Cubic splines and the Lippmann-Schwinger equation

The Galerkin method of solution of integral equations using splines is proposed. This method is applied to the Lippmann-Schwinger equation. Bound state energies and correspondingt-matrices are calculated for various potentials. This method can also be applied to reduce the Faddeev equation to the one-dimensional ones.The authors are grateful to Doc. J.Kvasnica for number of useful discussions and to M.erný for help with numerical calculations.     

Magnetic moments and the high field susceptibilities of MnFe2O4

An extended version of the noncollinear spin model bySawatzky et al. is developed to derive a dependence of the differential high field susceptibility on the degree of inversion of the ferrite MnFe₂O₄. Using the available data on the main molecular field coefficients it is shown that the present model imposes restrictions on values of. Determination of from the measurements of the field dependence of the saturated moments at low temperatures on samples with varying degrees of inversion reveals good quantitative agreement with the present model.     

A model of oxide film originating at thermal oxidation of GaAs

In this paper an approximative procedure to determine of the most probable model of oxide film originating at thermal oxidation of GaAs single-crystal samples within the temperature range 480–530 °C is proposed. It is shown that the system presented is more complicated if compare with that presumed previously.     

Synthesis, characterization, biocide and toxicological activities of di-n-butyl- and diphenyl-tin(IV)-salicyliden-beta-amino alcohol derivatives

The one pot reaction of salicylaldehyde 1, beta-amino alcohols 2a-2c, and di-n-butyltin(IV) oxide 3a or diphenyltin(IV) oxide 3b produced five diorganotin(IV) compounds, 4a-4c, 5a, and 5c, in good yields. All compounds were characterized by IR, (1)H, (13)C, and (119)Sn NMR spectroscopy, and elemental analysis; furthermore, compounds 4b, 4c, 5a, and 5c were characterized by X-ray diffraction analysis. After the structural characterization, all of the compounds were tested in vitro against Bacillus subtilis (Gram-positive, strain ATCC 6633), Escherichia coli (Gram-negative, strain DH5alpha), Pseudomonas aeruginosa (Gram-negative, strain BH3), Desulfovibrio longus (strain DSM 6739), and Desulfomicrobium aspheronum (strain DSM 5918) to assess their antimicrobial activity. Compounds 4 and 5 demonstrated a wide range of bactericidal activities against the tested aerobic (one Gram-positive and two Gram-negative subtypes) and anaerobic bacteria (two sulfate-reducing bacteria, SRB). Compound 5 had better bactericidal performances than compound 4. For all of the compounds, the acute toxicity was measured using luminescent bacteria toxicity (LBT-Microtox) tests to track their further environmental impact. According to these results and in order to fulfill environmental regulations, the toxicity of the compounds studied herein can be modulated through the proper selection of the disubstituted tin(IV) moiety.     

Synthese von Clathratverbindungen des Typs Cd(mea) m [Pd(CN)4] ·nG

The preparation, identification and some properties of three new clathrate compounds Cd(mea)[Pd(CN)₄] · 2C₆H₆, Cd(mea)₂[Pd(CN)₄] · C₄H₄S and Cd(mea)₂[Pd(CN)₄] · C₄H₄NH (mea = HO-CH₂-CH₂-NH₂) are described.

     

Effects of non-ionic surfactants on isotachophoretic separations of 2-arylpropionic acids

