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91.
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93.
Glen B. Deacon Ewan E. Delbridge Brian W. Skelton Allan H. White 《Angewandte Chemie (International ed. in English)》1998,37(16):2251-2252
A higher degree of coordination saturation is attainable through the unusual coordination mode in the title compound 1 , in which the central pyrazolate groups function both as chelating and as bridging ligands. There is some asymmetry in the bridging, and the N atoms of each μ-η2:η2-pyrazolato ligand are 0.07–0.11 Å closer to one of the two Yb centers. 相似文献
94.
Glen B. Deacon Pauline Pearson Brian W. Skelton Leone Spiccia Allan H. White 《Acta Crystallographica. Section C, Structural Chemistry》2003,59(12):m537-m539
The syntheses and crystal structure determinations of a pair of `sawhorse' dimers are reported, viz. [Ru2(C6H5CO2)2(C5H5N)2(CO)4] [a new polymorph, cf. Kepert, Deacon, Spiccia, Fallon, Skelton & White (2000). J. Chem. Soc. Dalton Trans. pp. 2867–2874] and [Ru2(CF3CO2)2(C5H5N)2(CO)4]. The Ru⋯Ru distances are 2.6724 (2) and 2.7122 (5) Å, respectively. 相似文献
95.
Glen B. Deacon Alex Gitlits Gerd Zelesny Dirk Stellfeldt Gerd Meyer 《无机化学与普通化学杂志》1999,625(5):764-772
The complexes [K(H2O)2LnL2] (Ln = La or Nd; L = 1,2‐benzenedisulfonate) and [K(H2O)Yb(H2O)4L2] were initially isolated fortuitously from attempts to prepare the corresponding Ln2L3 complexes from Ln2O3 and H2L in water. Indeed the bulk products from these reactions have the composition Ln2L3. Subsequently, deliberate syntheses by reacting equimolar amounts of Ln2L3 with K2L in water gave the complexes in good yield. X‐ray crystal structures of [K(H2O)2LnL2] (Ln = La or Nd) showed the complexes to be isostructural with a two dimensional polymeric network structure in which LnL2 units are linked into chains crosslinked by potassium ions. Each Ln is nine coordinate with solely sulfonate oxygen donor atoms. Between adjacent lanthanoid ions there are three different types of sulfonate bridges and two examples of each. Most noteworthy is highly unsymmetrical bridging through μ‐η2‐sulfonate oxygen atoms. Consequently, one Ln–O bond is ca. 0.5 Å longer than the other eight. Potassium is nine‐coordinate with seven sulfonate oxygen atoms and two aqua ligands, and surprisingly <K–O(sulfonate)> is much longer than <K–O(H2O)>. Pairs of potassium ions are linked by two μ‐η2‐sulfonate oxygen atoms, which are unsymmetrically bridging. The structure of [K(H2O)Yb(H2O)4L2] comprises discrete tetranuclear units containing two independent ytterbium ions, each coordinated by four water molecules and two chelating (via seven membered rings) disulfonate ligands, and two potassium ions, each coordinated by six sulfonate oxygen atoms and a water molecule. For each potassium, four of the coordinated sulfonate oxygen atoms are from sulfonate ligands bonded to one ytterbium atom and two from sulfonate ligands attached to the other ytterbium atom. In contrast to the Nd and La complexes, <K–O(sulfonate)> is shorter than <K–O(H2O)>. 相似文献
96.
97.
Martin E. Keillor Craig E. Aalseth Anthony R. Day James E. Fast Eric W. Hoppe Brian J. Hyronimus Todd W. Hossbach Harry S. Miley Allen Seifert Glen A. Warren 《Journal of Radioanalytical and Nuclear Chemistry》2009,282(3):703-708
Physics experiments, environmental surveillance, and treaty verification techniques continue to require increased sensitivity
for detecting and quantifying radionuclides of interest. This can be done by detecting a greater fraction of gamma emissions
from a sample (higher detection efficiency) and reducing instrument backgrounds. A current effort for increased sensitivity
in high resolution gamma spectroscopy will produce an intrinsic germanium (HPGe) array designed for high detection efficiency,
ultra-low-background performance, and useful coincidence efficiencies. The system design is optimized to accommodate filter
paper samples, e.g. samples collected by the Radionuclide Aerosol Sampler/Analyzer (RASA). The system will provide high sensitivity
for weak collections on atmospheric filter samples, as well as offering the potential to gather additional information from
more active filters using gamma cascade coincidence detection. The current effort is constructing an ultra-low-background
HPGe crystal array consisting of two vacuum cryostats, each housing a hexagonal array of 7 crystals on the order of 70% relative
efficiency per crystal. Traditional methods for constructing ultra-low-background detectors are used, including use of materials
known to be low in radioactive contaminants, use of ultra pure reagents, clean room assembly, etc. The cryostat will be constructed
mainly from copper electroformed into near-final geometry at PNNL. Details of the detector design, simulation of efficiency
and coincidence performance, HPGe crystal testing, and progress on cryostat construction are presented. 相似文献
98.
Maize kernel hardness classification by near infrared (NIR) hyperspectral imaging and multivariate data analysis 总被引:1,自引:0,他引:1
The use of near infrared (NIR) hyperspectral imaging and hyperspectral image analysis for distinguishing between hard, intermediate and soft maize kernels from inbred lines was evaluated. NIR hyperspectral images of two sets (12 and 24 kernels) of whole maize kernels were acquired using a Spectral Dimensions MatrixNIR camera with a spectral range of 960-1662 nm and a sisuChema SWIR (short wave infrared) hyperspectral pushbroom imaging system with a spectral range of 1000-2498 nm. Exploratory principal component analysis (PCA) was used on absorbance images to remove background, bad pixels and shading. On the cleaned images, PCA could be used effectively to find histological classes including glassy (hard) and floury (soft) endosperm. PCA illustrated a distinct difference between glassy and floury endosperm along principal component (PC) three on the MatrixNIR and PC two on the sisuChema with two distinguishable clusters. Subsequently partial least squares discriminant analysis (PLS-DA) was applied to build a classification model. The PLS-DA model from the MatrixNIR image (12 kernels) resulted in root mean square error of prediction (RMSEP) value of 0.18. This was repeated on the MatrixNIR image of the 24 kernels which resulted in RMSEP of 0.18. The sisuChema image yielded RMSEP value of 0.29. The reproducible results obtained with the different data sets indicate that the method proposed in this paper has a real potential for future classification uses. 相似文献
99.
We propose to synthesize a new class of single-walled nanotubular compounds (SWNCs) and investigate the interplay between their structural and electronic properties using ab initio density functional calculations. SWNCs are composed of cyclacenes of variable diameter interconnected by various linker compounds. Cyclacenes map directly onto and can be viewed as the shortest segments of (n,0) zigzag carbon nanotubes. We focus on cyclacenes with n=6-12 fused benzene rings interconnected by biphenyl, tetrazine, or acetylene linkers. Depending upon the nature and the orientation of the linkers, we find it possible to change the systems from narrow-gap to wide-gap semiconductors, and to modulate the band dispersion, suggesting the possibility of band gap engineering. 相似文献
100.
Nucleophilic substitution reactions of 4-substituted cyclohexanone acetals display different selectivities depending upon the electronic nature of the substituent. Alkyl groups favor equatorial positions in the oxocarbenium ions, but alkoxy groups prefer axial conformers. The reactions of acetals with alkoxy groups constrained to either equatorial or axial positions suggest that the presence of an axial alkoxy group distorts the oxocarbenium ion, changing its inherent preferences for facial attack. 相似文献