Spectroscopic determination of binding between human serum albumin and a platinum(II) dimethylsulfoxide complex

We have used electronic absorption and fluorescence spectroscopy to study binding between a platinum(II) dimethylsulfoxide complex (cis-[Pt(DMSO)₂Cl₂]) and human serum albumin (HSA), and the effect of complexation on the structure of the protein. We have calculated the binding parameters for binding between cis-[Pt(DMSO)₂Cl₂] and HSA. We have determined the binding constant K_B = (1.2 ± 0.1)·10³ M⁻¹ and the Hill coefficient h = 1.03 ± 0.1. We have determined that binding between cis-[Pt(DMSO)₂Cl₂] and the protein leads to a change in the internal packing of the macromolecule. __________ Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 75, No. 4, pp. 573–576, July–August, 2008.     

Isospin symmetry violating effects and scattering length extraction from kaon decays

The isospin symmetry breaking effects in the charged kaons decays to two or three pions are considered. In semileptonic decay K ^± → π ⁺ π ^?e^± ν (called K _e4) these effects turn out to be crucial for correct extraction of ππ scattering lengths. Taking in account electromagnetic interaction between the pions in the final state and isospin symmetry breaking due to different masses of charged and neutral pions allows to adjust the values of scattering lengths obtained from experimental data on K _e4 decay and predictions of Chiral Perturbation Theory (ChPT). Final state interactions of pions in the decay K ^± → π ^± π ⁰ π ⁰ leading to the anomaly (cusp) in the π ⁰ π ⁰ invariant mass distribution in the vicinity of charged pions’ threshold are discussed and recent results of accounting of the electromagnetic interaction among charged pions leading to π ⁺ π ^? bound states (pioniumatom) just under the charged pions’ threshold are presented.     

The effect of electron irradiation on the optical properties of the natural armenian zeolite-clinoptilolite

Infrared (IR) absorption and luminescence in chemically and radiation-modified natural Armenian Zeolite (clinoptilolite) samples have been studied. The luminescence was studied in 390–450 nm and 620–710 nm wavelength bands, and the IR measurements were carried out in the 400–5400 cm⁻¹ range. It is shown that the luminescence intensity depends on the content of pure clinoptilolite in the samples and, probably on the distribution of “passive” luminescence centers over Si and Al sites that became “active” under radiation or chemical treatment. The samples of electron irradiated clinoptilolite have higher luminescence intensity than the chemically and thermally treated ones. A decrease in the intensity of IR absorption bands at 3550 cm⁻¹ and 3650 cm⁻¹ was found after irradiation.     

Formation of relativistic positron systems by the axial channeling of positrons in ionic crystals

An analytical expression is written for the effective interaction potential of a fast charged particle with ionic crystals of the CsCl type as a function of the temperature of the medium, taking long-range order into account. A numerical analysis shows that there is a real possibility of axial superchanneling of positrons along the 〈100〉 axis of negatively charged ions in crystals with this structure. The wave function and energy spectrum of the localized state are investigated, and the possibility of the formation of metastable, two-dimensional, relativistic positron systems is analyzed. Zh. Tekh. Fiz. 68, 116–120 (April 1998)     

Synthesis and some reactions of isopropenyloxirane

A convenient method for the synthesis of isopropenyloxirane by dehydrohalogenation of halohydrins obtained by isomerization of 1-halo-3-methyl-2,3-epoxybutanes was developed. The reactions of isopropenyloxirane with alcohols, water, secondary amines, hydrogen halides, dichlorocarbene, acetic acid anhydrides, and Grignard reagents were studied.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 450–457, April, 1985.