首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   10163篇
  免费   629篇
  国内免费   372篇
化学   6299篇
晶体学   74篇
力学   563篇
综合类   40篇
数学   1617篇
物理学   2571篇
  2023年   87篇
  2022年   242篇
  2021年   299篇
  2020年   330篇
  2019年   273篇
  2018年   229篇
  2017年   208篇
  2016年   375篇
  2015年   377篇
  2014年   357篇
  2013年   622篇
  2012年   641篇
  2011年   737篇
  2010年   481篇
  2009年   458篇
  2008年   570篇
  2007年   562篇
  2006年   516篇
  2005年   448篇
  2004年   385篇
  2003年   301篇
  2002年   299篇
  2001年   177篇
  2000年   130篇
  1999年   138篇
  1998年   91篇
  1997年   90篇
  1996年   109篇
  1995年   92篇
  1994年   101篇
  1993年   98篇
  1992年   93篇
  1991年   69篇
  1990年   55篇
  1989年   51篇
  1988年   43篇
  1987年   56篇
  1986年   33篇
  1985年   65篇
  1984年   76篇
  1983年   55篇
  1982年   68篇
  1981年   65篇
  1980年   69篇
  1979年   77篇
  1978年   53篇
  1977年   44篇
  1976年   46篇
  1975年   33篇
  1974年   30篇
排序方式: 共有10000条查询结果,搜索用时 625 毫秒
81.
A novel power generator has been achieved to convert vibration to electrical energy via the piezoelectric effect. The generator obtained by micro fabrication process mainly consists of silicon based frame and composite cantilever. The prototype tested at resonant vibration generates 1.15μW of effective power to a 20.4-kΩ resistance load. The potential of this work is to offer miniaturization solutions for power generators, and with the proposed method the ambient ubiquitous vibration can be harvested effectively as endless energy source to form an integrated self-powering system.  相似文献   
82.
Differentkindsofopenchaincrownethershavebeensynthesizedasthemodelcompoundsofionophoresandtheirinteractionswithsodium,potassiumandrareearthionshavealsobeenstudiedl'z.PanshowedCe(III)yieldedalf1complexwithl,8-bis(8'-quinolyloxy)-3,6-dioxaandtheCe(IIl)ioncoordinatedbothtoetheroxygenandquinolinenitrogenatoms3.TUmInleridentifiedtwolanthanidenitratecomplexeshavingastoichiometryof3:2(3RE:2L)'.InordertostUdythefunctionsofbothquinolineandbenzenering,introducedintothepolyetherchain,a1inearpolyether…  相似文献   
83.
A set of coordinates in the non-parametric loop-space is introduced. We show that these coordinates transform under infinite dimensional linear representations of the diffeomorphism group. An extension of the group of loops in terms of these objects is proposed. The enlarged group behaves locally as an infinite dimensional Lie group. Ordinary loops form a subgroup of this group. The algebraic properties of this new mathematical structure are analyzed in detail. Applications of the formalism to field theory, quantum gravity and knot theory are considered.  相似文献   
84.
85.
For any d and g such that the Brill-Noether number (d,g,3) is negative, d20 and gf(d), where f(d)=d3/2/(6·21/2) + lower order terms, there exists a regular component of H d,g 3 (the closure in Hilb3 of the open set parametrizing smooth, connected, non-degenerate curves in 3) with the expected number of moduli. Moreover, examples of the fact that such components are not unique are given.  相似文献   
86.
Summary In this paper we introduce some new classes of functions, among these a class of weak diffeomorphisms. In these classes we prove by direct methods the existence of minimizers for several kinds of variational integrals. In particular, we prove the existence of one-to-one orientation-preserving maps that minimize suitable energies associated with hyperelastic materials. The minimizers are also proved to satisfy equilibrium equations. Finally radial deformations are discussed in connection with cavitation.  相似文献   
87.
A novel method for preparing silver nanoelectrode ensembles(SNEEs) and gold nanoelectrode ensembles (GNEEs) has been developed. Silver colloid particles were first absorbed to the gold electrode surface to form a monolayer silver colloid. N-hexadecyl nercaptan was then assembled on the electrode to form a thoil monolayer on which hydrophilic ions cannot be transfered. The SNEEs was prepared by removing thiol from silver colloid surface through applying and AC voltage with increasing frequency at 0.20V(vs.SCE). Finally,GNEEs was obtained by immersing a SNEEs into 6 mol/L HNO3 to remove the silver colloid particles. By comparison with other methods such as template method ect., this method enjoys some advantages of lower resistance, same diameter,easy preparation,controllable size and density.  相似文献   
88.
The arylidene malonates with two different geminal carboxylate functions, a suitable class of substrates of several synthetic and pharmacological studies, are easily available through Knoevenagel condensation of ethyl tert-butyl malonate and different aromatic aldehydes. The results have increased the potentialities of CeCl3·7H2O-NaI system as a type of water-tolerant green Lewis acid promoter for carbon-carbon bond forming procedures.  相似文献   
89.
立方介孔相含钇氧化硅的合成与表征   总被引:4,自引:0,他引:4  
以低浓度的十六烷基三甲基溴化铵为结构导向剂,在碱性条件下通过水热法合成了具有立方结构的含钇Y MCM 48介孔分子筛材料。XRD测试表明当Y/Si<0.05时可以获得典型的长程有序介孔立方结构相,随Y/Si比的增加,晶胞参数的增大和红外吸收光谱(FTIR)的变化为Y进入介孔分子筛骨架中提供了有力证据。N2吸附-脱附实验给出这种立方介孔材料的BET表面积为1180m2·g-1,BJH平均孔径为3.4nm。紫外 可见漫反射光谱(UV vis)证明钇以一种六配位的形式存在。X射线光电子能谱(XPS)进一步证明钇以三价形式存在于立方介孔分子筛骨架中。  相似文献   
90.
利用一缺位杂多酸对一维链式配合物的断链取代反应,合成了未见文献报道的以甘氨酸为桥联配体的双核稀土杂多配合物,其结构简式为K10[(O39W11Si)RE(Gly)3RE(SiW11O39)]·9H2O(RE=La,Pr,Nd,Sm,Eu,Gd,Tb,Dy,Y;Gly=NH3+CH2COO<  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号