H2004 and n-alkanes (n-hexane, n-heptane, n-octane, and n-decane) were studied over the temperature range from about (260 up to 360) K. The polymer is partially miscible with n-alkanes and the solubility decreases with an increase of the chain length of the solvent. Corresponding LLE phase diagrams including spinodal and binodal (liquid + liquid) coexistence curves were calculated in terms of the statistical mechanics – based on the lattice-cluster theory, based only on the upper critical solution temperature, and the polymer chain architecture. The results show semi-qualitative agreement of predicted and experimental equilibrium compositions and temperatures. Boltorn® H2004 reveals complete miscibility in the liquid phase with alcohols (C1–C8), aromatic hydrocarbons (benzene, toluene, and thiophene), and ethers (methyl tetra-butyl ether, ethyl tetra-butyl ether, and tetrahydrofurane). 相似文献
949.
Karamov O. G. Rybalkin V. P. Makarova N. I. Metelitsa A. V. Kozyrev V. S. Borodkin G. S. Popova L. L. Breń V. A. Minkin V. I. 《Russian Chemical Bulletin》2011,60(1):168-174
New dihetarylethenes containing the six-membered bridging moiety, viz., N
2-alkyl-5-furyl-4-thienylpyridazinones, were synthesized. These compounds have photochromic properties in solution. The hindered
rotation of the thiophene and furan rings around the single bonds that link these rings to the double bond of the pyridazinone
moiety results in the formation of mixtures of chiral diastereomers in solution, the lifetimes of the diastereomers being
no longer than 0.2 s. The photochromic rearrangement of pyridazinones is characterized by the highly efficient photocoloration
and the photobleaching, which is an order of magnitude less efficient, in the absence of thermal relaxation processes. 相似文献
950.
A GC/tandem quadrupole MS/MS method was developed and validated for the determination of the residues of 140 pesticides in fruits and vegetables. Pesticides were extracted from samples by using a miniaturized acetonitrile-based extraction technique known as the quick, easy, cheap, effective, rugged, and safe (QuEChERS) method. Validation studies were carried out on carrots, tomatoes, and strawberries. In order to reduce systematic errors due to a matrix-induced effect, quantification was carried out using matrix-matched standard calibration curves. The recovery and precision results satisfied the European Union criteria (i.e., average recoveries were in the range 70-120% with RSDs < or = 20%) for 125 of the 140 pesticides at a spiking level of 0.01 mg/kg. At the higher spiking levels, there were just two instances of overall average recovery < 70% (chlorothalonil and captan). The measurement uncertainty was estimated following a "top down" approach as being 21 and 35%, on average, based on validation and ongoing recovery data, respectively (coverage factor k = 2, confidence level 95%). Practical application to 541 samples of apples, tomatoes, strawberries, cucumbers, currants, mushrooms, carrots, peppers, pears, onions, and gooseberries under strict QC conditions demonstrated the ruggedness of the total procedure. 相似文献