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141.
Extraction of radiolabeled cobalt(II) from aqueous solution into one or more solvents using 25 reagents was studied. Both reagent concentration and pH variation were investigated. The relevant association and partition constants for several of the better reagent-solvent systems were determined. These systems were hexanoic acid in I-hexanol, octanoic acid in I-octanol, and thenoyltrifluoroacetone in benzene. 相似文献
142.
A new catalytic oxidation procedure, involving the use of a cerium(IV) sulfate reagent in perchloric acid with a mixed silver(I)—manganese(II) perchlorate catalyst, has been developed for the determination of phosphite, hypophosphite, and tellurium. By this method 15—100 mg of phosphite, 5—35 mg of hypophosphite, and 10—105 mg of tellurium may be determined with standard deviations of ±0.17, ±0.32, and ±0.21% respectively. A direct titration procedure for mercury(I) is described using a ceric perchlorate solution as titrant with the mixed catalyst system. Samples from 65–510 mg may be analyzed with a standard deviation of ±0.36%. 相似文献
143.
George B. Kauffman 《The Chemical Educator》2000,5(6):340-342
Dr. Dean Stanley Tarbell, Distinguished Professor Emeritus of chemistry at Vanderbilt University, where he served on the faculty from 1967 to 1981, died on May 26, 1999 in Bolingbrook, Ill. Earlier he taught for many years and chaired the chemistry department at the University of Rochester. In retirement, he and his wife, Ann Tracy Tarbell, researched and wrote articles and books on the history of chemistry in the U.S. For his writings he received the American Chemical Societys Dexter Award for Distinguished Contributions to the History of Chemistry in 1989. He was an avid reader and book collector, a linguist who taught himself Arabic, Russian, and classical Greek, and a lifelong baseball fan. 相似文献
144.
Clark GR Pytel PD Squire CJ Neidle S 《Journal of the American Chemical Society》2003,125(14):4066-4067
The first crystal structure of a drug (daunomycin) bound to a parallel-stranded intermolecular telomeric G4 quadruplex (d(TGGGGT)4) has been determined to high resolution. A planar assemblage of three daunomycin molecules stacks onto the 5' end of the G4 column, with the daunosamine substituents occupying three of the four quadruplex grooves. The surface area of the terminal G-quartet in this parallel DNA quadruplex, presently occupied by three daunomycins, is sufficiently large that it could easily accommodate other potential telomerase inhibitors such as substituted porphyrins or telomestatin. 相似文献
145.
Jerald C. Hinshaw W. Wayne Edwards Clifford George Richard Gilardi 《Journal of heterocyclic chemistry》1992,29(7):1721-1724
Dealkylation of 1-tert-butyl-2,3,4-trinitropyrrole in boiling trifluroacetic acid gave 2,3,4-trinitropyrrole, the structure of which was confirmed by X-ray crystallography. Treatment of this trinitropyrrole with nitric acid/oleum briefly at 60° gave 2,3,4,5-tetranitropyrrole. 相似文献
146.
Heterogeneous activation of oxone using Co3O4 总被引:3,自引:0,他引:3
Anipsitakis GP Stathatos E Dionysiou DD 《The journal of physical chemistry. B》2005,109(27):13052-13055
This study explores the potential of heterogeneous activation of Oxone (peroxymonosulfate) in water using cobalt oxides. Two commercially available cobalt oxides, CoO and Co3O4 (CoO.Co2O3) were tested for the activation of peroxymonosulfate and the consequent oxidation of 2,4-dichlorophenol (2,4-DCP) via a sulfate radical mechanism. Both systems, CoO/Oxone and Co3O4/Oxone, were tested at acidic and neutral pH and compared with the homogeneous Co(NO3)2/Oxone. The activity of these systems was evaluated on the basis of the induced transformation of 2,4-DCP as well as the dissolution of cobalt occurred after 2 h of reaction. It was observed that only Co3O4 activates peroxymonosulfate heterogeneously, with its heterogeneity being more pronounced at neutral pH. Both CoO and Co2O3 contained in Co3O4 might be responsible for the observed heterogeneity, and the relative mechanisms are further discussed here. To our knowledge, this is perhaps the first study that documents the heterogeneous activation of peroxymonosulfate with cobalt, the best-known catalyst-activator for this inorganic peroxide. 相似文献
147.
