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91.
Rajendra J Baxendale M Dit Rap LG Rodger A 《Journal of the American Chemical Society》2004,126(36):11182-11188
Structures of carbon nanotube/ligand complexes were studied by flow linear dichroism (the differential absorption of light polarized parallel and perpendicular to the flow orientation direction) with the aim of establishing linear dichroism as a technique to study such systems. Anthracene, naphthalene, and DNA were chosen as ligands, and the potential for flow linear dichroism to probe ligands noncovalently (as well as covalently) bound to single-walled nanotubes is reported. Linear dichroism enables the determination of approximate orientations of the ligands on the carbon nanotubes. 相似文献
92.
Lucca A Debourg G Jacquemet M Druon F Balembois F Georges P Camy P Doualan JL Moncorgé R 《Optics letters》2004,29(23):2767-2769
We report what is believed to be the first demonstration of a high-power passively mode-locked diode-pumped femtosecond laser based on an Yb3+:CaF2 single crystal, directly pumped by a 15-W fiber-coupled laser diode. With a 5-at. % Yb3+ -doped sample and prisms for dispersion compensation we obtained pulses as short as 150 fs, with 880 mW of average power and up to 1.4-W average output power, with a pulse duration of 220 fs, centered at 1049 nm. The laser wavelength could be tuned from 1040 to 1053 nm in the femtosecond regime. Using chirped mirrors for dispersion compensation, the oscillator provided up to 1.74 W of average power, with a pulse duration of 230 fs, corresponding to a pulse energy of 20 nJ and a peak power of 85 kW. 相似文献
93.
Single-component adsorption isotherm data were acquired by frontal analysis (FA) for phenol and caffeine on a new C18-Chromolith column (Merck, Darmstadt, Germany), using a water-rich mobile phase (methanol/water, 15/85, v/v). These data were modeled for best agreement between the experimental data points and the adsorption isotherm model. The adsorption-energy distributions, based on the expectation-maximization (EM) procedure, were also derived and used for the selection of the best isotherm model. The adsorption energy distributions (AEDs) for phenol and caffeine converged toward a trimodal and a quadrimodal distribution, respectively. Energy distributions with more than two modes had not been reported before for the adsorption of these compounds on packed columns. The third high energy mode observed for both phenol and caffeine seems to be specific of the surface of the monolithic column while the first and second low energy modes have the same physical origin as the two modes detected on packed columns. These results suggest significant differences between the structures of the porous silica in these different materials. 相似文献
94.
Papadopoulos DN Forget S Delaigue M Druon F Balembois F Georges P 《Optics letters》2003,28(19):1838-1840
We demonstrate the operation of an ultralow-repetition-rate, high-peak-power, picosecond diode-pumped Nd:YVO4 passively mode-locked laser oscillator. Repetition rates lower than 1 MHz were achieved with the use of a new design for a multiple-pass cavity and a semiconductor saturable absorber. Long-term stable operation at 1.2 MHz with a pulse duration of 16.3 ps and an average output power of 470 mW, corresponding to 24-kW peak-power pulses, is reported. These are to our knowledge the lowest-repetition-rate high-peak-power pulses ever generated directly from apicosecond laser resonator without cavity dumping. 相似文献
95.
It is shown that the large- N approach yields two energy scales for the Kondo lattice model. The single-impurity Kondo temperature, T(K), signals the onset of local singlet formation, while Fermi-liquid coherence sets in only below a lower scale, T small star, filled. At low conduction electron density n(c) ("exhaustion" limit), the ratio T small star, filled/T(K) is much smaller than unity, and is shown to depend only on n(c) and not on the Kondo coupling. The physical meaning of these two scales is demonstrated by computing several quantities as a function of n(c) and temperature. 相似文献
96.
A full mean-field solution of a quantum Heisenberg spin-glass model is presented in a large- N limit. A spin-glass transition is found for all values of the spin S. The quantum critical regime associated with the quantum transition at S = 0 and the various regimes in the spin-glass phase at high spin are analyzed. The specific heat is shown to vanish linearly with temperature. In the spin-glass phase, intriguing connections between the equilibrium properties of the quantum problem and the out-of-equilibrium dynamics of classical models are pointed out. 相似文献
97.
Georges Pinczon 《Letters in Mathematical Physics》2007,82(2-3):237-253
We give a new proof and an improvement of two Theorems of J. Alev, M.A. Farinati, T. Lambre and A.L. Solotar [1] : the first
one about Hochschild cohomology spaces of some twisted bimodules of the Weyl Algebra W, and the second one about Hochschild cohomology spaces of the smash product G * W (G a finite subgroup of SP (2n)) and, as a consequence, we then give a new proof of a Theorem of P. Etingof and V. Ginzburg (Invent Math 147:243–348, 2002),
which shows that the Symplectic Reflection Algebras are deformations of G * W (and, in fact, all possible ones).
Dedicated to my friend J.-C. Cortet. 相似文献
98.
Eric Messens Alfons Lenaerts Marc Van Montagu André De Bruyn Arnold W.H. Jans Georges Van Binst 《Journal of carbohydrate chemistry》2013,32(4):683-699
The 1H NMR data of agrocinopine in D2O solution as extracted from standard 2D NMR experiments, along with 1D 31P and 13C NMR experiments allow to support the trisaccharide structure originally proposed on basis of comparative 13C NMR measurements. 相似文献
99.
Henri Edouard Audier Arielle Milliet Georges Sozzi Steen Hammerum 《Journal of mass spectrometry : JMS》1990,25(1):44-48
The key intermediates to the fragmentation of metastable methyl and ethyl benzoate radical cations are α- and β-distonic isomers of the molecular ions. The α-distocic isomers are also formed by fragmentation of longer chain alkyl benzoates, but may not be long-lived, stable species. Rearrangement of the α-distonic ions prior to fragmentation can take place, but (re)formation of the benzoate molecular ions does not occur. 相似文献
100.
Marie Odile Monnet Thierry Fauret Vincent Levacher Georges Dupas Jean Bourguignon Guy Quguiner 《Journal of heterocyclic chemistry》1989,26(4):1029-1037
Pyrrolo[2,3-b] and [3,2-b]pyridines derivatives, precursors for annealated NADH models have been prepared. Several methods for building a pyridinic annealates ring have been used starting from 2- or 3-aminopyrrole. The corresponding dihydropyridine structure leads to highly reactive NADH models compounds and are very much more stable than common models. 相似文献