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151.
152.
M.S. Attia A.O. Youssef Amr A. Essawy M.S.A. Abdel-Mottaleb 《Journal of luminescence》2012,132(10):2741-2746
Highly luminescent complexes of Eu and Tb ions with norfloxacin (NFLX) and gatifloxacin (GFLX) were prepared in sol–gel matrix. The red and green emissions of Eu and Tb ions were obtained by the energy transfer from the triplet state of (NFLX) and (GFLX) to the excited emitting states (5D0 and 5D4) of Eu and Tb, respectively. The intensity of the electric field emission bands (5D0→7F2, 617 nm and 5D4→7F5, 545 nm) of Eu and Tb ions were proportional to the concentration of (NFLX at pH 6.0) and (GFLX at pH 3.5) in acetonitrile with excitation wavelengths (λex) (340 and 395) and (370 and 350 nm) for Eu and Tb ions, respectively. The monitored luminescence intensity of the system showed a good linear relationship with the concentration of NFLX within a range of 5×10?9–5.8×10?6 and 5×10?8–1.0×10?6 mol L?1 with a correlation coefficient of 0.990, and for GFLX within a range of 2.4×10?9–3.2×10?5 and 5×10?8–8.0×10?6 mol L?1 with a correlation coefficient of 0.995. The detection limit (LOD) was determined as 3.0×10?9 and 1.0×10?8 mol L?1 for NFLX and 1.6×10?10 and 2.0×10?8mol L?1 for GFLX. The limit of quantification (LOQ) is 9×10?9 and 3.0×10?8 and 4.8×10?10 and 6.0×10?8 in case of Eu and Tb, respectively. 相似文献
153.
A new, simple, sensitive, rapid, and accurate isocratic RP-HPLC method was developed and validated for simultaneous analysis of the principal antioxidants of Nigella sativa, i.e., thymoquinone (TQ), carvacrol (CR), and its isomer thymol (THY), in different phytopharmaceuticals. The mobile phase was water-methanol (40 + 60, v/v) at a flow rate of 1.5 mL/min. Quantification was achieved with UV detection at 254 nm, based on peak area. The method was validated for linearity, accuracy, precision, selectivity, and robustness. The proposed method is stability-indicating for determination of TQ in the presence of its degradants. The LOD and LOQ (microg/mL) were, respectively, 0.006 and 0.021 for TQ, 0.002 and 0.006 for CR, and 0.027 and 0.090 for THY. The mean recoveries measured at three concentrations were higher than 99%, with RSD <2%. This analytical method is suitable for quality control of the marker substances in this widely used natural protective and curative remedy. 相似文献
154.
Youssef Saab 《Journal of Heuristics》2001,7(3):235-250
A divide-and-conquer approach for the feedback arc set is presented. The divide step is performed by solving a minimum bisection problem. Two strategies are used to solve minimum bisection problem: A heuristic based on the stochastic evolution methodology, and a heuristic based on dynamic clustering. Empirical results are presented to compare our method with other approaches. An algorithm to construct test cases for the feedback arc set problem with known optimal number of feedback arcs, is also presented. 相似文献
155.
