The Assignment of the 1600 cm−1 Mystery Band of Carbons

Abstract

The assignment of a band near 1600 cm^?1 in IR spectra of carbons has been controversial for four decades. However, many different carbons have been studied: effectively, a single band assignment was sought for an absorption appearing with three different classes of carbon. As these differ in over-all structure, not one but three explanations are needed. These are discussed. However, undue emphasis has been placed on a single absorption; attention should also be paid to other absorptions accompanying the 1600 cm^?1 band.     

Compressive Mass Analysis on Quadrupole Ion Trap Systems

Conventionally, quadrupole ion trap mass spectrometers eject ions of different mass-to-charge ratio (m/z) in a sequential fashion by performing a scan of the rf trapping voltage amplitude. Due to the inherent sparsity of most mass spectra, the detector measures no signal for much of the scan time. By exploiting this sparsity property, we propose a new compressive and multiplexed mass analysis approach—multi Resonant Frequency Excitation (mRFE) ejection. This new approach divides the mass spectrum into several mass subranges and detects all the subrange spectra in parallel for increased mass analysis speed. Mathematical estimation of standard mass spectrum is demonstrated while statistical classification on the parallel measurements remains viable because of the sparse nature of the mass spectra. This method can reduce mass analysis time by a factor of 3–6 and increase system duty cycle by 2×. The combination of reduced analysis time and accurate compound classification is demonstrated in a commercial quadrupole ion trap (QIT) system.

The Cesàro operator on the Bergman space $ A^{2} (\mathbb{D}) $

The Cesàro operator is shown to be subdecomposable on the Bergman spaces A^p (\mathbbD) A^{p} (\mathbb{D}) for p \geqq 2 p \geqq 2 , extending a result of [12] to the case that p < 4. For A² (\mathbbD) A^{2} (\mathbb{D}) , we show that Cesàro operator is in fact subscalar, but in contrast to the situation in the Hardy space, C |_A² C |_{A^2} fails to be hyponormal.     

The reaction of the hydroxyl radical with acetylene

The reaction of OH with acetylene was studied in a discharge flow system at room temperature. OH was generated by the reaction of atomic hydrogen with NO₂ and was monitored throughout the reaction using ESR spectroscopy. Mass-spectrometric analysis of the reaction products yielded the following results: (1) less than 3 molecules of OH were consumed, and less than 2 molecules of H₂O were formed for every molecule of acetylene that reacted; (2) CO was identified as the major carbon-containing product; (3) NO, formed in the generation of OH, reacted with a reaction intermediate to give among other products N₂O. These observations placed severe limitations on the choice of a reaction mechanism. A mechanism containing the reaction OH + C₂H₂ → HC₂O + H₂ better accounted for the experimental results than one involving the abstraction reaction OH + C₂H₂ → C₂H + H₂O. The rate constant for the initial reaction was measured as 1.9 ± 0.6 × 10^?13 cm³ molecule^?1 sec^?1.     

Surface plasmons propagating parallel to the grooves of a large amplitude grating

The dispersion relation is obtained for a surface plasmon propagating parallel to the grooves of a large amplitude grating. Two variants of the Rayleigh method arc used: the first requires the evaluation of the zeros of a determinant; the second yields the dispersion relation in terms of the solution of a matrix eigenvalue problem. The dispersion relations are solved numerically for a sinusoidal and for a symmetric sawtooth grating profile, yielding in each case an infinity of discrete branches.     

The ionic conductivity of rapidly quenched tungstate and molybdate glasses containing lithium halides

Rapidly quenched lithium tungstate and molybdate glasses containing up to 20 mole% lithium chloride and bromide additives have been prepared. The additives are found to give a small increase (up to a factor of two at room temperature) in the lithium ion conductivity of the glass which can be understood in terms of models developed for network forming glasses.     

Photorefractive effects for reversible holographic storage of information

Optical storage of information offers great potential for high capacity and speed. A very promising approach to the embodiment of an optical memory is based on volume storage in the form of phase holograms. Attractive storage materials for such a system are electrooptic crystals. The storage mechanism in these materials is based on light induced permanent changes of the refractive index-the photorefractive effect. In this article the physical processes underlying photorefractive hologram recording are outlined, and some of the advantages and limitations of this method are discussed.     

A comparison of local search methods for flow shop scheduling

Local search techniques are widely used to obtain approximate solutions to a variety of combinatorial optimization problems. Two important categories of local search methods are neighbourhood search and genetic algorithms. Commonly used neighbourhood search methods include descent, threshold accepting, simulated annealing and tabu search. In this paper, we present a computational study that compares these four neighbourhood search methods, a genetic algorithm, and a hybrid method in which descent is incorporated into the genetic algorithm. The performance of these six local search methods is evaluated on the problem of scheduling jobs in a permutation flow shop to minimize the total weighted completion time. Based on the results of extensive computational tests, simulated annealing is found to generate better quality solutions than the other neighborhood search methods. However, the results also indicate that the hybrid genetic descent algorithm is superior to simulated annealing.