Non-ionic surfactant (Brij 35, Tween 20, Tween 80 and Tergitol NPX) modified capillary isotachophoresis was investigated for the separation of 2-arylpropionic acids (fenoprofen, flurbiprofen, ibuprofen, ketoprofen and naproxen) and benzoic acid and its derivatives (salicylic, acetylsalicylic and gallic acids). The relative step height (RSH) values of analytes were found to be dependent on the type and concentration of the surfactant. The strength of the affinity of the 2-arylpropionic acids to the non-ionic micelles was found to be as follows: flurbiprofen > fenoprofen > ibuprofen > naproxen > ketoprofen. In general, the RSH values of 2-arylpropionic acids increase with an increase in the concentration of surfactants. However, the RSHs of benzoic, salicylic and gallic acids are not considerably affected. Separation of all acids was obtained with the Tween 20 (1.5%, w/v) in the leading electrolyte 10 mmol L(-1) hydrochloric acid/L-histidine (pH 6.0). Changes in the fluorescence intensity of fenoprofen, flurbiprofen and naproxen were also investigated in micellar media (Tween 20, Tween 80 and Brij 35). The strength of the affinity of the 2-arylpropionic acids to the Tweens micelles was found to be as follows: flurbiprofen > fenoprofen > naproxen, which is consistent with the isotachophoretic results. On the contrary, the strength of the affinity to the Brij micelles was found to be as follows: fenoprofen > naproxen > flurbiprofen.     

Constituents of labiatae—XIV: Vierol and powerol,two new diterpenes from Sideritis canariensis

The two new diterpenes, vierol (1) [(?)kaurane-16α,18-diol] and powerol (3) [(?)kaurane-7β,16α-diol] have been isolated from Sideritis canariensis Ait. 1 was obtained by partial synthesis from epicandicandiol (7), and 3 was related with (?)kauranol (6) and (?)kauren-7β-ol acetate (11). Reduction of the acetoxy-aldehyde 14 by the method of Huang-Minlon and posterior acetylation gave 11, (?)isokauren-7β-ol acetate (17) and (?)kauran-7β-ol acetate (18).     

Optimization of the Microwave-Assisted Saponification and Extraction of Organic Pollutants from Marine Biota Using Experimental Design and Artificial Neural Networks

Several improvements in sample pretreatment for the determination of organic pollutants (i.e. n-alkanes, polycyclic aromatic hydrocarbons, PAHs) in marine biota (mussels) are presented. The use of liquid nitrogen and homogenization of the samples are shown to be an alternative to the time consuming liophilization step required for the analysis of biota samples. Microwave-assisted hydrolysis and extraction are combined to isolate organic pollutants (19 n-alkanes and 27 PAHs) from biota matrices. Experimental design (ED) and artificial neural networks (ANNs) were used to optimize the experimental conditions. NIST-CRM 2978 was used to test the validity of the developed method which shows a good agreement with certified values.     

Thermal behaviour of benzenesulfenamides and of their chromium carbonyl complexes

Benzenesulfenamides with the formula R-S-N-(R)₂ (R=C₆H₅ andR=NC₄H₈O, C₇H₇ and C₆H₁₁) and their chromium carbonyl complexes were studied by means of TG and mass spectrometric methods. The thermal behaviour of the compounds the stabilities of free sulfenamides are lower than those observed for the corresponding chromium carbonyl complexes. Combined thermogravimetry — mass spectrometry results suggest that the fragmentation mechanism of the carbonyl complexes involves cleavage of the Cr-S and Cr-CO bonds while that of sulfenamide depends mainly on the dissociation rates of the NR₂ groups.This work was partially supported by the Departamento técnico de Investigation of the Universidad de Chile, Grant Q3280/9324.     

Cadmium colloids from non-aqueous solvents

Cadmium colloids have been prepared by Chemical Liquid Deposition (CLD). The metal is evaporated to yield atoms which are solvated at liquid nitrogen temperature, and upon warming, stable liquid colloids are formed with particle size ranging between 25–100 Å. Zeta potentials were calculated according to the conversion of Hunter and the Hückel equation, for ethanol and dimethyl sulphoxide. UV/VIS measurement of most of the black colloids showed absorption band around 280 nm. For comparison, we prepared CdS colloid with size 400–625 Å. The colloids are stable to oxidation in air and/or oxygen bubbling. The synthesis of colloids and films from Cd with acetone, 2-butanone, ethanol, 2-propanol, 2-methoxyethanol, DMF and DMSO is reported. Transmission Electron Microscopy (TEM) allows us to determine particle size.