Ahmed S. A. Youssef Kamal A. Kandeel Fouli A. Fouli Wael S. I. Abou‐Elmagd 《Heteroatom Chemistry》2005,16(1):6-11
2‐Amino‐3‐cyano‐4,5,6,7‐tetrahydrobenzo[b]thiophene 1a or 2‐amino‐3‐cyano‐4,7‐di‐ phenyl‐5‐methyl‐4H‐pyrano[2,3‐c]pyrazole 2a reacted with phenylisocyanate in dry pyridine to give 2‐(3‐phenylureido)‐3‐cyanobenzo[b]thiophene 1b or 2‐disubstituted amino‐3‐cyanopyranopyrazole 2b derivative. However, when 1a and 2a were refluxed with carbon disulfide in 10% ethanolic sodium hydroxide solution, they afforded the thieno[2,3‐d]pyrimidin‐2,4‐dithione derivative 5 in the former case, 2,4‐dicyano‐1,3‐bis(dithio carboxamino)cyclobuta‐1,3‐ diene 6 and pyrazolopyranopyrido[2,3‐d]pyrimidin‐ 2,4‐dithione derivative 7 in the latter one. Treatment of 2a with thiourea in refluxing ethanol in the presence of potassium carbonate gave 2,2′‐dithiobispyrimidine derivative 9 (major) in addition to pyranopyrazole derivative 10 and 2,2′‐dithiobis ethoxypyrimidine derivative 11 in minor amounts. The structures of all products were evidenced by microanalytical and spectral data. © 2005 Wiley Periodicals, Inc. Heteroatom Chem 16:6–11, 2005; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20070 相似文献
156.
HamdyM.Youssef 《应用数学和力学(英文版)》2005,26(4):470-475
Introduction Thetheoryofgeneralizedthermoelasticitywithonerelaxationtimebasedonamodified Fourier’slawofheatconductionwasdevelopedbyLordandShulman[1].Thistheoryallowsfor theso_calledsecond_soundeffectsinsolids,hencethermaldisturbancespropagatewithfinite wavespeeds. Themathematicalmodelofthegeneralizedthermoelasticitytheoryisofacomplicatednature thathindersthepossibilityofderivingananalyticalsolution.Mostattemptsdealingwiththese equationsarebasedoneithershort_timesolution[2-4]. Modernstructur… 相似文献
157.
Cellulose - The synthesis of multi-function flame retardants is widely increasing to fulfill industrial and economic goals. In this work, a novel flame retardant, melamine salt of tannic phosphate... 相似文献
158.
159.
New Ni(II), Pd(II) and Pt(II) complexes coordinated to azo pyrazolone ligand with a potent anti‐tumor activity: Synthesis,characterization, DFT and DNA cleavage studies 下载免费PDF全文
Eman A. Bakr Gad B. Al‐Hefnawy Mohamed K. Awad Hossam H. Abd‐Elatty Mohamed S. Youssef 《应用有机金属化学》2018,32(2)
The absolute necessity to fight some class of tumor is perceived as serious health concerns, so the discovery and development of effective anticancer agents are urgently needed. (E)‐4‐((2‐hydroxyphenyl)diazenyl)‐3‐phenyl‐1H‐pyrazol‐5(4H)‐one, HL, and its Ni(II), Pd(II) and Pt(II) complexes were synthesized and the biological activity was evaluated for antitumor, antioxidant and antimicrobial activity as well as DNA cleavage. Their structures were assigned depending on the elemental analysis, conductivity, magnetic moment, spectral measurements (IR, 1HNMR, mass and UV–Vis) and thermal analysis. 3D molecular modeling using DFT method confirmed that the geometrical structures agree well with the suggested experimental ones. The antitumor activity was evaluated against four different cell lines using MTT assay. The ligand HL showed a potent cytotoxic activity compared to 5‐fluorouracil as a reference drug. For metal complexes, the order of activity was: Pd(II) > Ni(II) > Pt(II). A remarkable antioxidant activity for the ligand HL was recorded. It was higher than that of the metal complexes. Results of antimicrobial experiments revealed that all compounds were moderate to highly active against selected bacterial strains but inactive as antifungal except Pd(II) which showed a moderate antifungal activity. Gel electrophoresis showed insignificant nucleases activity for the ligand or its metal complexes even in the presence of H2O2 providing protection of DNA from damage. The antitumor activity of our compounds may be not due to DNA cleavage but may be referred to a mechanism similar to that of 5‐fluorouracil which interfere with DNA replication. The present work suggests the use of this ligand in the design and development of new anticancer drugs. 相似文献
160.
Youssef Haouat 《Archiv der Mathematik》1988,51(4):303-307
Sans résumé 相似文献