Ergänzungen zu einem Artikel über dualisierende Komplexe

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Acyl- und Alkylidenphosphane. XXV. Molekül- und Kristallstruktur des 1,2-Di(tert-butyl)-3-dimethylamino-1-thio-4-trimethylsilylsulfano-1λ5,2λ3-diphosphet-3-ens

Acyl- and Alkylidenephosphines. XXV. Molecular and Crystal Structure of 1,2-Di(tert-butyl)-3-dimethylamino-1-thio-4-trimethylsilylsulfano-1λ⁵, 2λ³-diphosphet-3-ene The title compound 1 formed in a nearly quantitative yield by decomposition of tert-butyl(N,N-dimethylthiocarbamoyl)trimethylsilylphosphine, crystallizes in the orthorhombic space group P2₁2₁2₁ with {a = 1067.3(1); b = 1077.1(1); c = 1924.6(5) pm; Z = 4} at +20°C. An X-ray structure determination (R_G = 0.038) shows two tert-butyl groups at a four- (P1) and a three-coordinate phosphorus atom (P2) to be placed on different sides of the four membered ring. Characteristic bond lengths as well as the angles at the atoms P1, P2, C3, and C4 inside the ring have already been given above.