Leak testing of carbon–tin nanocomposites by thermal analysis methods

Electrode materials consisted of tin nanograins encapsulated in different origin carbon buffer matrix (starch or water soluble polymer) were obtained in a simple and inexpensive process. The tin precursor was synthesized using modified reverse nanoemulsion technique (w/o) and then coated by a source of carbon. The composites precursors were pyrolysed, affording formation of C/Sn anode materials. The resulting samples were investigated by powder X-ray diffraction studies in order to verify the structure and calculate crystallites sizes. The morphology of the nanocomposites was characterized by low-temperature nitrogen adsorption method (N₂-BET). Thermal analysis measurements (EGA-TG/DTG/DTA and DSC) allowed determining optimal conditions of preparation process and estimating carbon content in the obtained anode materials. Thermogravimetric studies also proved to be highly useful in establishing the leak behaviour of C/Sn nanocomposites. The electrochemical performance of the nanopowders was examined by charge–discharge tests in R2032-type coin cell. The thermal analysis results as well as low-temperature nitrogen adsorption data indicated that the origin of carbon precursor has major impact on morphology and leak behaviour of the obtained carbon buffer matrix. The electrochemical tests showed that better tightness of carbon–tin nanocomposites resulted in higher gravimetric capacity and better cell performance.     

Analysis of flammability and smoke emission of rigid polyurethane foams modified with nanoparticles and halogen-free fire retardants

Using one-step method, rigid polyurethane foams were made, modified with developed fire retardant systems containing halogen-free flame retardants and nanofillers in the form of multi-walled carbon nanotubes or nanoscale titanium dioxide. The materials were subjected to a test using a cone calorimeter and smoke-generating chamber, and selected samples were further analyzed via thermogravimetry and oxygen index. Moreover, the products of thermal degradation of selected samples were identified using gas chromatography with mass spectrometer. Conducted flammability tests confirmed the presence of a synergistic effect between the used nanofillers and halogen-free flame retardants. It has been observed that the carbonized layer, the formation of which favored the presence of nanoadditives, inhibits the combustion process. Furthermore, nanofillers influenced favorably reduction in the amount and the number of occurring products of thermal degradation.     

Thermal and mechanical properties of chitosan nanocomposites with cellulose modified in ionic liquids

In this paper, ionic liquid treatment was applied to produce nanometric cellulose particles of two polymorphic forms. A complex characterization of nanofillers including wide-angle X-ray scattering, Fourier transform infrared spectroscopy, and particle size determination was performed. The evaluated ionic liquid treatment was effective in terms of nanocrystalline cellulose production, leaving chemical and supermolecular structure of the materials intact. However, nanocrystalline cellulose II was found to be more prone to ionic liquid hydrolysis leading to formation larger amount of small particles. Each nanocrystalline cellulose was subsequently mixed with a solution of chitosan, so that composite films containing 1, 3, and 5% mass/mass of nanometric filler were obtained. Reference samples of chitosan and chitosan with micrometric celluloses were also solvent casted. Thermal, mechanical, and morphological properties of films were tested and correlated with properties of filler used. The results of both, tensile tests and thermogravimetric analysis showed a significant discrepancy between composites filled with nanocrystalline cellulose I and nanocrystalline cellulose II.     

Thermal evolution of ladder-like silsesquioxanes during formation of black glasses

Heat capacity of single-crystal samples of five chalcogenides (LiInS₂, LiInSe₂, LiGaS₂, LiGaSe₂, and LiGaTe₂) was measured with DSC in a temperature range from 180 to 460 K. The data for LiInS₂ and LiInSe₂ were compared with the literature data and shown to agree with the results of adiabatic calorimetry (Gmelin and Hönle in Thermochimica Acta 269: 575–590, 1995) better than with other DSC data (Kühn et al. in Cryst Res Technol 22: 265–269, 1987). Besides, the high-temperature fitting polynomial for C _P(T) published about 30 years ago for LiInS₂ is wrong. LiGaS₂, LiGaSe₂, and LiGaTe₂ were measured for the first time.     

Lévy-driven GPS queues with heavy-tailed input

In this paper, we derive exact large buffer asymptotics for a two-class generalized processor sharing (GPS) model, under the assumption that the input traffic streams generated by both classes correspond to heavy-tailed Lévy processes. Four scenarios need to be distinguished, which differ in terms of (i) the level of heavy-tailedness of the driving Lévy processes as well as (ii) the values of the corresponding mean rates relative to the GPS weights. The derived results are illustrated by two important special cases, in which the queues’ inputs are modeled by heavy-tailed compound Poisson processes and by \(\alpha \)-stable Lévy motions.     

SDEs with constraints driven by semimartingales and processes with bounded p-variation

We study the existence, uniqueness and stability of solutions of general stochastic differential equations with constraints driven by semimartingales and processes with bounded $p$-variation. Applications to SDEs with constraints driven by fractional Brownian motion and standard Brownian motion are given.     

The 1‐2‐3‐Conjecture for Hypergraphs

A weighting of the edges of a hypergraph is called vertex‐coloring if the weighted degrees of the vertices yield a proper coloring of the graph, i.e. every edge contains at least two vertices with different weighted degrees. In this article, we show that such a weighting is possible from the weight set for all hypergraphs with maximum edge size and not containing edges solely consisting of identical vertices. The number is best possible for this statement.     

Modelluntersuchungen des Wärmeaustausches und Strömungswiderstandes an den Heizflächen mit Diagonalflossen

This paper presents the results of an experimental study on the heat transfer and pressure drop in diagonally finned tube banks. The investigations have been carried out using the napthalene analogy. The performance of a heat exchanger with fins arranged a certain angle to the flow direction with the plain tube heat exchanger have been compared.     

Boundary and initial fluctuation effect on dynamic behaviour of a laminated solid

Two problems will be studied in this contribution. First, we analyse some phenomena which take place in a laminated solid and are caused by a fluctuation of time-dependent boundary tractions. Second, we investigate the transient effect of initial displacement fluctuations on the behaviour of a laminate. To solve the above problems we propose a new macroscopic 3D model for investigations of initial-boundary value problems in elastodynamics of a laminated medium.