全文获取类型
收费全文 | 324篇 |
免费 | 12篇 |
专业分类
化学 | 184篇 |
晶体学 | 3篇 |
力学 | 4篇 |
数学 | 42篇 |
物理学 | 103篇 |
出版年
2023年 | 12篇 |
2022年 | 7篇 |
2021年 | 11篇 |
2020年 | 6篇 |
2019年 | 9篇 |
2017年 | 5篇 |
2016年 | 6篇 |
2015年 | 14篇 |
2014年 | 17篇 |
2013年 | 23篇 |
2012年 | 37篇 |
2011年 | 27篇 |
2010年 | 12篇 |
2009年 | 15篇 |
2008年 | 20篇 |
2007年 | 20篇 |
2006年 | 8篇 |
2005年 | 18篇 |
2004年 | 7篇 |
2003年 | 3篇 |
2002年 | 2篇 |
2001年 | 6篇 |
2000年 | 3篇 |
1999年 | 1篇 |
1998年 | 2篇 |
1997年 | 3篇 |
1996年 | 6篇 |
1995年 | 1篇 |
1993年 | 5篇 |
1992年 | 3篇 |
1988年 | 3篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1983年 | 2篇 |
1982年 | 1篇 |
1981年 | 3篇 |
1980年 | 1篇 |
1979年 | 3篇 |
1978年 | 2篇 |
1977年 | 2篇 |
1972年 | 1篇 |
1971年 | 2篇 |
1965年 | 1篇 |
1939年 | 2篇 |
1938年 | 1篇 |
排序方式: 共有336条查询结果,搜索用时 15 毫秒
71.
A novel route to the synthesis of cyclopropane derivatives is described. 1,1-Dimethyls in 2-(1,1-dimethylalkyl)dimethyloxazolines are first converted into 1,3-diiodide derivatives via Pd-catalyzed sequential C-H activation and then radically cyclized to provide 2-(1-alkylcylclopropyl)dimethyloxazolines. The use of EtOAc as a solvent is crucial for the diiodination of the functionalized substrates. [reaction: see text] 相似文献
72.
Nanocrystalline Cr2O3 and NiO are prepared using high-energy ball milling. Average sizes of the particles obtained from Scanning Electron Microscopy and crystallite sizes obtained from X-ray diffraction are larger for Cr2O3 than NiO particles. At low temperature, large high-field magnetization and small coercivity lead to a weak exchange bias for Cr2O3, whereas small high-field magnetization and large coercivity lead to a considerable exchange bias for NiO. The training effect is observed for NiO at 4 K which could be described with a recursive formula constructed in the framework of the spin configurational relaxation model. The results suggest that the pinning mechanism at the interface between the antiferromagnetic and the weak ferromagnetic component ascribed to uncompensated spins leads to the exchange bias effect. 相似文献
73.
The critical behaviour of surface adsorption and collapse transition of a flexible self-attracting self-avoiding polymer chain
is examined. Depending upon the underlying lattice and space dimensionality, phase diagrams that exhibit many different universality
domains of critical behavior are found. We discuss these phase diagrams and the values of the critical exponents found from
different theoretical methods. 相似文献
74.
We have previously reported a novel approach to implementing multiplex enzyme-linked immunosorbent assay (ELISA) in connected microchannels by exploiting the slow diffusion of the enzyme reaction product across the different assay segments. This work builds on that report by implementing the noted assay in segments arranged along the circumference of a circular channel layout to reduce the footprint size and sample volume requirement. Using the current design, a 5-plex cytokine ELISA was demonstrated in a 1.5 × 1.5-cm region, which corresponded to a reduction in the footprint area by about a factor of 3 compared to that reported in our previous study. Additionally, the selective coating of our assay segments with the target molecules was realized in this work using electroosmosis instead of hydrodynamic flow as was the case in the previous report. This aspect of our experimental design is particularly significant as it permits the use of cross-sectional channel dimensions significantly shorter than those employed in the current work. Moreover, the use of an electric field for coating purposes enables the integration of functionalities such as electrokinetic preconcentration of analyte molecules during the sample incubation period that can further enhance the capabilities of our assay method. 相似文献
75.
Time-independent quantum mechanical (TIQM) approach (helicity basis truncated at k = 2) has been used for computing differential and integral cross sections for the exchange reaction H- + D2 (v = 0, j = 0-4) --> HD + D- and D- + H2 (v = 0, j = 0-3) --> HD + H- in three dimensions on an accurate ab initio potential energy surface. It is shown that the j-weighted differential reaction cross section values are in good agreement with the experimental results reported by Zimmer and Linder at four different relative translational energies (Etrans = 0.55, 0.93, 1.16 and 1.48 eV) for (H-, D2) and at one relative translational energy (Etrans = 0.6 eV) by Haufler et al. for both (H-, D2) and (D-, H2) collisions. The j-weighted integral reaction cross section values are in good agreement with the crossed beam measurements by Zimmer and Linder in the Etrans range 0.5-1.5 eV and close to the guided ion beam results by Haufler et al. for (H-, D2) in the range 0.8-1.2 eV. Time-dependent quantum mechanical (TDQM) results obtained using centrifugal sudden approximation are reported in the form of integral reaction cross section values as a function of Etrans in the range 0.3-3.0 eV for both reactions in three dimensions on the same potential energy surface. The TDQM reaction cross section values decline more sharply than the TIQM results with increase in the initial rotational quantum number (j) for the D2 molecules in their ground vibrational state (v = 0) for (H-, D2) collisions. The computed j-weighted reaction cross section values are in good agreement with the experimental results reported by Zimmer and Linder for (H-, D2) collisions and guided ion beam results by Haufler et al. for both (H-, D2) and (D-, H2) collisions for energies below the threshold for electron detachment channel. 相似文献
76.
A Pd(II)-catalyzed reaction protocol for the direct carboxylation of benzoic and phenylacetic acid derivatives to form dicarboxylic acids has been developed. The reaction conditions are also applicable for the carboxylation of vinyl C-H bonds. The first C-H insertion Pd-aryl complex from carboxylic acids has been characterized by X-ray crystallography. 相似文献
77.
O-Methyl hydroxamic acids, readily available from carboxylic acids, are found to be extremely reactive for beta-C-H activation by Pd(OAc)2. This reactivity is exploited to develop the first example of cross-coupling sp3 C-H bonds with sp3 boronic acids. Air was shown to be a suitable stoichiometric oxidant for the catalytic oxidative coupling reaction. A biologically active natural product is readily converted to its novel analogues through this coupling reaction. 相似文献
78.
Archiv der Mathematik - The convergence analysis of the Landweber iteration for solving inverse problems in Banach spaces via Hölder stability estimates is well studied by de Hoop et al.... 相似文献
79.
80.
The collision-induced process He + H(2)(+)(v = 0-2; j = 0-3) → He + H + H(+) has been investigated using a time-dependent quantum mechanical wave packet approach, within the centrifugal sudden approximation. The exchange reaction He + H(2)(+) → HeH(+) + H, which has a lower threshold, dominates over the dissociation process over the entire energy range considered in this study. The reaction cross section for both the exchange and dissociation channels and the branching ratio between the two channels have been computed on the McLaughlin-Thompson-Joseph-Sathyamurthy potential-energy surface and compared with the available experimental and quasiclassical trajectory results. 相似文献