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51.
Marcos Almeida Bezerra Sérgio Mitihiro do Nascimento Maêda Eliane Padua Oliveira Maria de Fátima Batista de Carvalho Ricardo Erthal Santelli 《Spectrochimica Acta Part B: Atomic Spectroscopy》2007
In the present paper a procedure is proposed for the determination of traces of Cd, Co, Mn and Cr in petroleum industry produced water by inductively coupled plasma optical emission spectrometry. The procedure is based on cloud point extraction of these metals, as their dithizonate complexes, into the surfactant-rich phase of octylphenoxypolyethoxyethanol surfactant (Triton X-114). Extractions were carried out in solutions with salinities between 10‰ and 70‰. Since residual salinity in the surfactant-rich phase caused differences in its transport to the plasma, yttrium was used as an internal standard to correct for this effect. The simultaneous metal extraction procedure was optimized by response surface methodology using a Doehlert design and desirability function. Enhancement factors of 21, 21, 9 and 19, along with limits of quantification of 0.093, 0.20, 0.73 and 1.2 μg L− 1, and precision expressed as relative standard deviation (n = 8, 20.0 μg L− 1) of 5.8, 1.2, 1.7 and 5.7% were obtained for Cd, Co, Mn and Cr, respectively. The accuracy was evaluated by spike recovery tests on the high salinity water samples with salinity of 40 and 63‰. 相似文献
52.
René Meziat Diego Patiño Pablo Pedregal 《Computational Optimization and Applications》2007,38(1):147-171
We propose an alternative method for computing effectively the solution of non-linear, fixed-terminal-time, optimal control
problems when they are given in Lagrange, Bolza or Mayer forms. This method works well when the nonlinearities in the control
variable can be expressed as polynomials. The essential of this proposal is the transformation of a non-linear, non-convex
optimal control problem into an equivalent optimal control problem with linear and convex structure. The method is based on
global optimization of polynomials by the method of moments. With this method we can determine either the existence or lacking
of minimizers. In addition, we can calculate generalized solutions when the original problem lacks of minimizers. We also
present the numerical schemes to solve several examples arising in science and technology. 相似文献
53.
Humberto César Chaves Fernandes Arthur Rodrigo Barros da Rocha 《International Journal of Infrared and Millimeter Waves》2003,24(7):1171-1176
The use of photonic materials has been used in the theory of optical waves. The PBG (Photonic Band Gap) theory and material, was developed recently for optical frequencies and can be easily applied to millimeter waves, microwaves and planar antenna frequencies. The presence of photonic materials as substrate in antennas has some good characteristics such as, supression of light spontaneous emission and suppression of surface waves, allowing the application in planar antenna array. In this work an elaborate analysis using the full wave Transverse Transmission Line - TTL method, that provides efficient and concise results is applied to the planar antennas array with PBG substrate. 相似文献
54.
字节全加器及其在无线电测控系统中的应用 总被引:1,自引:1,他引:0
对全加器概念进行了推广,并在此基础上给出了使用字节全加器网络的无线电抗干扰算法。通过在实际的无线电测控系统中的应用,结果表明该算法具有良好的无线电抗干扰效果。 相似文献
55.
J. H. de Araújo J. B. M. da Cunha A. Vasquez L. Amaral J. T. Moro F. C. Montenegro S. M. Rezende M. D. Coutinho Filho 《Hyperfine Interactions》1991,67(1-4):507-511
57Fe Mössbauer effect measurements in the diluted Ising antiferromagnet Fe x Zn1?x F2 withx=0.25 andx=0.57 at temperatures between 4.2 and 55 K, are reported. DC suceptibility measurements show a spin-glass (SG) phase at low temperatures forx≤0.31. Our Mössbauer spectra show a phase transition to a SG state with antiferromagnetic order (AFSG) forx=0.25 and only antiferromagnetic order forx=0.57. 相似文献
56.
