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941.
J. Kierzek B. Małożewska-Bućko P. Bukowski J. L. Parus A. Ciurapiński S. Zaraś B. Kunach K. Wiland 《Journal of Radioanalytical and Nuclear Chemistry》1999,240(1):39-45
Gamma-ray spectrometry (GS), energy dispersive X-ray fluorescence (EDXRF) analysis methods and wavelength dispersive X-ray
fluorescence (WDXRF) were applied for the studies of some coal components, e.g., sulphur, light and heavy metal element concentrations
and naturally occurring radioactive isotope contents. Hundred fifty coal samples originating mostly from eight different coal
mines from Upper Silesian Coal Basin and 150 samples of ash obtained from these coal samples in laboratory by total combustion
at final temperature of 820°C, were analyzed. Such comparitive analyses can be helpful in selection of most suitable kind
of coal for burning in electrical power and heat plants to minimize the environmental pollution. 相似文献
942.
The synthesis of both enantiomers of TEI-9826 has been accomplished in seven steps with an overall yield of 44% starting from diastereomeric camphor protected 3-[(dimethoxyphosphoryl)methyl]-4,5-dihydroxycyclopent-2-enones. The key steps include a fully diastereoselective hydrogenation of the endocyclic carbon–carbon double bond in the cyclopentenone ring controlled with a chiral diol moiety and the conversion of the latter into a new transposed olefinic bond. 相似文献
943.
Marcin Płosiński Tomasz Laskowski Paweł Sowiński Jan Pawlak 《Magnetic resonance in chemistry : MRC》2012,50(12):818-822
The absolute configurations of all the stereogenic centers of the antibiotic mycoheptin A2 were established upon previously elaborated general procedure, consisting of DQF‐COSY, NOESY, ROESY, HSQC and HMBC experiments as major tools. The structure of mycoheptin A2 without stereochemistry of its aglycone has been reported before. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
944.
945.
Wojciech Kiciński Mateusz Szala Marcin Nita 《Journal of Sol-Gel Science and Technology》2011,58(1):102-113
The impact of solvent composition as well as inorganic salt content and type on carbon xerogel structure was investigated.
Carbon xerogels were derived from the sol–gel polycondensation of resorcinol with furfural in a water–methanol–inorganic salt
solution. As inorganic salts, NaCl, NH4ClO4 and FeCl3 were used. In order to conduct an accurate examination of the carbon xerogel structures and textures, inorganic salts were
removed prior to carbonization. The xerogel structures can be tailored according to the water/methanol ratio and, to a lesser
extent, according to the inorganic salt content and type in the starting solution. As a result, a significant amount of salt
can be introduced to the gel network of the desired structure. The morphology and physical properties of the organic xerogels,
carbon xerogels and their composites were characterized by means of SEM, N2 sorption and XRD. It was found that samples derived from mixtures with FeCl3 manifest well developed mesoporosity and depleated microporosity in comparison to samples prepared from mixtures with NaCl
and NH4ClO4. Iron ions chemically bond to the xerogel matrix and cause its partial graphitization during the carbonization process, resulting
in enhanced mesoporosity. 相似文献
946.
947.
Density and viscosity were determined for the binary mixtures containing the ionic liquid 1-butyl-3-methylimidazolium thiocyanate
([BMIM][SCN]) and 1-alcohols (1-butanol, 1-pentanol and 1-hexanol) at six temperatures (298.15, 308.15, 318.15, 328.15, 338.15
and 348.15) K and ambient pressure. The density and viscosity correlation for these systems was tested by an empirical second-order
polynomial and by the Vogel-Fucher-Tammann equation in wide ranges of temperatures. Excess molar volumes were described by
the Redlich-Kister polynomial expansions. The density and viscosity variations with composition were described by polynomials.
A qualitative analysis of the trend of the properties with solvent and temperature was performed. The obtained results indicate
that ionic liquid interactions with 1-alcohols are strongly dependent on the special trend of packing of this ionic liquid
into hydroxylic solvents. As previously observed, an increase of the 1-alcohol carbon-chain length leads to lower interactions
on mixing.
Electronic Supplementary Material The online version of this article () contains supplementary material, which is available to authorized users. 相似文献
948.
O. Habarova O. Bobiļeva E. Loža N. Romančikova 《Chemistry of Heterocyclic Compounds》2011,47(6):719-727
Inhibition of histone deacetylase activity appears as an original and effective approach for the treatment of cancer. A series
of novel quinoline-containing derivatives has been synthesized and found that some of these compounds possess nanomolar histone
deacetylase inhibitory activity. 相似文献
949.
Oya Tagit Dominik Jańczewski Ming Yong Han Jennifer L. Herek 《European Polymer Journal》2010,46(7):1397-16948
Synthesis, characterization, and applications of novel thermoresponsive polymeric coatings for quantum dots (QDs) are presented. Comb-copolymers featuring hydrophobic alkyl groups, carboxylic groups and poly(N-isopropylacrylamide) (PNIPAM) side chains with molar masses ranging from 1000 g/mol to 25,400 g/mol were obtained. The amphiphilic comb-copolymers were shown to efficiently transfer the QDs to aqueous media. The PNIPAM-coated QD materials display a lower critical solution temperature (LCST). The absorbance, luminescence emission, size of the assemblies, and electrophoretic mobility were followed as a function of temperature and the reversibility of the temperature induced changes is demonstrated by cyclic heating and cooling. 相似文献
950.
Honey produced by honeybees is a valuable food product. The presence of xenobiotics in honey may harm its quality and constitute a danger to human health. Antibiotics are commonly applied by beekeepers to eliminate disease among honeybees. Moreover, ubiquitous administration of antibiotics may cause bacteria to become resistant to many drugs and spread antibiotic-resistant strains of bacteria. Appropriate sample preparation and determination of antibiotics at very low concentrations in foodstuffs are real analytical challenges. This article reviews analytical methods used for determination of residues of different sorts of antibiotic in honey and other honeybee products. 相似文献