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51.
Perez Gutierrez RM Rosario Vargas S Martinez Martinez F Garcia Baez E Figueroa Torres G 《Natural product research》2006,20(3):305-310
Antispasmodic activity-guided fractionation together with chemical analysis led to the isolation of one novel delta-lactone named oedogonolide from Oedogonium capillare. Identification was based on spectroscopic methods. The oedogonolide produces a significant antispasmodic effect on the contractions of the rat ileum induced by acetylcholine, histamine and barium chloride. 相似文献
52.
53.
Bo Chen Fangyue Chen Junbiao Guan Genaro J. Mart ''{ i}nez 《Journal of Applied Analysis & Computation》2016,6(4):1164-1179
By introducing a sequence-block transformation and vector-block transformation, we explore the dynamical properties of hybrid cellular automation (HCA) and hybrid cellular automation with memory (HCAM) in the framework of symbolic dynamics. As the local evolution rules of HCA and HCAM are not-uniform, the new uniform cellular automata (CAs) with multiple states are constructed by specifical the block transformations. Furthermore, because the new CA rules are topologically conjugate with the originals, the complex dynamics of the HCA and HCAM rules can be investigated via the new CA rules. 相似文献
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55.
John Blackwell Robin A. Chivers Genaro A. Gutierrez Amit Biswas 《Journal of Macromolecular Science: Physics》2013,52(1-4):39-59
This paper describes x-ray analysis of the structure of a group of wholly aromatic thermotropic liquid crystalline copolyesters, focusing on two systems: condensation copolymers of 4-hydroxy-benzoic acid (HBA) and 2-hydroxy–6-naphthoic acid; and of HBA, 2,6-dihydroxy-naphthalene, and terephthalic acid. The fiber diagrams of these copolymers contain a series of aperiodic meridional maxima that shift in position with the monomer ratio. We have shown that these characteristics are predicted by a structure consisting of an array of chains of completely random monomer sequence. The positions of the maxima are predicted by a simple model in which the monomers are represented by points, separated from their neighbors by the appropriate monomer lengths. Use of atomic models for the monomers leads to prediction of both the positions and the intensities of the maxima. Calculations for nonrandom sequence distribution show that all but minimal blockiness can be ruled out. From the breath of the meridional maximum at d = 2.1 Å it is possible to estimate the correlation or persistence length for the stiff chain conformation in the solid state. 相似文献
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57.
Audra M. Judd Danielle B. Gutierrez Jessica L. Moore Nathan Heath Patterson Junhai Yang Carrie E. Romer Jeremy L. Norris Richard M. Caprioli 《Journal of mass spectrometry : JMS》2019,54(8):ii-ii
Matrix‐assisted laser desorption/ionization imaging mass spectrometry (MALDI IMS) is a molecular imaging technology uniquely capable of untargeted measurement of proteins, lipids, and metabolites while retaining spatial information about their location in situ. This powerful combination of capabilities has the potential to bring a wealth of knowledge to the field of molecular histology. Translation of this innovative research tool into clinical laboratories requires the development of reliable sample preparation protocols for the analysis of proteins from formalin‐fixed paraffin‐embedded (FFPE) tissues, the standard preservation process in clinical pathology. Although ideal for stained tissue analysis by microscopy, the FFPE process cross‐links, disrupts, or can remove proteins from the tissue, making analysis of the protein content challenging. To date, reported approaches differ widely in process and efficacy. This tutorial presents a strategy derived from systematic testing and optimization of key parameters, for reproducible in situ tryptic digestion of proteins in FFPE tissue and subsequent MALDI IMS analysis. The approach describes a generalized method for FFPE tissues originating from virtually any source. 相似文献
58.
We study the deterministic spin dynamic of two interacting magnetic moments with anisotropy and dipolar interaction under the presence of an applied magnetic field, by using the Landau–Lifshitz equation with and without a damping term. Due to different kinds of interactions, different time scales appear: a long time scale associated with the dipolar interaction and a short time scale associated with the Zeeman interaction. We found that the total magnetization is not conserved; furthermore, for the non-dissipative case it is a fluctuating function of time, with a strong dependence on the strength of the dipolar term. In the dissipative case there is a transient time before the total magnetization reaches its constant value. We examine this critical time as a function of the distance between the magnetic moments and the phenomenological damping coefficient, and found that it strongly depends on these control parameters. 相似文献
59.
A directed path graph is the intersection graph of a family of directed subpaths of a directed tree. A rooted directed path graph is the intersection graph of a family of directed subpaths of a rooted tree. Clearly, rooted directed path graphs are directed path graphs. Several characterizations are known for directed path graphs: one by forbidden induced subgraphs and one by forbidden asteroids. It is an open problem to find such characterizations for rooted directed path graphs. With the purpose of proving knowledge in this direction, we show in this paper properties of directed path models that can not be rooted for chordal graphs with any leafage and with leafage four. Therefore, we prove that for leafage four directed path graphs minimally non rooted directed path graphs have a unique asteroidal quadruple, and can be characterized by the presence of certain type of asteroidal quadruples. 相似文献
60.
Paola Acosta Braulio Insuasty Rodrigo Abonia Margarita Gutierrez Jairo Quiroga 《Molecular diversity》2017,21(4):943-955
An efficient route for the synthesis of novel 7-aryl and 7-spiropyrazolo[4\(^{\prime }\),3\(^{\prime }\):5,6]pyrido[2,3-d]pyrimidine derivatives is described. These compounds were obtained by a cyclocondensation reaction between pyrazolopyridinediamines 4 and aldehydes 5 or cyclic ketones 6 in the presence of acetic acid as catalyst. This procedure provides the desired compounds in good yields under a simple two-step methodology. The obtained compounds were evaluated as AChE inhibitors and showed weak AChe inhibition with \(\hbox {IC}_{50} = 115{-}470 \, \upmu \hbox {M}\). 相似文献