Miguel Gascón-LópezMajid Motevalli George PaloumbisPeter Bladon Peter B Wyatt 《Tetrahedron》2003,59(47):9349-9360
Stabilised tributylphosphonium ylids Bu3PCHCH(EWG), where EWG is CO2Me, CO2tBu or CN, react with protected sugar lactones under mild conditions to give high yields of glycosylidene derivatives (4 and 5) with good Z/E selectivity. X-Ray crystallography shows that in the solid state the tetra-O-benzyl protected (Z)-glucosylideneacetonitrile (Z)-4c adopts a conformation intermediate between a boat and a twist-boat, whereas the isomeric galactose derivative (Z)-5c exists as a distorted chair. NMR data suggest that in solution chair-like conformations are again more favoured for galactosylidene derivatives than for their glucosylidene analogues. Solution phase NMR studies and molecular modelling show that the (E)-double bond geometry disfavours the chair-like geometry of the ring, even in the galactose series; this is consistent with the avoidance of allylic 1,3-strain. Reduction of the glycosylidene double bond to give stereoselective formation of β-C-glycoside derivatives may be achieved by using Et3SiH-CF3CO2H or Et3SiH-BF3·Et2O. 相似文献
148.
George Bobowski 《Journal of heterocyclic chemistry》1983,20(1):183-187
The treatment of N-[2-(1H-indol-3-yl)ethyl]alkanamide, 1 (1), with phosphorus oxychloride under controlled conditions gave l-alkyl-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indol-1-ol, 2 . The reaction of 2 with acetic anhydride or with methyl isocyanate at room temperature resulted in the formation of amido carbinol 3 and urea carbinol 7, respectively. The former was transformed into amido ester 4 by boiling acetic anhydride. When the reaction of 3 with acetic anhydride was carried out in the presence of excess triethylamine at 105°, C-N bond cleavage of the tetrahydropyridine ring took place with concurrent bis(N-acetylation) to give the enol ester derivative 5 . The structures of all compounds are consistent with chemical and spectral evidence. 相似文献
149.
Potyrailo RA Chisholm BJ Morris WG Cawse JN Flanagan WP Hassib L Molaison CA Ezbiansky K Medford G Reitz H 《Journal of combinatorial chemistry》2003,5(4):472-478
Coupling of combinatorial chemistry methods with high-throughput (HT) performance testing and measurements of resulting properties has provided a powerful set of tools for the 10-fold accelerated discovery of new high-performance coating materials for automotive applications. Our approach replaces labor-intensive steps with automated systems for evaluation of adhesion of 8 x 6 arrays of coating elements that are discretely deposited on a single 9 x 12 cm plastic substrate. Performance of coatings is evaluated with respect to their resistance to adhesion loss, because this parameter is one of the primary considerations in end-use automotive applications. Our HT adhesion evaluation provides previously unavailable capabilities of high speed and reproducibility of testing by using a robotic automation, an expanded range of types of tested coatings by using the coating tagging strategy, and an improved quantitation by using high signal-to-noise automatic imaging. Upon testing, the coatings undergo changes that are impossible to quantitatively predict using existing knowledge. Using our HT methodology, we have developed several coatings leads. These HT screening results for the best coating compositions have been validated on the traditional scales of coating formulation and adhesion loss testing. These validation results have confirmed the superb performance of combinatorially developed coatings over conventional coatings on the traditional scale. 相似文献
150.
Fomblin [poly(perfluoropropylene oxide)], PFK (perfluorokerosene) and FC-43 (perfluorotributylamine) are investigated as mass calibrants in electron-capture negative ionization mass spectrometry on a magnetic sector hybrod mass spectrometer. This work provides exact negative ion mass tables of these three calibrants obtained using high-resolution peak matching of representative ions of the calibrants against ions of known mass. The suitability of these calibrants for full data system control in the negative ionization mode is demonstrated for the techniques of high-resolution scanning, selected ion recording and calibration of the quadrupole sector of a hybrid instrument. 相似文献