The equilibrium statistical volume distribution in foams, which has been previously demonstrated to be the so-called log-normal, is accounted on probability grounds by a scaling law on the bubble's volume time-evolution. This law states that the conditional probability for a given bubble to have the volume v(t + Δt), he assumption that it was v(t), to depend solely on the relationship v(t + Δt)/v(t), and in particular, to be independent of the time t. The theoretical results, however, allow to go further. Indeed, since the time dependece of its parameters (expectation and variance) are given functions of time, only two parameters are necessary to describe completely the foam. 相似文献
57.
Audrey A S G Lonni Ieda S Scarminio Lucas M C Silva Dalva T Ferreira 《Analytical sciences》2003,19(7):1013-1017
Phytochemical investigation of the aerial parts of three Baccharis species (Asteraceae family) was performed using HPLC and chemometric methods, with the objective of distinguishing between three morphologically very similar species: Baccharis genistelloides Persoon var. trimera (Less.) DC, B. milleflora (Less.) DC and B. articulata (Lam.) Persoon. With the help of Principal Component Analysis (PCA) and variance weights, it was possible to characterize the chromatographic profiles of the alcoholic extracts of the three species. Application of Soft Independent Modeling of Class Analogy (SIMCA) and K-Nearest Neighbor (KNN) methods on a training set of 74 extracts resulted in models that correctly classified all eight samples in an independent test set. 相似文献
58.
I. Bretos J. Ricote R.J. Jiménez-Riobóo L. Pardo M.L. Calzada 《Applied Physics A: Materials Science & Processing》2007,89(4):967-973
A novel method to investigate the early formation stages of polycrystalline (Pb1-xCax)TiO3 (PCT) perovskite films by means of traditional Brillouin and micro-Brillouin spectroscopy (BS, mBS) is described in the present
work. The films were prepared by chemical solution deposition (CSD) onto oxidized (100)Si substrates and treated at temperatures
between 350–650 °C by rapid thermal processing (RTP). The elastic instability observed by Brillouin spectroscopy at the nano-structured
state of the PCT films was used here to determine their crystallization temperatures. Coexistence of different nanocrystalline
phases (e.g., pyrochlore, perovskite) in the films could also be detected by this technique. The reliability of these results
is demonstrated by complementary information obtained by X-ray diffraction (XRD) and scanning force microscopy (SFM). The
effects of the annealing temperature and of the Ca2+ content on the crystallization process of these films are also discussed.
PACS 78.35.+c; 77.84.-s; 61.82.Rx 相似文献
59.
Roberto D. Galvão Luis Gonzalo Acosta Espejo Brian Boffey 《Annals of Operations Research》2006,143(1):31-44
A study has been carried out aimed at reducing perinatal mortality in the municipality of Rio de Janeiro through a better
distribution of health care facilities. The algorithmic aspects are detailed elsewhere and here the emphasis is on practical
issues and difficulties encountered.
A 3-level hierarchical model was developed. Both uncapacitated and capacitated versions are briefly described together with
some results based on actual data. The project brought to light many contradictions between OR theory and practice in developing
countries and, unfortunately, the models developed were not implemented by the municipality health authorities. Possible reasons
for this outcome are analysed. 相似文献
60.
A fully coupled formulation combining reactive transport and an existing thermo-hydro-mechanical (THM) code is presented.
Special attention has been given to phenomena likely to be encountered in clay barriers used as part of containment systems
of nuclear waste. The types of processes considered include hydrolysis, complex formation, oxidation/reduction reactions,
acid/base reactions, precipitation/dissolution of minerals and cation exchange. Both kinetically-controlled and equilibrium-controlled
reactions have been incorporated. The total analytical concentrations (including precipitated minerals) are adopted as basic
transport variables and chemical equilibrium is achieved by minimizing Gibbs Free Energy. The formulation has been incorporated
in a general purpose computer code capable of performing numerical analysis of engineering problems. A validation exercise
concerning a laboratory experiment involving the heating and hydration of an expansive compacted clay is described. 相似文献